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2 protocols using 1 2 diaminobenzene

1

Synthesis of Organic Compounds and Materials

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The chemicals used were purchased from commercial
suppliers and utilized without further purification. 1,2-Diaminobenzene
(Alfa Aesar, 98%), benzenesulfonyl chloride (Alfa Aesar, 98%), pyridine
(Sigma-Aldrich, 99+), palladium on activated carbon (Pd/C, Acros Organics,
10% Pd), hexaketocyclohexane octahydrate (HKH·8H2O,
Fisher Scientific, 97%), terephthalaldehyde (ThermoFisher Scientific,
98%), anhydrous 1,4-dioxane (Acros Organics), mesitylene (Acros Organics),
sulfuric acid (H2SO4, Fisher Scientific, 94–98%),
diethylene glycol dimethyl ether (DEGDME, Sigma-Aldrich, anhydrous
99.5%), conductive carbon black (Ketjenblack-600JD), sodium hexafluorophosphate
(NaPF6, Alfa Aesar, 99+%), and sodium alginate (Alfa Aesar,
high viscosity).
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2

Synthesis of Pyridine-based Compounds

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Pyridine-2-carboxaldehyde, 6-methylPyridine-2-carboxaldehyde, 2-(aminomethyl)pyridine, nickel(ii) perchlorate hexahydrate, nitrilotriacetic acid, iodoethane (Sigma-Aldrich), sodium triacetoxyborohydride, 1,2-diaminobenzene, 3-hydroxyflavone (Alfa Aesar), ethyl acetate, triethylamine, sodium sulphate (Merck, India), were used as received. Dichloromethane, diethylether, tetrahydrofuran, acetonitrile (Merck, India) and methanol, acetone (Sisco Research Laboratory, Mumbai) were distilled before use. The supporting electrolyte tetra-N-butylammonium perchlorate (Aldrich) was recrystallized and used.
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