PCDTBT (Mn = 36 kDa and Mw = 110 kDa) and PC71BM (>99%) were purchased from PCAS Canada Inc. and Nano-C, respectively, and used without any further purification. ZnO nanoparticles were prepared according to previous reports.25 (link) Molybdenum oxide (MoO3) (>99.5%) was purchased from Sigma-Aldrich and used with no further purification. The carbazole SiPc based derivative was synthesized according to Fig. 1 .
Molybdenum oxide moo3
Manufactured by Merck Group
Sourced in United States
Molybdenum oxide (MoO3) is a chemical compound that is a key component in various laboratory equipment. It serves as a catalyst, oxidizing agent, and refractory material. Molybdenum oxide possesses a high melting point and is commonly used in high-temperature applications. Its core function is to provide specific chemical and physical properties required for various laboratory applications.
Automatically generated - may contain errors
Lab products found in correlation
Sodium chloride (nacl), by Fujifilm (1 mentions)
Ingenuity pathway analysis (ipa), by Fujifilm (1 mentions)
Silver nitrate agno3, by Merck Group (1 mentions)
Zinc oxide, by Merck Group (1 mentions)
1 2 dichlorobenzene, by Merck Group (1 mentions)
Chlorobenzene, by Merck Group (1 mentions)
1 3 5 trimethylbenzene tmb, by Merck Group (1 mentions)
Toluene, by Merck Group (1 mentions)
6 protocols using molybdenum oxide moo3
1
Organic Photovoltaic Device Fabrication
2
Synthesis of Metal Nanostructures
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Silver
nitrate (AgNO3, Sigma-Aldrich), ethylene glycol (EG, Wako),
1,2-dodecanediol
(DD, TCI), sodium chloride (NaCl, Wako), iron(III) nitrate nonahydrate
[Fe(NO3)3, Wako], ammonia solution (28% NH4OH, Wako), acetic acid (AcOH, Wako), IPA (Wako), CBP (Lumtec),
and molybdenum oxide (MoO3, Sigma-Aldrich) were used as
received.
nitrate (AgNO3, Sigma-Aldrich), ethylene glycol (EG, Wako),
1,2-dodecanediol
(DD, TCI), sodium chloride (NaCl, Wako), iron(III) nitrate nonahydrate
[Fe(NO3)3, Wako], ammonia solution (28% NH4OH, Wako), acetic acid (AcOH, Wako), IPA (Wako), CBP (Lumtec),
and molybdenum oxide (MoO3, Sigma-Aldrich) were used as
received.
3
Aqueous Solution Processing of Doped ZnO for Optoelectronics
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All the materials, zinc oxide (99.9%, Sigma-Aldrich, Saint Louis, MI, USA), ammonia solution (≥28%, NH3 in H2O, Aladdin, Hamden, CT, USA), poly(3-hexylthiophene) (P3HT, BASF), phenyl-C61-butyric acid methyl ester (PC61BM, 98%, Nano-C, Westwood, MA, USA), poly({4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl}{3-fluoro-2-[(2-ethylhexy)carbonyl]thieno[3,4-b]thiophenediyl}) (PTB-7, 1-material), [6,6]-phenyl-C71-butyric acid methyl ester (PC71BM, 99%, Nano-C), 1,8-diiodooctane (DIO, 98%, Sigma-Aldrich), 1,2-dichlorobenzene (99%, Sigma-Aldrich), chlorobenzene (99.8%, Sigma-Aldrich), molybdenum oxide (MoO3, 99.98%, Sigma-Aldrich) are used as received without further purification.
For the low-temperature aqueous solution processing, ZnO solution was obtained by ZnO powder directly dissolved in ammonia solution (8 mg/mL). For Al-doped-ZnO (AZO), Al was added into well prepared ZnO solution with different immersion times.
For the low-temperature aqueous solution processing, ZnO solution was obtained by ZnO powder directly dissolved in ammonia solution (8 mg/mL). For Al-doped-ZnO (AZO), Al was added into well prepared ZnO solution with different immersion times.
