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Bis triphenylphosphine palladium 2 dichloride pd pph3 2cl2

Manufactured by Merck Group
Sourced in Germany

Bis(triphenylphosphine)palladium(II)dichloride (Pd(PPh3)2Cl2) is a coordination complex of palladium. It is a yellow crystalline solid that is soluble in organic solvents. The compound serves as a source of palladium for various catalytic applications.

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2 protocols using bis triphenylphosphine palladium 2 dichloride pd pph3 2cl2

1

Brominated Pyrene Synthesis

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1,3,6,8-Tetrabromopyrene,
1-octyne, 1-dodecyne, bis(triphenylphosphine)palladium(II)
dichloride (Pd(PPh3)2Cl2) and copper(I)
iodide (CuI) were procured from Sigma-Aldrich. The solvents, dichloromethane
(DCM) and petroleum benzine, were procured from Merck Ltd., and anhydrous
tetrahydrofuran (THF) and diisopropylamine were obtained from Sigma-Aldrich.
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2

Synthesis and Characterization of Carbazole-based Materials

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9H-Carbazole (1), 3,3-bis(chloromethyl)oxetane, 4-(diphenylamino)phenylboronic acid, 9-ethyl-9H-carbazole-3-boronic acid pinacol ester, naphthalene-1-boronic acid, bis(triphenylphosphine)palladium(II) dichloride (Pd(PPh3)2Cl2), K2CO3, KOH, KI, KIO3, tetra-n-butylammonium hydrogen sulfate (TBAHS), Na2SO4 and solvents were purchased from Sigma Aldrich (Merck, Darmstadt, Germany) and used as received. Materials used for prepared perovskites solar cells: fluorine-doped tin oxide coated glass slides (FTOs, 7 Ω/sq, Sigma-Aldrich), tetraethyl orthotitanate ((C2H5O)4Ti, Merck), hydrochloric acid (HCl, CHEMPUR), anhydrous ethanol (EtOH, POCH), paste Ti-Nanoxide T/SP (Solaronix), methylammonium iodide (MAI, Solaronix), isopropanol (IPA, POCH), chlorobenzene (C6H5Cl, POCH). Lead iodide (PbI2), anhydrous N,N-dimethylformamide (DMF), lithium bis(trifluoromethanesulfonyl)imide (Li-TFSI), 4-tert-butyl pyridine (TBP). All were purchased from Sigma-Aldrich. 3-Iodo-9H-carbazole (2) was synthesized according to the procedure described in the literature [14 ].
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