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2 protocols using 5 methylfurfural

1

Biobased Furans Synthesis from Carbohydrates

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Co (NO3)2•6H2O, 2-methylimidazole, 5-hydroxymethylfurfural (97.0%), 5-methylfurfural, 2-butanol, urea, and melamine were procured from Shanghai Macklin Biochemical Co. Cu (NO3)2•3H2O, methanol, tetrahydrofuran (THF), and isopropanol (IPA) were procured from Guangzhou Chemical Reagent Factory. Glucose was procured from Tianjin Zhiyuan Chemical Reagent Co. Ltd.
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2

Quantification of Carbonyl Compounds

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Glyoxal (40% solution in water, high-performance LC [HPLC] grade), methylGlyoxal (40% solution in water, HPLC grade) and ethanol (99.9%, HPLC grade) were purchased from Sigma-Aldrich (Shanghai, China). Water was purified using a Milli-Q purification system (Millipore, Bedford, MA). Methanol (99.9%, LC grade), acetonitrile (ACN; 99.90%, LC grade), formic acid (99%, LC grade), furfural, 5-hydroxymethylfurfural, 5-methylfurfural, 2,3-butanedione and 2,3-pentanedione were purchased from Macklin Biochemical Co., Ltd. (Shanghai, China). 3-Deoxyglucosone was purchased from Yuanye Bio-Technology Co., Ltd. (Shanghai, China).
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