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4 protocols using butyl methacrylate

1

Preparation of Functionalized Graphene Oxide

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Tryptone and yeast extract were purchased from Suzhou Biogene Biotechnology Co.,Ltd. Graphite powder, sulfuric acid (H2SO4), hydrochloric acid (HCl), hydrogen peroxide (H2O2), dimethylacetamide (DMAC), triethylamine (TEA), methacryloyl chloride (MAC), azobisisobutyronitrile (AIBN), methacrylic acid (MAA), butyl methacrylate (BMA), N-hydroxy succinimide (NHS), N,N’-Dicyclohexylcarbodiimide (DCC), 4-dimethylaminopyridine (DMAP), cyclohexanone, petroleum ether, ether and inorganic salts were all in analytical reagent grade were commercially obtained from Sinopharm Chemical Reagent Co.,Ltd. and used as received without further treatment. HPLC grade methanol was purchased from Shanghai Qiangshun Chemical Reagent Co.,Ltd. HPLC grade DMF was obtained from Tedia Company Inc.
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2

Emulsion Polymerization of Acrylate Monomers

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Styrene (St), methyl methacrylate (MMA), n-butyl acrylate (BA), butyl methacrylate (MBA), initiator potassium persulfate (KPS), and sodium bicarbonate (NaHCO3) were purchased from Sinopharm Group Chemical Reagent Co. LTD (Shanghai, China) at reagent grade. Emulsifiers, sodium dodecyl benzene sulfonate (SDS) and alkylphenol polyoxyethylene ether (OP-10), were available from Aladdin (Shanghai, China) and Tianjin Photonics Reagent Co. LTD (Tianjin, China), respectively. Deionized water (DDI) was used in all experiments. All the chemicals were used directly without further purification.
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3

Synthesis of Polymer-Coated Copper Meshes

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The copper meshes with different mesh sizes were commercially available. Tryptone and yeast extract were commercially get from Suzhou Biogene Biotechnology Co., Ltd. Graphite flake, methacryloyl chloride (MAC), meth acrylic acid (MAA), butyl methacrylate (BMA) was purchased from Sinopharm Chemical Reagent Co., Ltd, and can be used directly without no further processing. HPLC grade methanol was purchased from Shanghai Qiangshun Chemical Reagent Co., Ltd.
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4

Synthesis and Characterization of MVMQ-based Flame Retardant Coatings

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Methylvinyl MQ silicone resin (MVMQ) with a vinyl group content of 0.08 mol/100 g was obtained from Dayi Chemical Industry Co., Ltd. (Yantai, China), the mole ratio of M:Q is 0.8:1. Methyl methacrylate, butyl methacrylate, isopropanol, and 2,2′-azobis(2-methylpropionitrile) (AIBN) were purchased from Sinopharm Chemical Reagent Co., Ltd. (Shanghai, China). Phenylmethylsilicone oil (PSO) with a viscosity of 30 mPa·s was obtained from CINDA Chemical Co., Ltd. (Bengbu, China). Acetone, toluene, xylene, ethanol, and acetylacetonate were supplied by Yongda Chemical Reagent Company (Tianjin, China). The compound 2-hydroxyethyl methacrylate phosphate (HEMAP) was supplied by YINCHANG XINCAI Company (Shanghai, China). The above chemicals were used for synthesis and related coating preparation, which were applied as received without any further purification. In addition, the commercial silicone resin was used for preparing the control FR coating, including the following raw materials: 10,000 mPa·s of hydroxyl-terminated polydimethylsiloxane (PDMS) from Dayi Chemical Industry Co., Ltd., tetraethylorthosilicate (TEOS) from Kemiou Chemical Co., Ltd. (Tianjin, China), and bismuth neodecanoate (BiND) from Deyin Chemical Co., Ltd. (Shanghai, China).
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