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4 protocols using cyclohexane

1

Synthesis and Characterization of Copper Sulfate

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Ethyl ether (AR), acetone (AR), cyclohexane (AR) and CuSO4·5H2O (AR) were purchased from Chengdu Kelong Chemical Reagent Factory (Chengdu, China). Trichlorfon (≥90%) was provided by Shanghai Biochemical Reagent Co., Ltd. (Shanghai, China). All other chemicals used in this experiment were of analytical reagent grade (AR).
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2

Synthesis of Polyurethane-Based Composites

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Guanidine carbonate, ethyl acetoacetate, alpha-acetyl-gamma-butyrolactone, triethylamine, ethylene glycol monoallyl ether, 1-thioglycerol, 2,2-dimethoxy-2-phenylacetophenone, hexamethylene diisocyanate, polytetramethylene ether glycol (PTMEG, Mn = ∼1000 g mol−1), ditinbutyl dilaurate (DBTDL) were purchased from Aladdin Chemistry Regent Co., Ltd (China). Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-methylphenyl)propionate (AO-70) was obtained from Beijing Additive Research Institute (China). Hydroxyl groups modified multi-walled carbon nanotubes (MWCNTs-OH) with hydroxyl content of 1.85 wt% was purchased from Chengdu Organic Chemicals Co. Ltd (China). 4,4′-Dicyclohexylmethane diisocyanate (HMDI) was kindly provided by Wanhua Chemical Group Co., Ltd (China). Absolute alcohol, sodium hydroxide, dichloromethane, hydrochloric acid, p-toluene sulfonic acid, cyclohexane, sodium bicarbonate, tetrahydrofuran, anhydrous sodium sulfate, acetone, petroleum ether and dimethyl formamide (DMF) were purchased from Chengdu Kelong Chemical Reagent Co. Ltd (China). DMF was dehydrated with activated 4A molecular sieves for at least one week before use, the other reagents were used as received.
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3

Trichlorfon Synthesis and Purification

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Ethyl acetate (AR), acetone (AR), cyclohexane (AR), and CuSO4·5H2O (AR) were purchased from Chengdu Kelong Chemical Reagent Factory (Chengdu, China). Trichlorfon (≥90%) was provided by Shanghai Biochemical Reagent Co., Ltd. (Shanghai, China). All other chemicals used in this experiment were of analytical reagent grade (AR).
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4

Synthesis of Cadmium Sulfide Nanoparticles

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All chemicals are commercially available and used as received without purification (except stated otherwise). Cadmium oxide (CdO, 99.99%), oleic acid (OA, 90%), ODE (90%), and bis(trimethylsilyl)sulfide ((TMS)2S) were purchased from Sigma-Aldrich. Cadmium acetate dihydride (Cd(OAc)2·2H2O, 99.999%) and the bulk cadmium sulfide (CdS, 98%) were from Alfa Aesar. Powder sulfur (S, 99.5%) and isopropanol (i-PrOH, 99.7%) were received from Chengdu Ke Long Chemical. Phenylacetic acid (PhCH2COOH, 98%) was from Sinopharm Chemical Reagent. DCTB (98.0%) and CHCA were obtained from Tokyo Chemical Industry. Toluene (99.5%) and cyclohexane (CH, 99.5%) were from Chengdu Ke Long Chemical; dried solvents were used for the kinetic study (with ~20 g of Na2SO4 for 1000 mL of solvents).
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