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Trimethylsilane

Manufactured by Merck Group

Trimethylsilane is a colorless, flammable gas that is used as a precursor in the semiconductor industry. It has the chemical formula (CH3)3SiH. The main function of Trimethylsilane is to serve as a source of silicon in various chemical vapor deposition (CVD) processes for the fabrication of semiconductor devices and integrated circuits.

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2 protocols using trimethylsilane

1

Alcohol Dehydrogenase Enzyme Assay

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Alcohol dehydrogenase (ADH) from Saccharomyces cerevisiae, β-nicotinamide adenine dinucleotide sodium salt (NAD+), phosphate buffer solution, β-alanine, triethanolamine, 2-mercaptoethanol, deuterated chloroform (CDCl3) containing trimethylsilane (TMS), octadecylphosphonic acid (ODPA), trioctylphosphine oxide (TOPO), trioctylphoshine (TOP), octanoic acid, crotonaldehyde (CA), and butyraldehyde (BA) were purchased from Sigma-Aldrich. Acetaldehyde (AA), n-octane, and palladium acetylacetonate were purchased from Acros Organics. (1,5-Cyclooctadiene)-dimethylplatinum(II), cadmium oxide, glycerol tributyrate (GT), and sulfur were purchased from Alfa Aesar. β-Nicotinamide adenine dinucleotide disodium salt hydrate (NADH) and 2-ethylhexenal (2-EH) were purchased from TCI Chemicals. Butanol (BuOH), 2-propanol, acetone, dextrose, and toluene were purchased from Fisher Scientific. Yeast nitrogen base (w/o amino acids and ammonium sulfate) was purchased from Beckton, Dickinson, and Company. Active dry yeast was purchased from ACH Food Companies, Inc. Ethanol (EtOH) was purchased from Decon Laboratories, Inc. Deuterium oxide (D2O) and sodium 2,2-dimethyl-2-silapentane-5-sulfonate (DSS) were purchased from Cambridge Isotope Laboratories, Inc.
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2

Synthesis and Characterization of Photosensitizers

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The starting materials, including N-bromosuccinimide, 4-(N,N-diphenylamino)benzaldehyde, (3,5-dimethoxyphenyl)boronic acid, aliquat-336, K2CO3, Pd(PPh3)4, 4,4′-dimethyl-2,2′-dipyridyl and trimethylsilane, were purchased from Sigma-Aldrich, Alfa Aesar and Ark Pharm companies. In addition, 2,2′-bipyridinyl-4,4′-dicarboxylic acid and the MH-12 and MH-13 photosensitizers were synthesized according to the reported procedure23,24 (link) (see ESI). All required solvents were ordered from Fischer Scientific. A Bruker advance 400 MHZ was used to obtain the 1H-NMR spectra, applying DMSO-d6 and TMS as an internal standard for chemical shift calibration. A Bruker alpha spectrophotometer was used for FTIR spectroscopy analysis. The mass spectra were acquired on a Thermo Scientific EXACTIVE (ESI-MS) spectrometer. The UV-visible and fluorescence spectra were obtained utilizing SPECORD S600 and Horiba Fluromax-4 spectrophotometers.
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