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2 protocols using zirconium nitrate pentahydrate

1

Synthesis of Metal Oxide Nanostructures

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Cerium nitrate hexahydrate (AR, 99%) and zirconium nitrate pentahydrate (AR, 99%) were purchased from Macklin Biochemical Co., Ltd. (Shanghai, China). Iron nitrate nonahydrate (AR, ≥98.5%), cobalt nitrate hexahydrate (AR, ≥99%), nickel nitrate hexahydrate (AR, 98%), cupric nitrate trihydrate (AR, 99%), zinc nitrate hexahydrate (AR, 99%), glycerol (ACS, ≥99.5%), and tetraethylene glycol (AR, 99%) were supplied by Aladdin Chemistry Co., Ltd. (Shanghai, China). Acetonitrile (AR, 99%) and ethanol (AR, 99%) were obtained from Sinopharm Chemical Reagent Co., Ltd. (Beijing, China). Other reagents were of analytical grade and all of the reagents were used as received without further purification.
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2

Synthesis of Hierarchical Mesoporous Silicas

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All reagents were utilized as received without undergoing additional purification. Hierarchically mesoporous silicas (HMS), MCM-41, KIT-6, and SiO2-70 Å (pore size 70 Å), were purchased from Jiangsu XFNANO Nano Materials Tech Co., Ltd. (Jiangsu, China). Zirconium nitrate pentahydrate (Zr(NO3)4·5H2O), sodium nitrate (NaNO3), ferric nitrate nonahydrate(Fe(NO3)3·9H2O), silver nitrate (AgNO3), strontium nitrate (Sr(NO3)2), caesium nitrate (CsNO3), barium nitrate (Ba(NO3)2), lanthanum nitrate hexahydrate (La(NO3)3·6H2O), cerium nitrate hexahydrate (Ce(NO3)3·6H2O), neodymium nitrate hexahydrate (Nd(NO3)3·6H2O), samarium nitrate hexahydrate (Sm(NO3)3·6H2O), and europium nitrate hexahydrate (Eu(NO3)3·6H2O) were purchased from Macklin. HNO3 (68 wt%) was purchased from Sinopharm Chemical Reagent Co., Ltd (Beijing, China). with the grade of A.R.
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