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5 protocols using cetyltrimethylammonium bromide

1

Fabrication of Silica-Based Nanoparticles

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Submicron-sized silica particles (Sciqas
series, Sakai Chemical Industry Co., Ltd. (Sakai, Japan)) were used
as received as core particles. The average diameter of the silica
core particles (Dcore) was 451 nm. The
coefficient of variation of diameters (CV), which is commonly used to evaluate the monodispersity of particles,
was 4.9%. Sodium bromide (NaBr, 99.9%), tetraethyl orthosilicate (TEOS,
95%), cetyltrimethylammonium bromide (CTAB, 98%), ammonia aqueous
solution (NH3, 25%), and ethanol (99.5%) were purchased
from FUJIFILM Wako Pure Chemical Corporation (Osaka, Japan). Deionized
water (>18.2 MΩ·cm) was prepared by Direct-Q3 UV (Merck
KGaA; Darmstadt, Germany).
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2

Synthesis of Bismuth-Based Metal-Organic Framework

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Sodium hydroxide (NaOH), and 2-propanol (C3H8O, IPA) were purchased from Nacalai Tesque, Inc. (Kyoto, Japan). 1,3,5-Benzentricaboxylic acid (H3BTC) was obtained from Tokyo Chemical Industry Co., LTD (Tokyo, Japan). Bismuth nitrate pentahydrate (Bi(NO3)3·5H2O), cetyltrimethylammonium bromide (CTAB), methanol (MeOH), ethanol (EtOH), sodium chloroacetate (ClCH2COONa), ethylenediaminetetraacetic acid disodium (EDTA–2Na), rhodamine B (RhB) and 1,4-benzoquinone (C6H4O2, BQ) were purchased from Fujifilm Wako Pure Chemical Co., (Osaka, Japan). Cotton fabric (CF) was provided by Shikisensha Co., LTD (Osaka, Japan). All materials were analytical grade and used as received without further purification.
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3

Synthesis and Characterization of Metal Complexes

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Chemicals were purchased from commercial sources and used without further purification, unless otherwise noted. Tetraethyl orthosilicate, cetyltrimethylammonium bromide, sodium aluminate, sodium hydroxide, an aqueous solution of hydrogen peroxide (30 wt%) and perchloric acid (60%) were purchased from Wako Pure Chemical Industries. Tris(2-pyridylmethyl)amine and oxo[5,10,15,20-tetra(4-pyridyl)porphyrinato]titanium(IV) (Ti–TPyP) were supplied from Tokyo Chemical Industry. Copper(II) perchlorate hexahydrate were delivered by Sigma-Aldrich. Acetone and acetonitrile were purchased from Nacalai tesque as a spectral grade and used as received. Ultra-Pure water was provided by a water purification system, Millipore Direct-Q3 UV, where the electronic conductance was 18.2 MΩ cm. Benzene was purchased from Wako Pure Chemical Industries and purified by washing with sulphuric acid and water and following distillation. [Cu(tmpa)(CH3CN)](ClO4)2, [Cu(tepa)(ClO4)]ClO4, [CuII2(N5)(H2O)2](NO3)4 and Al-MCM-41 were synthesised by literature methods.53a (link),58 (link)–61
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4

Synthesis and Characterization of Metal Complexes

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Chemicals were purchased from commercial sources and used without further purification, unless otherwise noted. Tetraethyl orthosilicate, cetyltrimethylammonium bromide, sodium aluminate, sodium hydroxide, aqueous solutions of hydrogen peroxide (30 wt%) and perchloric acid (60%) were purchased from Wako Pure Chemical Industries. Tris(2-pyridylmethyl)amine and oxo[5,10,15,20-tetra(4-pyridyl)porphyrinato]titanium(iv) (Ti–TPyP) were supplied from Tokyo Chemical Industry. Copper(ii) perchlorate hexahydrate was supplied by Sigma-Aldrich. Acetone and acetonitrile were purchased from Nacalai tesque as a spectral grade and used as received. Ultra-pure water was provided by a water purification system, Millipore Direct-Q3 UV, wherein the electronic conductance was 18.2 MΩ cm. Benzene was purchased from Wako Pure Chemical Industries and purified by washing with sulphuric acid and water following distillation. [Cu(tmpa)(CH3CN)](ClO4)2, [Cu(tepa)(ClO4)]ClO4, [CuII2(N5)(H2O)2](NO3)4 and Al-MCM-41 were synthesised by literature methods.53a ,61 (link)–64
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5

Emulsion Preparation for Biomolecule Analysis

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All of the reagents used in this study were of analytical grade. Deionized water was prepared by means of an Elix water purification system (Millipore Co. Ltd., Molsheim, France). Cetyltrimethylammonium bromide (CTAB), sodium dodecyl sulfate (SDS), and 1-buthanol were obtained from Wako Pure Chemical Industries (Osaka, Japan). Polyethylene glycol #200 (PEG) and n-decane were purchased from Kanto Chemical (Tokyo, Japan) and Nacalai Tesque (Kyoto, Japan), respectively. Mineral oil (refractive index, 1.467) was purchased from Sigma-Aldrich (St. Louis, MO, USA).
Aqueous solutions of CTAB, SDS, and PEG were dissolved in water and placed into separate 5 mL vials. To prepare the emulsions, a 50-μL aliquot of a mixture containing 1-butanol and n-decane at a volume ratio of 1:1 was added to each aqueous solution, and then the mixtures were sonicated twice for 3 min each time.
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