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4 protocols using furfuryl alcohol

1

Synthesis and Characterization of Furan-Based Monomers

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All reagents were commercially available materials and were used without further purification. Maleic anhydride (≥98%) and dibutyltin dilaurate (95%) were provided by Alfa Aesar (Haverhill, MA, USA). Furan (≥99%) was obtained from Fluka. Hydroquinone (≥99%), 2-hydroxypropyl acrylate (HPA) (mixture of the isomers, 95%), 2-hydroxyethyl methacrylate (HEMA) (97%), hexamethylene diisocyanate (for synthesis), polyethylene glycol PEG 1000 (for synthesis), and 2-hydroxypropyl methacrylate (HPMA) (mixture of hydroxypropyl and 2-hydroxypropyl methacrylates, ≥97%) were purchased from Sigma-Aldrich (Steinheim am Albuch, Germany). Furfuryl alcohol (98%) and isophorone diisocyanate (98%) were provided by Acros Organics (Geel, Belgium). 2-hydroxyethyl acrylate (HEA) was kindly donated by Cognis Performance Chemicals (Hythe, UK). Chempur (Piekary Śląskie, Poland) provided analytical-grade ethanolamine and triethanolamine. Diethyl ether (99.5%) and anhydrous ethanol p.a. (99.8%) were provided by Avantor Performance Materials Poland S.A. (POCH, Gliwice, Poland). Acetone, isopropanol, xylene, toluene, and dichloromethane of high purity were purchased from StanLab (Lublin, Poland).
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2

Mimosa Tannin Extract Powder Functionalization

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Spray-dried mimosa tannin (Acacia mearnsii formerly mollissima, de Wildt) extract powder was supplied by Silva Chimica (St. Michele Mondovi’, Italy). Furfuryl alcohol and lauroyl chloride were purchased from Acros Organics (Geel, Belgium). Para-toluene-sulphonic acid (pTSA), diethyl ether, acetaldehyde, and glutaraldehyde were purchased from Sigma-Aldrich (St. Louis, MO, USA). Formaldehyde was provided by Merck-Schuchardt OHG (Hohenbrunn, Germany). Oleoyl chloride and palmitoyl chloride were acquired from Alfa Aesar (Kandal, Germany). Chloroform was obtained from Merck (Darmstadt, Germany).
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3

Synthesis of Functionalized Alcohols

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All starting materials were used without further purification. Pluronic F-127, vanadyl acetylacetonate (98%, VO(acac) 2 ), and ethanol ( p.a.), were purchased from Sigma Aldrich. Benzyl alcohol (BzOH, 99%), furfuryl alcohol (99%), 1-dodecanol (98%) and triethylamine were obtained from Acros Organics.
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4

Lignin-based Tannin-Furfuryl Composite

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The commercial tannin acid (95 %), furfuryl alcohol (98%), surfactant (Tween 85) used in the experiments were ordered from Acros Organic. Catalyst, para- toluene sulfonic acid monohydrate (PTSA), and blowing agent (n-pentane) were ordered from Merck Company. Three types of lignin LBS (Lignoboost Kraft lignin) extractions from softwood (pine and spruce), LBD (Lignoboost kraft) extractions from pine wood, and LBHT (Lignoboost hydrothermal lignin) were obtained from pulping mills.
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