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30 protocols using indium acetate

1

Synthesis of Colloidal Nanocrystals

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Indium acetate (In(Ac)3, 99.99%), indium chloride (InCl3, 98%), myristic acid (HMA) (≥99%), oleic acid (OA) (≥99%), octadecylphosphonic acid (ODPA) (97%), chlorotrimethylsilane (TMS-Cl) (≥98%), zinc stearate (Zn(SA)2) (technical grade), zinc oxide (99.99%), toluene (99.5%), hexanes (98.5%), 1-octadecene (ODE, 90%), squalane (≥95%), toluene-d8 (99 atom % D), deuterium oxide (99.9 atom % D), hydrochloric acid aqueous solution (35.0%), and phosphoric acid aqueous solution (85.0%) were purchased from Aldrich. Tris(trimethylsilyl)phosphine ((TMS)3P) (95%) was purchased from SK chemicals. Bio-Beads S-X1 GPC medium was purchased from Bio-Rad Laboratories, Inc. All chemicals were used without further purification.
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2

Synthesis of Copper-Indium-Zinc Sulfide

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Zinc acetate (Zn(OAc)2, 99.99%), indium acetate (In(OAc)3, 99.99%), oleylamine (OAm, 95%), 1-octadecene (ODE, 97%), sulfur powder (99.99%) were purchased from Aldrich, copper iodide (CuI, 99.99%), 3-mercaptopropionic acid (MPA, 99%) were obtained from Alfa Aesar. All reagents were used as received without further treatments.
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3

Synthesis of Indium-based Nanocrystals

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Indium acetate [In(OAc)3, 99.99%], oleic acid (OA, technical grade, 90%), dioctylamine (DOA, Aldrich, ≥97%), 1-octadecene (ODE, 90%), N, N-dimethylformamide (DMF, 99.8% anhydrous), octane (99% anhydrous), 1-butanol (BuOH, 99.8% anhydrous), toluene (Tol, 99.8% anhydrous), ammonium acetate (AA, 99.999%), 2-MCE (99%), MTA (98%) were purchased from Sigma-Aldrich. Tris(trimethylsilyl)arsine [(TMSi)3As] was purchased from Dockweiler Chemicals Inc. Indium (III) bromide (InBr3, 99.999% anhydrous) was purchased from Strem Chemicals, Inc. All the mentioned chemicals were used as received.
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4

Synthesis of Colloidal Nanocrystals

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Copper iodide (CuI, 99.999%), indium acetate (In(OAc)3, 99.99%), 1-dodecanethiol (DDT, 98%), 1-octadecene (ODE, 90%), oleic acid (OA, 90%), and zinc acetate (Zn(OAc)2, 99.99%) were purchased from Aldrich. All chemicals were used as received.
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5

Synthesis of Indium-Copper Nanocrystals

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Indium acetate (In(OAc) 3 , 99.99%), copper iodide (CuI, ≥99.5%), oleylamine (OAm, 97%), 1-octadecene (ODE, 90%), 3-mercaptopropionic acid (3-MPA, >99%), sulfur powder (S, 99.5%),
N-(3-dimethylaminopropyl)-N′-ethylcarbodiimide hydrochloride (EDC, ≥99.0%), N-hydroxysuccinimide (NHS, 98%), dibenzocyclooctyne-amine (DBCO-amine), triethanolamine (TEOA, ≥99.0%), and dimethyl sulfoxide (DMSO) were purchased from Sigma-Aldrich. All chemicals and solvents were used as received.
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6

Synthesis of Nanocrystalline Materials

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Indium acetate (InOAc, 99.99%), OA (≥99%), dioctylamine (DOA, ≥97%), 1‐octadecene (ODE, 90%), ME (≥99%), and InCl3 (≥98%) were purchased from Sigma‐Aldrich Chemical Co. Trimethylsilylarsine ((TMSi)3As, 99%) was purchased from JSI Silicone. All solvents used in the experiments (hexane, butanol, and ethyl alcohol) were purchased from Sigma‐Aldrich Chemical Co.
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7

Synthesis of Functionalized Nanomaterials

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Indium acetate (99.99%), copper iodide (99.999%),
mercaptoundecanol, thiourea, and ethylene glycol were purchased from
Sigma-Aldrich. HS-PEG(3400)-Biotin was purchased from ChemQuest. Methanol
(analytical reagent grade) was purchased from Fisher. All chemicals
were used as supplied.
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8

Synthesis of Indium-based Nanomaterials

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Indium acetate (99.99%), myristic acid (>99%), tris(trimethylsilyl)phosphine (95%), 1-dodecanethiol (97%), 1-octadecene (90%), D-penicillamine, tetramethylammonium hydroxide (TMAOH), and tris(2carboxyethyl) phosphine hydrochloride solution 0.5 M (TCEP) were purchased from Sigma-Aldrich. Zinc stearate (90%) was acquired from Riedel de Haen. Indium(III) oxide (99.9997%), indium (III) sulphur (99.995%), indium (III) phosphide (99.99%) and indium (III) phosphate (>98%) were purchased from VWR. Further solvents used within the synthesis were bought from Sigma-Aldrich, Fluka, Acros, and used without further purification.
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9

Synthesis of Colloidal Nanocrystals

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Silver acetate (Ag(OAc), 99.9%) and 1-dodecanethiol (DDT, 98.0%) were purchased from Fujifilm Wako Pure Chemical, Japan. Indium acetate (In(OAc)3, 99.9%) and gallium acetylacetonate (Ga(acac)3, 99.9%) were obtained from Sigma-Aldrich, USA. 1,3-dimethylthiourea (DMTU, >97.0%) and tri-n-octylphosphine (TOP, >85%) were supplied by Tokyo Chemical Industry, Japan. The above-mentioned chemicals were used as received without further purification. Oleylamine (OAm, >50%) was purchased from Fujifilm Wako Pure Chemical and then purified by vacuum distillation in the presence of calcium hydride.
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10

Synthesis of Metal Chalcogenide Nanoparticles

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Zinc acetate (Zn(Ac)2, 99.5%), silver nitrate (AgNO3, 99.8%), sulfur powder (S, 99.99%), 1-dodecanethiol (DDT, 98.0%), methyl alcohol (analytical regent), and chloroform (analytical regent) were purchased from Sinopharm Chemical Reagent Co., Ltd. Indium acetate (In(Ac)3, 99.99%) and oleylamine (OAm, 70%) were purchased from Sigma-Aldrich Co. LLC. All regents were used as received without further experimental purification.
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