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2 protocols using isopropanol

1

Synthesis and Characterization of Furan-Based Monomers

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All reagents were commercially available materials and were used without further purification. Maleic anhydride (≥98%) and dibutyltin dilaurate (95%) were provided by Alfa Aesar (Haverhill, MA, USA). Furan (≥99%) was obtained from Fluka. Hydroquinone (≥99%), 2-hydroxypropyl acrylate (HPA) (mixture of the isomers, 95%), 2-hydroxyethyl methacrylate (HEMA) (97%), hexamethylene diisocyanate (for synthesis), polyethylene glycol PEG 1000 (for synthesis), and 2-hydroxypropyl methacrylate (HPMA) (mixture of hydroxypropyl and 2-hydroxypropyl methacrylates, ≥97%) were purchased from Sigma-Aldrich (Steinheim am Albuch, Germany). Furfuryl alcohol (98%) and isophorone diisocyanate (98%) were provided by Acros Organics (Geel, Belgium). 2-hydroxyethyl acrylate (HEA) was kindly donated by Cognis Performance Chemicals (Hythe, UK). Chempur (Piekary Śląskie, Poland) provided analytical-grade ethanolamine and triethanolamine. Diethyl ether (99.5%) and anhydrous ethanol p.a. (99.8%) were provided by Avantor Performance Materials Poland S.A. (POCH, Gliwice, Poland). Acetone, isopropanol, xylene, toluene, and dichloromethane of high purity were purchased from StanLab (Lublin, Poland).
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2

Electrochemical Characterization of Ti-Mn Alloys

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Acetone, isopropanol, and methanol were purchased from P.P.H. “STANLAB” Sp. J. (Lublin, Poland), while ethylene glycol (EG) from CHEMPUR and ammonium fluoride from ACROS ORGANICS. Technical grade Ti foils and Ti–Mn alloys with 5, 10 and 15 wt. % of manganese content were provided by HMW-Hauner Metallische Werkstoffe (Röttenbach, Germany). Deionized (DI) water with conductivity of 0.05 μS was used to prepare all aqueous solutions.
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