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Pbbr2

Manufactured by Xi'an Yuri Solar Co.
Sourced in China, United States

PbBr2 is a laboratory compound that consists of lead and bromine. It is a crystalline solid that is commonly used in various scientific applications. The core function of PbBr2 is to serve as a precursor material in the synthesis of other lead-based compounds or as a dopant in certain materials.

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10 protocols using pbbr2

1

Perovskite Solar Cell Synthesis

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Cs2CO3(99.9%), didodecyldimethylammonium bromide (DDAB,98%), toluene (ACS grade, Fisher), Octanoic acid (OTAc,98%), Formamidine acetate (FAAc, 99%), tetraoctylammonium bromide (TOAB,98%), Methyl acetate (98%), and aluminum (Al) were purchased from Sigma-Aldrich. PbBr2 (99.9%), PbCl2 (99.9%), Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) dry re-dispersible pellets (PEDOT:PSS (4083)), Poly[N,N’-bis(4-butylphenyl)-N,N’-bis(phenyl)-benzidine (Poly-TPD), 1,3,5-Tris(1-phenyl-1H-benzimidazol-2-yl)benzene(TPBi), and LiF were purchased from Xi’an Polymer Light Technology Corp.
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2

Synthesis of Lead-Halide Perovskites

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PbBr2 (99.5%) and BABr (99.5%) were purchased from Xi’an Polymer Light Technology Corp (Xi’an, China) and stored in a glovebox filled with nitrogen. Toluene was purchased from Sinopharm Chemical Reagent Co., Ltd (Beijing, China). N,N-dimethylformamide (DMF, 99.9%) was purchased from Aladdin (Beijing, China). All chemicals were used as received without additional purification.
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3

Organic Semiconductor Material Synthesis

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PVK was purchased from Sigma Aldrich. FABr, PEABr, PbBr2, and MACl were purchased from Xi’an Polymer Light Technology Corp. TPBi and LiF were purchased from Jilin Oled Material Technology Corp. DMSO and ethyl acetate were purchased from J&K Scientific Corp. All the chemical materials were directly used without any further purifications.
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4

Perovskite Solar Cell Fabrication

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Methylammonium iodide (MAI), formamidinium iodide (FAI), methylammonium bromide (MABr) and TiO2 paste (30 NR-D) were ordered from Greatcell Solar, Ltd, Australia. PbI2 (99.999%) and dimethylformamide (DMF) were purchased from Alfa Aesar, UK. CsI (99.999%), dimethylsulfoxide (DMSO), chlorobenzene, titanium isopropoxide, 4-tert-butylpyridine (tBP) and bis(trifluoromethylsulfonyl)imide lithium salt (Li-TFSI) were purchased from Sigma–Aldrich, Ltd, USA. Methylammonium chloride (MACl) and PbBr2 (99.98%) were purchased from Xi’an Polymer Light Technology Corp, China. Spiro-OMeTAD was purchased from Taiwan Lumtec, Ltd, China.
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5

Perovskite Solar Cell Fabrication

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The fluorine-doped tin oxide coated glass (FTO, 6 Ω/□) was purchased from Opvtech New Energy Co., Ltd. (Yingkou, China). Titanium (IV) isopropoxide (99.9%), N,N-dimethylformamide (DMF, chromatographic grade, ≥99.9%), methanol (chromatographic grade, ≥99.9%), ethanol (chromatographic grade, ≥99.8%), and isopropanol (≥99.5%) were purchased from Aladdin (Shanghai, China). PbBr2 (99.99%) and CsBr (99.9%) were purchased from Xi’an Polymer Light Technology Corp (Xi’an, China). InBr3 (99.9%) was purchased from Macklin Biochemical Co., Ltd. (Shanghai, China). The commercial carbon paste was purchased from Shanghai MaterWin New Materials Co., Ltd. (Shanghai, China).
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6

