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2 protocols using sodium nitrate

1

Synthesis and Characterization of Cerium Nanoparticles

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Lithium chloride (LiCl) (ultra dry, 99.995% (metals basis)) and lithium bromide (LiBr) (anhydrous, 99.99% (metals basis)) have been obtained from Alfa Aesar (Ward Hill, MA). 2′-deoxyguanosine 5′-monophosphate (5′-dGMP) has been obtained from Sigma-Aldrich (St Louis, MO). Potassium persulfate (crystal) and sodium nitrate have been purchased from Mallinckrodt, Inc. (Paris, KY). All compounds were used without further purification. We chose to use CNPs generated from cerium chloride and cerium nitrate for our ESR spectral studies.
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2

Synthesis and Characterization of Europium and Gadolinium Doped Mesoporous Silica Nanoparticles

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98% Tetraethyl orthosilicate (TEOS), (3-Glycidyloxypropyl) trimethoxysilane (GPTMS), ethylenediamine (EDA), 98% Hexadecyl trimethyl ammonium bromide (CTAB), mannose, fucose, glucose, galactose, xylose, McCoy’5A medium and thiazolyl blue tetrazolium bromide (MTT) were purchased from Sigma-Aldrich; 99.9% Europium (III) chloride hexahydrate (EuCl3·6H2O) and 99.9% Gadolinium (III) chloride hexahydrate (GdCl3·6H2O) were purchased from Alfa Aesar; Sodium hydroxide (NaOH), Ethanol (C2H5OH), calcium chloride (CaCl2), barium chloride (BaCl2), gelatin, hydrochloric acid (HCl), sodium sulfate (Na2SO4), trifluoroacetic acid (TFA), 1-Phenyl-3-methyl-5-pyrazolone (PMP), methanol (CH3OH), chloroform (CHCl3), acetonitrile (ACN), sodium nitrate (NaNO3), sodium hydrogen phosphate (Na2HPO4), sodium chloride (NaCl), potassium dihydrogen phosphate (KH2PO4) and dimethyl sulfoxide (DMSO) were purchased from J.T. Baker; potassium chloride (KCl) were purchased from Mallinckrodt Chemical; minimum essential medium (MEM) were purchased from Biowes; fetal bovine serum (FBS), non-essential amino acids (NEAA), antibiotic–antimycotic (AA) and trypsin were purchased Gibco; mouse fibroblasts cell (L929) and human colorectal carcinoma cells (HCT116) were purchased ATCC; Sargassum aquifolium from Kenting-Chuanfan Rock.
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