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2 protocols using tert butylpyridine tbp

1

Perovskite Solar Cell Fabrication

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Fluorine-doped tin oxide glass (FTO) was obtained from YingKou OPV Tech New Energy Co. Ltd. Acetone, isopropanol, n-butyl alcohol and APMS were obtained from Aladdin. Bis(pentane-2,4-dionato-O,O′)bis(propan-2-olato)titanium, PbI2, γ-butyrolactone (GBL), tert-butylpyridine (tBP) and lithium bis(trifluoromethylsulfonyl)imide (Li-TFSI) were purchased from Sigma-Aldrich. CH3NH3I and spiro-MeOTAD were purchased from Xi'an Polymer Light Technology Corp.
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2

Synthesis of Lead Halide Perovskite Materials

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Lead(ii) iodide (99% PbI2, Sigma-Aldrich), lead chloride (PbCl2, Sigma-Aldrich), hydroiodic acid (HI, 57 wt% in H2O distilled stabilized 99.95% HI, Sigma-Aldrich), hydrochloric acid (37 wt% HCl, Sigma-Aldrich), methylamine (TCI, 40 wt% in water), γ-butyrolactone (GBL, Sigma-Aldrich), acetonitrile (Sigma-Aldrich), toluene (Sigma-Aldrich), mesoscopic TiO2 paste (m-TiO2, Sharechem), titanium diisopropoxide bis(acetylacetonate) (Sigma-Aldrich), Li-bis(trifluoromethanesulfonyl)imide (Li-TFSI, Sigma-Aldrich), tert-butylpyridine (t-BP, Sigma-Aldrich), acetonitrile (Sigma-Aldrich), and poly(triarylamine) (PTAA, EM-index) were used as received.
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