Fabrication of Halide Perovskite Devices

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Trimethylolpropane trimethacrylate (TMPTA, stabilized with MEHQ) was purchased from Innochem. PbBr2, CsBr, FABr, GABr, ethyl acetate (EA), chlorobenzene (CB) and 2,2′,2′′-(1,3,5-benzinetriyl)-tris(1-phenyl-1-H-benzimidazole) (TPBi) were purchased from Xi'an Polymer Light Technology Corp. PEABr was purchased from Dyesol. PEDOT:PSS (Clevious P VP Al 4083) was fabricated by Heraeus. Dimethyl sulfoxide (DMSO) was purchased from Alfa Aesar.
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7

Optimized Perovskite Solar Cell Synthesis

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Formamidinium iodide (FAI), methylammonium bromide (MABr), methylammonium chloride (MACl), and Butylammonium Iodide (BAI) were ordered from Greatcell Solar Ltd. PbI2 (99.999%) and SnO2 (15 wt % colloidal dispersion tin (IV) oxide) was purchased from Alfa Aesar. Cesium iodide (CsI) (99.999%), dimethylformamide (DMF), dimethylsulfoxide (DMSO), isopropanol, chlorobenzene (CB), ethyl acetate, 4-tert-Butylpyridine (tBP), bis(trifluoromethylsulphonyl)imide lithium salt (Li-TFSI), acetonitrile, and methylenediamine dihydrochloride (MDACl2) were all bought from Sigma-Aldrich Ltd. (Saint Louis, MO, USA) PbBr2 (99.999%) was purchased from Xi’an Polymer Light Technology Corp. (Xi’an, China) Spiro-OMeTAD was purchased from Lumtec Ltd. (Taiwan, China) All the chemicals and reagents were used as received without further purification.
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8

Synthesis of Halide Perovskite Precursors

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Cesium iodide (CsI, 99.99%), lead bromide (PbBr2, 99.99%), lead iodide (PbI2, 99.99%), and lead acetate (PbAc2, 99.5%) were purchased from Xi’an Polymer Light Technology Corp. PbI2(DMSO), and PbBr2(DMSO) were prepared by the antisolvent method. The ionic liquids (ILs) 1-butyl-2,3-dimethylimidazolium tetrafluoroborate (BMMIMBF4, 99%), 1-butyl-3-methylimidazolium tetrafluoroborate (BMIMBF4, 99%), 1-propyl-3-methylimidazolium tetrafluoroborate (PMIMBF4, 99%), 1-hexyl-3-methylimidazolium tetrafluoroborate (HMIMBF4, C10H19BF4N2, 99%), and 1-hexyl-2,3-dimethylimidazolium tetrafluoroborate (HMMIMBF4, 99%) were purchased from Shanghai Chengjie Chemical Co., Ltd. N,N-dimethylformamide (DMF) and dimethylsulfoxide (DMSO) were purchased from Shanghai Aladdin Biochemical Technology Co., Ltd.
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9

Perovskite Nanocomposite Synthesis

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PbCl2 (99.99%), MABr (MA = CH3NH3+, 99.5%), PbBr2 (99.99%) and MACl (99.5%) were purchased from Xi’an Polymer Light Technology Co. Ltd., Xi’an, China. N,N-dimethylformamide (DMF, 99.5%) and Poly(N-vinylpyrrolidone) (PVP) with molecular weight (Mw) ~130,000 were obtained from Aladdin (Shanghai, China). Another PVP with Mw ≈ 40,000 and PVDF pellets (Mw ≈ 275,000) were gotten from Sigma-Aldrich (Shanghai, China). AgNO3 (99.98%), ethylene glycol and acetone were purchased from Beijing Chemical Reagent Co. Ltd., Beijing, China. All the chemicals were used without further purification.
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10

Synthesis and Characterization of Perovskite Materials

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CsI, PbI2, PbCl2 and PbBr2 were purchased from Xi'an Polymer Light Technology Corp. FAI, MAI, MACl, MABr, 3-APAI, 4-ABAI, 5-AVAI were purchased from Greatcell Solar Limited. Dimethylsulfoxide (DMSO), N,N-Dimethylformaldehyde (DMF), and isopropanol (IPA) were purchased from Macklin Inc. SnO2 was obtained from Alfa Aesar. FTO glass, [6,6]-phenyl-C61butyric acid methyl ester (PCBM) and spiro-OMeTAD were purchased from Liaoning YouXuan Technology Co., Ltd. All these chemicals were used without further purification.
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