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5 protocols using pbcl2

1

Perovskite Solar Cell Synthesis

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Cs2CO3(99.9%), didodecyldimethylammonium bromide (DDAB,98%), toluene (ACS grade, Fisher), Octanoic acid (OTAc,98%), Formamidine acetate (FAAc, 99%), tetraoctylammonium bromide (TOAB,98%), Methyl acetate (98%), and aluminum (Al) were purchased from Sigma-Aldrich. PbBr2 (99.9%), PbCl2 (99.9%), Poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) dry re-dispersible pellets (PEDOT:PSS (4083)), Poly[N,N’-bis(4-butylphenyl)-N,N’-bis(phenyl)-benzidine (Poly-TPD), 1,3,5-Tris(1-phenyl-1H-benzimidazol-2-yl)benzene(TPBi), and LiF were purchased from Xi’an Polymer Light Technology Corp.
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2

Fabrication of PbCl2-CsCl Heterojunction

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PbCl2 (99.99%) and CsCl (99.9%) were purchased from Xi'an Polymer Light Technology Corporation (China), and dimethyl sulphoxide (DMSO, chromatographic grade) from Sigma-Aldrich (USA). The materials were used as received without any further purification.
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3

Perovskite Solar Cell Fabrication

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PEDOT:PSS (Clevios PVP Al 4083), methylammonium iodide (MAI, 99.5%), PbCl2 (99.99%), PbI2 (99.99%), PCBM (99%) were purchased form Xi'an Polymer Light Technology Corp (China), while N,N-dimethylformamide (DMF, 99.8%), dimethyl sulfoxide (DMSO, 99.9%), chlorobenzene (CB, 99.8%) and Alq3 (99.995%) were purchased from Sigma-Aldrich. A solution of 0.14 M PbCl2, 1.26 M PbI2 and 1.4 M MAI in a cosolvent of DMSO and DMF (vol. ratio = 1 : 9) was prepared in a glove box and stirred overnight under room temperature. 15 mg PCBM was dissolved in 1 mL CB and stirred overnight under room temperature.
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4

Perovskite Nanocomposite Synthesis

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PbCl2 (99.99%), MABr (MA = CH3NH3+, 99.5%), PbBr2 (99.99%) and MACl (99.5%) were purchased from Xi’an Polymer Light Technology Co. Ltd., Xi’an, China. N,N-dimethylformamide (DMF, 99.5%) and Poly(N-vinylpyrrolidone) (PVP) with molecular weight (Mw) ~130,000 were obtained from Aladdin (Shanghai, China). Another PVP with Mw ≈ 40,000 and PVDF pellets (Mw ≈ 275,000) were gotten from Sigma-Aldrich (Shanghai, China). AgNO3 (99.98%), ethylene glycol and acetone were purchased from Beijing Chemical Reagent Co. Ltd., Beijing, China. All the chemicals were used without further purification.
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5

Synthesis and Characterization of Perovskite Materials

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CsI, PbI2, PbCl2 and PbBr2 were purchased from Xi'an Polymer Light Technology Corp. FAI, MAI, MACl, MABr, 3-APAI, 4-ABAI, 5-AVAI were purchased from Greatcell Solar Limited. Dimethylsulfoxide (DMSO), N,N-Dimethylformaldehyde (DMF), and isopropanol (IPA) were purchased from Macklin Inc. SnO2 was obtained from Alfa Aesar. FTO glass, [6,6]-phenyl-C61butyric acid methyl ester (PCBM) and spiro-OMeTAD were purchased from Liaoning YouXuan Technology Co., Ltd. All these chemicals were used without further purification.
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