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2 protocols using d penicillamine

1

Analytical Standards Chemical Analysis

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All the
reagents were of analytical grade
unless otherwise stated. Hydrogen tetrachloroaurate trihydrate (min.
99.9%), PESTANAL analytical standards of dithiocarbamate fungicides
(Thiram and Propineb) and organophosphate pesticides (Phorate and
Methamidophos), zofenopril calcium, arginine, asparagine, aspartic
acid, l-cysteine, cystine, dl-homocysteine, glutamine,
glutamic acid, ammonium chloride, lactic acid, magnesium sulfate,
magnesium chloride hexahydrate, sodium sulfide, sodium chloride, sodium
sulfate, sodium bicarbonate, dipotassium hydrogen phosphate, potassium
dihydrogen phosphate, citric acid, tri-sodium citrate, potassium chloride,
calcium chloride dehydrate, uric acid, d(+)-glucose, and
creatinine were obtained from Sigma-Aldrich (Steinheim, Germany). l-Glutathione (reduced), meso-2,3-dimercaptosuccinic acid, d-(−)-penicillamine, N-acetyl-l-cysteine, and captopril were obtained from Alfa Aesar (Karlsruhe,
Germany). Glycine, histidine, lysine, and valine were supplied by
Serva Electrophoresis GmbH (Heidelberg, Germany). Finally, urea (>99.5%)
was purchased from Pharmacia Biotech AB (Uppsala, Sweden) and HPLC-grade
solvent from Fischer Scientific (Loughborough, U.K.).
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2

Synthesis of Monodisperse Quantum Dots

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Copper(II) nitrate, silver nitrate (≥99.9%), sodium borohydride (99.99%), 16mercaptohexadecanoic acid (90%), L -glutathione (≥98%), sodium hydroxide (≥98%, pellets anhydrous), cadmium chloride (≥99.99%), tetrabutyl ammonium hydroxide solution (40% in water), sodium sulfide nonahydrate (≥98.0%), dodecanethiol (≥98%), methyl viologen dichloride hydrate (98%), ultrapure water (Chromasolv Plus, for HPLC), 2-propanol (≥99.8%), and ethanol (≥99.8%) were obtained from Sigma-Aldrich (Milan, Italy). D -Penicillamine (99%) was purchased from Alfa Aesar (Karlsruhe, Germany). All glassware was washed with aqua regia and rinsed with ultrapure water.
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