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2 protocols using pyrrole monomer

1

Synthesis of Intersected PPy Nanotubes

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Ferric chloride [FeCl3], 2-(N-morpholino)ethanesulfonic acid monohydrate [MES], aluminium oxide [aluminium oxide, basic, for chromatography, 50–200 μm] and pyrrole monomer [Py, 99%, extra pure] were purchased from Acros. Alpha alumina powder (average diameter ∼ 1 μm) was provided by CH instruments. Sodium hydroxide [NaOH, reagent grade, 97% powder] was bought from Sigma-Aldrich. Nanoporous PC templates as well as PET filtration membranes were kindly supplied by it4ip [Louvain-la-Neuve, Belgium, https://www.it4ip.be]. Frameworks of intersected PPy nanotubes were synthesized using polycarbonate (PC) templates featuring a network of intersected nanopores. The characteristics of all the PC templates used throughout this work are detailed in Table 1. PET membranes used for sample deposition had an average pore diameter of 200 nm, with a pore density of 5 × 108 pores per cm2 and a thickness of 23 μm.
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2

Synthesis of Graphite-based Composites

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Graphite powder was purchased from Ashbury Graphite Mills Inc. (code no. 3061). Common chemicals such as iron (III) chloride (FeCl3, 98%), potassium permanganate (KMnO4, 99%), sodium p-toluenesulfonate (NapTS, 70%), sulfuric acid (H2SO4, 95–98%), phosphoric acid (H3PO4, 85%), ethyl alcohol (C2H6O), hydrogen peroxide (H2O2, 30%), hydrogen chloride (HCl, 37%), potassium chloride (KCl), cadmium acetate dihydrate (CH3COO2Cd.2H2O, 97%), and thiourea (NH2CSNH2, 96%) were procured from Merck. Triethanolamine (TEA) was obtained from Sigma Chemical, Co. N-butylamine (CH3(CH2)3NH2) and pyrrole monomer (99%) were purchased from Acros Organics. pyrrole monomer was stored at 0 °C and distilled prior to use. Conductive filament was purchased from Black Magic. Double distilled water was used throughout the experiments.
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