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Methylammonium chloride macl

Manufactured by Xi'an Yuri Solar Co.
Sourced in China

Methylammonium chloride (MACl) is a white crystalline solid that serves as a key precursor material in the production of perovskite solar cells. It is an essential component in the fabrication of high-performance photovoltaic devices.

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8 protocols using methylammonium chloride macl

1

Perovskite Solar Cell Fabrication

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Methylammonium iodide (MAI), formamidinium iodide (FAI), methylammonium bromide (MABr) and TiO2 paste (30 NR-D) were ordered from Greatcell Solar, Ltd, Australia. PbI2 (99.999%) and dimethylformamide (DMF) were purchased from Alfa Aesar, UK. CsI (99.999%), dimethylsulfoxide (DMSO), chlorobenzene, titanium isopropoxide, 4-tert-butylpyridine (tBP) and bis(trifluoromethylsulfonyl)imide lithium salt (Li-TFSI) were purchased from Sigma–Aldrich, Ltd, USA. Methylammonium chloride (MACl) and PbBr2 (99.98%) were purchased from Xi’an Polymer Light Technology Corp, China. Spiro-OMeTAD was purchased from Taiwan Lumtec, Ltd, China.
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2

Comprehensive Perovskite Solar Cell Materials

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DMF (99.8%), DMSO (99.7%), isopropanol (IPA; 99.7%), chlorobenzene (CB; 99.8%), acetonitrile (ACN; 99.8%), 4-tert-butyl pyridine (98%), lithium bis(trifluoromethanesulfonyl)imide (Li-TFSI; 99.95%), tris(2-(1H-pyrazol-1-yl)-4-tert-butylpyridine)cobalt(III) tri[bis(trifluoromethane)sulfonimide] [FK 209 Co(III) TFSI salt], and PbI2 (99.999%, perovskite grade) were purchased from Sigma-Aldrich. PbBr2 (99.999%), CsI (99.998%), deionized water, and SnO2 colloidal solution (15% in water) were purchased from Alfa Aesar. Formamidine iodide (FAI), formamidine bromide (FABr), methylammonium iodide (MAI), methylammonium bromide (MABr), and n-octylammonium iodide (OAI) were purchased from GreatCell Solar Materials (Australia). Methylammonium chloride (MACl) and Spiro-OMeTAD (99.8%) were purchased from Xi’an Polymer Light Technology (China). All the materials were used without further purification.
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3

Synthesis of Perovskite Solar Cell Materials

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The SnO2 colloidal dispersion in H2O (tin (IV) oxide, 15 wt%) was purchased from Alfa Aesar. The lead iodide (PbI2) (> 99.99%), FAI (≥ 99.5%), MAI (≥ 99.5%), methylammonium chloride (MACl) (> 99.5%), spiro-OMeTAD (≥ 99.8%), LiTFSI (> 99%), TBP (> 96%) and PEAI (≥ 99.5%) were purchased from Xi’an Polymer Light Technology Corp. (China). The 1,4-DITFB (97%) was obtained from Macklin. The N,N-dimethylformamide (DMF, 99.9%) and dimethyl sulfoxide (DMSO, 99%) were obtained from J&K Scientific. The isopropanol (IPA, ≥ 99.7%) was purchased from Sinopharm Chemical Reagent Co., Ltd.
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4

Perovskite Solar Cell Fabrication

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BHC, PHC, THC, PTAA (average Mn, 7000 to 10,000), BCP, lead iodide (PbI2, 99.999% trace metals), dimethyl sulfoxide (DMSO), L-α-phosphatidylcholine (LP), 2-ME, and toluene were purchased from Sigma-Aldrich and used without further purification. C60 was purchased from Nano-C Inc. MAI, FAI, 4-fluoro-phenylammonium iodide (p-F-PEAI) and n-dodecylammonium iodide were purchased from GreatCell Solar. Methylammonium chloride (MACl) was purchased from Xi’an Polymer Light Technology Corp.
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5

Perovskite Precursor Material Synthesis

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Dimethyl sulfoxide (DMSO), dimethylformamide (DMF), lead acetate trihydrate (PbAc 2 Á3H 2 O), lead bromide (PbBr 2 ), lead iodide (PbI 2 ), chlorobenzene (CB), tert-butanol (t-BuOH) and ethanol were purchased from Sigma-Aldrich. Formamidinium iodide (FAI), n-octylammonium iodide (OAI) and methylammonium bromide (MABr) were purchased from Greatcell Solar Materials. Tin oxide (SnO 2 ) nanoparticle water solution was from Alfa Aesar. Poly (3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS, AI 4083) was from Heraeus. Methylammonium chloride (MACl) was from Xi'an Polymer Light Technology. All materials above were used without further purification.
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6

Perovskite Solar Cell Fabrication

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The SnO2 colloid precursor (tin oxide, 15% in H2O colloidal dispersion) was purchased from Alfa Aesar. PbI2 (99.8%) was purchased from Kanto Chemical. Dimethyl sulfoxide (DMSO 99.8%), chlorobenzene (99.8%), N, N-dimethylformamide (DMF, 99.8%), and isopropanol (IPA, 99.8%) were obtained from Sigma-Aldrich. Lithium bis(trifluoromethylsulfonyl) imide (Li-TFSI, 95%), 4-tert-butylpyridine (TBP, 96%), and 2,2′,7,7′-tetrakis-(N, N-di-p-methoxyphenylamine)-9,9′-spirobifluorene (Spiro-OMeTAD, 99%) were purchased from Lumtec. Formamidinium iodide [CH(NH2)2I] and methylammonium iodide (CH3NH3I) were obtained from Dysel. Methylammonium chloride (MACl) was purchased from Xi’an Polymer Light Technology. All chemicals and reagents were used without further purification.
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7

Perovskite Solar Cells Material Synthesis

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All the chemicals were purchased from commercial businesses without further purification: Formamidinium iodide (FAI) (98%, Greatcell Solar Materials Pty Ltd), Lead iodide (PbI2) (99.99%, Zhejiang Yitai Technology Co., Ltd.), Urea (99.999%, Aladdin), Bathocuproine (BCP) (> 99.0%, TCI), Fullerene (C60) (99.9%, Tanfeng Tech. Inc.), and Copper particle (Cu) (99.999%, Fuzhou Yingfeixun Photoelectric Technology Co., Ltd). Isopropanol (IPA) was purchased from Sigma-Aldrich. Cesium bromide (CsBr) (99.9%) and methylammonium chloride (MACl) (99.5%) were purchased from Xi’an Polymer Light Technology in China. All the materials are stored in the nitrogen-filled glove box to avoid the water.
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8

Fabrication of Perovskite Solar Cells

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The modified PEDOT:PSS (m-PEDOT:PSS) solution is a mix of normal PEDOT:PSS (AI 4083) aqueous solution and 100 mg ml−1 PSS-Na (Sigma Aldrich) aqueous solution by a volume ratio of 6:5. TOPO, PbBr2, dimethyl sulfoxide (DMSO) and chlorobenzene (CB) were purchased from Sigma Aldrich. 2,2’,2”-(1,3,5-Benzinetriyl)- tris(1-phenyl-1-H-benzimidazole) (TPBi) and formamidinium bromide (FABr) and methylammonium chloride (MACl) were purchased from Xi’an Polymer Light Technology Corp. Phenylethylammonium bromide (PEABr) was purchased from Dyesol (now Greatcell Solar).
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