4
Organic Photovoltaic Device Fabrication
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P3HT was purchased from Rieke metals (4002-E,
molecular weight 50–70 kDa, regioregularity 91–94%,
and polydispersity index 2–2.5). PC61BM was purchased
from Nano-C and used without any further purification. Bis(tri-n-butyl
silyl oxide) silicon phthalocyanine 3(BS)2-SiPc) was synthesized
according to previous reports.36 (link) Zinc oxide
(ZnO) nanoparticle solution was used for the electron transport interlayer
and prepared according to our previous report.41 (link) Molybdenum oxide (MoO3) (>99.5%) was purchased
from Sigma-Aldrich and used as received for the hole transport layer.
1,2-Dichlorobenzene (o-DCB), o-xylene, 1,3,5-trimethylbenzene (TMB),
and toluene were purchased from Sigma-Aldrich.
molecular weight 50–70 kDa, regioregularity 91–94%,
and polydispersity index 2–2.5). PC61BM was purchased
from Nano-C and used without any further purification. Bis(tri-n-butyl
silyl oxide) silicon phthalocyanine 3(BS)2-SiPc) was synthesized
according to previous reports.36 (link) Zinc oxide
(ZnO) nanoparticle solution was used for the electron transport interlayer
and prepared according to our previous report.41 (link) Molybdenum oxide (MoO3) (>99.5%) was purchased
from Sigma-Aldrich and used as received for the hole transport layer.
1,2-Dichlorobenzene (o-DCB), o-xylene, 1,3,5-trimethylbenzene (TMB),
and toluene were purchased from Sigma-Aldrich.
5
Evaporated Organic Solar Cell Fabrication
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Devices were prepared by vacuum thermal evaporation in a high‐vacuum system with a base pressure of <10−7 mbar (Kurt J. Lesker Ltd.). All layers of materials were evaporated onto a glass substrate with a pre‐structured ITO contact (Thin Film devices), cleaned in subsequent ultrasonic baths with N‐methyl‐2‐pyrrolidone, deionized water, and ethanol and ultraviolet ozone cleaning system. Prior to evaporation, all organic materials were purified by vacuum gradient sublimation. Metal contacts were deposited through a shadow mask, to form a top contact and overlap with the bottom ITO contact, thus defining the device area of 6.44 mm2. To avoid degradation due to external conditions, all devices were encapsulated with a glass cavity glued on the substrate together with a moisture getter.
All provided materials were tested as donors against C60 fullerene acceptor (CreaPhys GmbH), incorporated in a p‐i‐n (standard) device architecture, using molybdenum oxide (MoO3) (Sigma Aldrich) and bathophenanthroline (BPhen) (Lumtec), as hole‐ and electron‐transporting layers (HTL and ETL), respectively. The structure of a complete device is:
Numbers in brackets represent the thicknesses in nm of the respective layer.
All provided materials were tested as donors against C60 fullerene acceptor (CreaPhys GmbH), incorporated in a p‐i‐n (standard) device architecture, using molybdenum oxide (MoO3) (Sigma Aldrich) and bathophenanthroline (BPhen) (Lumtec), as hole‐ and electron‐transporting layers (HTL and ETL), respectively. The structure of a complete device is:
Numbers in brackets represent the thicknesses in nm of the respective layer.
6
Fabrication of Quantum Dot Optoelectronics
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The ITO glass substrates were purchased from China Southern Glass Holding Corp. (Shenzhen, China) with sheet resistance around 17 Ω/sq. ZnO and ZnMgO nanoparticle solution was purchased from Guangdong Poly OptoElectronics Corp. (Jiangmen, China), with a concentration of 20 mg/mL in ethanol. The indium phosphide quantum dots (InP QDs) were purchased from Suzhou Xingshuo Nanotech Corp. (Suzhou, China), with the concentration of 25 mg/mL in normal octane. The 4,4′,4′′-tris(carbazol-9-yl) triphenylamine (TCTA) was purchased from Jilin OLED Material Tech Corp. (Changchun, China). The molybdenum oxide (MoO3) was purchased from Sigma Aldrich (St. Louis, MO, USA).
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