N hexane analytical grade

For extraction, n-hexane analytical grade (VWR International, Radnor, USA) and n-butane, 95% purity without mercaptan (Inventec Performance Chemical, St Priest, France) were used in this study. b-carotene (>98% UV purity) was purchased from Extrasynth ese (Genay, France). Fatty Acids Methyl Esters mix (Supelco 37 FAME mix), pentadecanoic acid (C15:0, 99% purity), d-carvone (98% purity) and d-limonene (99% purity) were purchased from Sigma-Aldrich (St. Louis, USA).

For laboratory-scale extractions, n-hexane analytical grade, ethanol 95% purity and acetone technical grade were purchased from VWR International (Radnor, USA).
Trans-1,3,3,3-Tetrafluoroprop-1-ene (HFO-1234ze) 99.5% purity was purchased from Inventec Performance Chemical (St Priest, France).
For analytical procedures, all reagents were HPLC grades. Acetonitrile, ammonium acetate, dichloromethane, primuline and potassium chloride were purchased from Sigma-Aldrich (St. Louis, USA). b-carotene (>98% UV purity) was purchased from Extrasynth ese (Genay, France). Oleuropein (HPLC grade, ! 98%), carnosic acid (HPLC grade, ! 97%), Fatty Acids Methyl Esters mix (Supelco 37 FAME mix), triheptadecanoin (C17:0 TAG, 99% purity), pentadecanoic acid (C15:0, 99% purity), 1-glyceryl palmitate (MAG), 1,3glyceryl palmitate (DAG), glyceryl tripalmitate (TAG), palmitic acid (FFA), ergosterol, phosphatidylcholine, phosphatidic acid, phosphatidylethanolamine and lysophosphatidylcholine were purchased from Sigma-Aldrich (St. Louis, USA). Chloroform, n- hexane, acetone, diethyl ether, acetic acid, methyl acetate, isopropanol and methanol were sourced from VWR International (Darmstadt, Germany).