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14 protocols using methyl orange

1

Synthesis and Characterization of Metal-Organic Complexes

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l-Aspartic acid and l-glutamic acid were obtained from Sigma-Aldrich. Neutral red, methyl orange, methylene blue, CuCl2·2H2O, and Na2S were purchased from Alfa Aesar. Finally, 35 wt% hydrogen peroxide was purchased from VWR. All chemicals were used as received without further purification. Milli-Q water (18 MΩ cm) was used for all experiments.
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2

Synthesis and Characterization of Gold Nanoparticles

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Gold(III) chloride trihydrate (520918), Bovine Serum Albumins (BSA, A2058), and Rhodamine 6G (R6G, R4127) were purchased from Sigma-Aldrich (Haverhill, UK). Iron(III) chloride, hexahydrate (FeCl3·6H2O, A16231), l-(+)-Ascorbic acid (A15613), and methyl orange (17874) were purchased from Alfa Aesar (Heysham, UK)). Sodium borohydride (NaBH4, 10599010), nitric acid (70%, UN2031), and hydrochloric acid (37%, UN1789) were purchased from Fisher Scientific (Loughborough, UK). All chemicals were used without further purification. Milli-Q water (18.2 MΩ) was used in all experiments.
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3

Synthesis and Characterization of Dye-Loaded Nanocomposites

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The chemicals
were of analytical
reagent grade and used without further purification. FeCl3·6H2O, FeCl2·4H2O, and
urea were purchased from Sigma-Aldrich. Al(NO3)3·6H2O, Mg(NO3)2·6H2O, NaOH, and ethylene glycol were purchased from Merck. Polyethylene
glycols (PEG) with different molecular weights (1.5, 2.0, 4.0, and
6.0 k) were purchased from Loba Chemie. Methyl orange, acid blue 113,
acid blue 147, and Nile blue A were purchased from Alfa Aesar. The
stock solution for all the experiments was prepared using double distilled
(DD) water.
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4

Synthesis and Characterization of Nanomaterials

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Zinc nitrate (98%), sodium
hydroxide (98%), nickel nitrate (98%), sodium borohydride (98%), rhodamine
B, methyl orange, methylene blue, 4-nitrophenol (99%), 2-nitrophenol
(98%), and 2-nitroaniline (98%) were purchased from Alfa Aesar, and
silver nitrate (>99.5%) was bought from Merck. These materials
were
utilized as precursors without further purification. Deionized water
was used for the preparation of solutions and in all the experiments.
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5

Laser Synthesis of Metal Oxide Nanoparticles

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Iron (III) oxide, Nickel (II) oxide, Cobalt (II) oxide, Methyl Orange and Methylene blue are from Alfa Aesar (China), and Methyl blue is from Sigma-Aldrich (China). All chemicals are of analytical grade. All solutions are prepared with deionized water. The laser irradiation in liquid technique has been reported in our previous works18 19 20 21 (link)22 (link)23 (link)24 25 (link)26 . In this case, 5 mg metal oxide nanoparticles powder with a purity of 99.99% is firstly placed in a glass bottle filled with 10 ml of deionized water. Magnetically-stirred operation is to make the powder monodisperse in water. Then, the aqueous solution is irradiated by a Q-switched Nd:YAG laser device with a wavelength of 532 nm, repeating frequency of 10 Hz, pulse width of 10 ns, energy density of 400 mJ/pulse and spot size of 4 mm in diameter. During laser irradiating, the liquid environment is maintained at ambient temperature and pressure. The laser irradiation process lasts for 30 min. Then, the colloidal solution is synthesized and then collected in a cuvette for measurements.
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6

Preparation of Pure Titanium Sheets

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Pure Ti sheets (purity 99.99%) were purchased from China New Metal Materials Technology Co., Ltd. H2O2 solution (30 wt.%) was purchased from Chinese Medicine Group Chemical Reagent Co., Ltd. Methyl orange was purchased from Alfa Aesar (China) Chemicals.
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7

Versatile Polymer-Mediated Nanocomposites

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N-Isopropylacrylamide (NIPAM, 97% Sigma-Aldrich) and 2-acrylamido-2-methylpropane sulfonic acid (AMPS, 99% Sigma-Aldrich) were used as monomers, N,N′-methylene-bis-acrylamide (MBA, 99% Sigma-Aldrich) was used as a crosslinker. Ammonium per sulfate (APS, 98% Sigma-Aldrich) was used as an initiator and sodium dodecyl sulfate (SDS, ≥98.5% BDH Chemicals) was used as a surfactant. Silver nitrate (AgNO3, 99% Sigma-Aldrich) was used as a metal precursor. Sodium borohydride (NaBH4, 98% Sigma-Aldrich) was employed as a reducing agent. 4-Nitrophenol (4-NP, 99% Sigma-Aldrich), 2-nitrophenol (2-NP, 98% Sigma-Aldrich), 2-nitroaniline (2-NA, 98% Sigma-Aldrich), methyl orange (MO, 85% Alpha Aesar), Methylene Blue (MB 82% Alpha Aesar), Eosin Y (EY, 82% Alpha Aesar) were used for catalytic degradation. Deionized water was prepared in the laboratory and used throughout this work.
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8

Synthesis and Characterization of Metal-Dye Complexes

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The chemicals in this study
were used as received and without any further purification. Aluminum
nitrate nonahydrate Al(NO3)3·9H2O was provided by BDH. Nickel nitrate hexahydrate Ni(NO3)2·6H2O and ethanol absolute were purchased
from Sigma-Aldrich. Propylene oxide (noted PO; CH3CHCH2O), orange II (noted OII, C16H11N2NaO4S), methyl orange (noted MO, C14H14N3NaO3S), Congo Red (noted CR,
C32H22N6Na2O6S2), methylene blue (noted MB, C16H18ClN3xH2O), rhodamine
B (noted rhB, C28H31ClN2O3), and rhodamine 6G (noted rh6G, C28H31N2O3Cl) were provided by Acros. Acetone was purchased
from Scharlau Chemie S.A. Double distilled water was obtained from
our laboratory.
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9

Photochemical Oxidation of Carvacrol and Thymol

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Carvacrol (1), thymol (2), Trolox and K2S2O8 were purchased from Aldrich. Methyl orange (MO) was purchased from Acros Organics. CRYSMEB (DS = 4.9) was provided from Roquette Frères (Lestrem, France), α-CD, β-CD, γ-CD, HP-β-CD (DS = 5.6) and RAMEB (DS = 12.6) were purchased from Wacker-Chemie (Lyon, France). All products were of analytical grade and were used as received. Distilled deionized water was used all over the study.
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10

Cyclodextrin complexation of plant phenolics

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trans-Anethole (99%) and 2,2-diphenyl-1-picrylhydrazyl were purchased from Aldrich. Estragole (analytical standard) was provided by Fluka Chemicals. Isoeugenol (99%), eugenol (99%), p-coumaric acid (≥98%), caffeic acid (≥98%), ferulic acid (99%) and methyl orange (MO) were purchased from Acros Organics. α-CD, β-CD, HP-β-CD (DS = 5.6) and RAMEB (DS = 12.6) were purchased from Wacker-Chemie (Lyon, France). CRYSMEB (DS = 4.9) was provided from Roquette Frères (Lestrem, France). Distilled deionized water was used throughout this work.
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