1H NMR and 13C NMR spectra were recorded with a Bruker ARX 400 NMR spectrometer. High-resolution mass spectra (HRMS) were recorded on a GCT premier CAB048 mass spectrometer operating in a MALDI-TOF mode. UV-Vis absorption spectra were recorded on a PerkinElmer Lambda 365 Spectrophotometer. Photoluminescence (PL) spectra were recorded on a Fluorolog®-3 Spectrofluorometer. The absolute fluorescence quantum yield was measured using a Hamamatsu quantum yield spectrometer C11347 Quantaurus QY. The lifetime was measured on an Edinburgh FLS980 fluorescence spectrophotometer equipped with a xenon arc lamp (Xe900). Single crystal X-ray diffraction was performed on a D/max-2550 PC X-ray diffractometer (XRD; Rigaku, Cu-Kα radiation). The crystal data were collected on an Oxford Diffraction Xcalibur Atlas Gemini ultra instrument. The scanning electron microscope image was taken using a JSM-6390 scanning electron microscope. The fluorescence images were taken by confocal laser scanning microscope (CLSM) (Zeiss, Germany).
Quantum yield spectrometer c11347 quantaurus qy
The Quantum yield spectrometer C11347 Quantaurus QY is a laboratory instrument designed to measure the quantum yield of fluorescent samples. It utilizes an integrating sphere to capture the total light emission from a sample, allowing for accurate and reliable quantum yield measurements.
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Comprehensive Analytical Characterization Protocol
1H NMR and 13C NMR spectra were recorded with a Bruker ARX 400 NMR spectrometer. High-resolution mass spectra (HRMS) were recorded on a GCT premier CAB048 mass spectrometer operating in a MALDI-TOF mode. UV-Vis absorption spectra were recorded on a PerkinElmer Lambda 365 Spectrophotometer. Photoluminescence (PL) spectra were recorded on a Fluorolog®-3 Spectrofluorometer. The absolute fluorescence quantum yield was measured using a Hamamatsu quantum yield spectrometer C11347 Quantaurus QY. The lifetime was measured on an Edinburgh FLS980 fluorescence spectrophotometer equipped with a xenon arc lamp (Xe900). Single crystal X-ray diffraction was performed on a D/max-2550 PC X-ray diffractometer (XRD; Rigaku, Cu-Kα radiation). The crystal data were collected on an Oxford Diffraction Xcalibur Atlas Gemini ultra instrument. The scanning electron microscope image was taken using a JSM-6390 scanning electron microscope. The fluorescence images were taken by confocal laser scanning microscope (CLSM) (Zeiss, Germany).
Characterization of Copper(I) Complexes
[Cu(MeCN) 4 ][PF 6 ] 20 and 6-Mebpy 21 were prepared following literature methods, tBu-xantphos was purchased from Strem chemicals, bpy from Apollo Scientific, 6-Brbpy from TCI, 4,4'-tBu 2 bpy from Sigma-Aldrich and Ag[PF 6 ] from Fluorochem. All chemicals were used as received.
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