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Quantum yield spectrometer c11347 quantaurus qy

Manufactured by Hamamatsu Photonics

The Quantum yield spectrometer C11347 Quantaurus QY is a laboratory instrument designed to measure the quantum yield of fluorescent samples. It utilizes an integrating sphere to capture the total light emission from a sample, allowing for accurate and reliable quantum yield measurements.

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2 protocols using quantum yield spectrometer c11347 quantaurus qy

1

Comprehensive Analytical Characterization Protocol

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All chemicals were purchased from J&K Chemistry, Sigma-Aldrich and TCI, and used directly without further purification. Cells were obtained from the American Type Culture Collection.
1H NMR and 13C NMR spectra were recorded with a Bruker ARX 400 NMR spectrometer. High-resolution mass spectra (HRMS) were recorded on a GCT premier CAB048 mass spectrometer operating in a MALDI-TOF mode. UV-Vis absorption spectra were recorded on a PerkinElmer Lambda 365 Spectrophotometer. Photoluminescence (PL) spectra were recorded on a Fluorolog®-3 Spectrofluorometer. The absolute fluorescence quantum yield was measured using a Hamamatsu quantum yield spectrometer C11347 Quantaurus QY. The lifetime was measured on an Edinburgh FLS980 fluorescence spectrophotometer equipped with a xenon arc lamp (Xe900). Single crystal X-ray diffraction was performed on a D/max-2550 PC X-ray diffractometer (XRD; Rigaku, Cu-Kα radiation). The crystal data were collected on an Oxford Diffraction Xcalibur Atlas Gemini ultra instrument. The scanning electron microscope image was taken using a JSM-6390 scanning electron microscope. The fluorescence images were taken by confocal laser scanning microscope (CLSM) (Zeiss, Germany).
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2

Characterization of Copper(I) Complexes

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General. 1 H, 13 C and 31 P NMR spectra were recorded at room temperature using a Bruker Avance III-600, III-500 or III-400 NMR spectrometer. 1 H and 13 C NMR chemical shifts were referenced to residual solvent peaks with respect to δ(TMS) = 0 ppm and 31 P NMR chemical shifts with respect to δ(85% aqueous H 3 PO 4 ) = 0 ppm. Solution absorption and emission spectra were measured using an Agilent 8453 spectrophotometer and a Shimadzu RF-5301PC spectrofluorometer, respectively. Electrospray ionization (ESI) mass spectra were recorded on a Shimadzu LCMS-2020 instrument. Quantum yields for CH 2 Cl 2 solution and powder samples were measured using a Hamamatsu absolute photoluminescence (PL) quantum yield spectrometer C11347 Quantaurus-QY. Emission lifetimes and powder emission spectra were measured with a Hamamatsu Compact Fluorescence lifetime Spectrometer C11367 Quantaurus-Tau, using an LED light source with λ exc = 365 nm.
[Cu(MeCN) 4 ][PF 6 ] 20 and 6-Mebpy 21 were prepared following literature methods, tBu-xantphos was purchased from Strem chemicals, bpy from Apollo Scientific, 6-Brbpy from TCI, 4,4'-tBu 2 bpy from Sigma-Aldrich and Ag[PF 6 ] from Fluorochem. All chemicals were used as received.
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