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2 protocols using barium nitrate

1

Synthesis of Hierarchical Mesoporous Silicas

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All reagents were utilized as received without undergoing additional purification. Hierarchically mesoporous silicas (HMS), MCM-41, KIT-6, and SiO2-70 Å (pore size 70 Å), were purchased from Jiangsu XFNANO Nano Materials Tech Co., Ltd. (Jiangsu, China). Zirconium nitrate pentahydrate (Zr(NO3)4·5H2O), sodium nitrate (NaNO3), ferric nitrate nonahydrate(Fe(NO3)3·9H2O), silver nitrate (AgNO3), strontium nitrate (Sr(NO3)2), caesium nitrate (CsNO3), barium nitrate (Ba(NO3)2), lanthanum nitrate hexahydrate (La(NO3)3·6H2O), cerium nitrate hexahydrate (Ce(NO3)3·6H2O), neodymium nitrate hexahydrate (Nd(NO3)3·6H2O), samarium nitrate hexahydrate (Sm(NO3)3·6H2O), and europium nitrate hexahydrate (Eu(NO3)3·6H2O) were purchased from Macklin. HNO3 (68 wt%) was purchased from Sinopharm Chemical Reagent Co., Ltd (Beijing, China). with the grade of A.R.
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2

Synthesis of Metal Oxide Nanostructures

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Polyethyleneimine solution (PEI solution, average Mn ~ 60,000 by GPC, 50 wt% in H2O), zinc nitrate hexahydrate (Zn (NO3)2·6H2O, 98%) and titanium (IV) bis (ammonium lacato) dihydroxide solution (TALH solution, 50 wt% in H2O), gallium nitrate octahydrate (Ga(NO3)3·8H2O, 99.9%) were purchased from Sigma-Aldrich. copper nitrate trihydrate (Cu(NO3)2·3H2O, 99%) was purchased from Adamas-beta. yttrium nitrate hexahydrate (Y(NO3)3·6H2O, 99.9%), indium nitrate (In(NO3)3·4H2O, 99.9%), barium nitrate (Ba(NO3)2, 99%), strontium nitrate (Sr(NO3)2, 99%), ethylene diamine tetraacetic acid (EDTA, 99.9%) and anhydrous D-glucose (99%) were purchased from Macklin Inc. Crystal bond™ 509 was purchased from Structure Probe, Inc.
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