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3 protocols using potassium peroxodisulfate

1

Synthesis of NIPMAm-Based Microgels

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N-Isopropyl methacrylamide (NIPMAm, purity 97%) was purchased from Sigma-Aldrich and used as received. N,N′-Methylenebis(acrylamide) (BIS, 97%), sodium dodecyl sulfate (SDS, 95%), and potassium peroxodisulfate (KPS, 95%) were purchased from FUJIFILM Wako Pure Chemical Corporation (Japan) and used as received. Fluorosurf® was purchased from Fluoro Technology (Japan). Distilled ion-exchanged water used in the preparation of the microgels was obtained from EYELA, SA-2100E1.
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2

Synthesis and Characterization of Polymeric Microspheres

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2-Methoxyethyl acrylate (MEA, purity 98%),
styrene (St, 99%), butyl acrylate (BA, 99%), potassium peroxodisulfate
(KPS, 95%), sodium dodecyl sulfate (SDS, 95%), disodium hydrogenphosphate
(99%), eosin Y (EoY, 95%), phloxine B (PhB, 98%), erythrosine (Ery,
95%), rose bengal (RB, 95%), orange II (OrII, 98%), tartrazine (Ttz,
98%), and ethanol (EtOH, 99.5%) were purchased from Wako Pure Chemical
Industries and used as received. 2-(2-Ethoxyethoxy) ethyl acrylate
(ET2A, 98%), 4-methoxystyrene (MSt, 98%), N-isopropylacrylamide
(NIPAm, 98%), and N,N′-methylenebis(acrylamide)
(BIS, 97%) were purchased from Tokyo Chemical Industry and used as
received. 2-(2-Methoxyetoxy) ethyl acrylate (ME2A, 95%) was purchased
from Monomer-Polymer and Dajac Labs, Inc. 2-[2-(2-Methoxyethoxy)ethoxy]ethyl
acrylate (Me3A, 98%) was kindly donated by Kyoeisha Chemical Co.,
Ltd. The cross-linker, ethylene glycol dimethacrylate (EGDMA, 98%),
was purchased from Sigma-Aldrich and used as received. Water used
for microsphere preparations was distilled and then ion-exchanged
(EYELA, SA-2100E1).
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3

Zirconium-based Polymer Composite Synthesis

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Styrene monomer, p-styrenesulfonic acid sodium salt (NaPSS), potassium peroxodisulfate (KPS), potassium hydroxide (KOH), potassium dihydrogen phosphate (KH2PO4), zirconyl chloride octahydrate (ZrOCl2·8H2O), rhodamine B (RhB), ethylene glycol (EG), ethanol, and acetone were purchased from FUJIFILM Wako Pure Chemical Corp. 1-Butanol solution (ca. 80%) of zirconium(iv) tetrabutoxide (Zr(OBu)4) was purchased from Tokyo Chemical Industry Co., Ltd. All of the chemical reagents and ultrapure water (18.2 MΩ cm) were used without further purification.
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