St (99.0%), azobisisobutyronitrile (AIBN) (98.0%) and PBS buffer solution (×10) were purchased from Wako Pure Chemical Industry Ltd., Osaka, Japan. Super dehydrated toluene (99.5%), divinylbenzene (DVB) (50.0%), 4-vinylpyridine (4VP) (95.0%), Sodium 4-styrenesulfonate (93.0%), Acetonitrile (99.0%) and isobutylphenyl propionic acid (Ibuprofen,> 98.0%) were all purchased from Tokyo Chemical Industry Co., Ltd., Tokyo, Japan (TCI). d -limonene (90.0%), tetrahydrofuran (98.0%), dimethyl sulfoxide (99.0%) and bromocresol purple were purchased from Nacalai Tesque Inc. Kyoto Japan. Rhodamine B was purchased from Sigma Aldrich Co., St.Louis, MO, USA. Vinylbenzyl trimethylammonium chloride (VBAC) was purchased from Santa Cruz Biotechnology, Kyoto, Japan. All chemicals were used as supplied without further purification, except where noted otherwise.
Azobisisobutyronitrile
Manufactured by Fujifilm
Sourced in Japan
Azobisisobutyronitrile is a chemical compound that functions as an initiator in various polymerization processes. It is commonly used in the synthesis of polymers and copolymers.
Automatically generated - may contain errors
Lab products found in correlation
Lysozyme from chicken egg white, by Merck Group (2 mentions)
Dimethyl sulfoxide (dmso), by Nacalai Tesque (1 mentions)
Tetrahydrofuran, by Nacalai Tesque (1 mentions)
Divinylbenzene dvb, by Tokyo Chemical Industry (1 mentions)
Acetonitrile, by Tokyo Chemical Industry (1 mentions)
D limonene, by Nacalai Tesque (1 mentions)
Rhodamine b, by Merck Group (1 mentions)
2 dodecylthiocarbonothioylthio 2 methylpropionic acid, by Merck Group (1 mentions)
Thioflavin t tht, by Merck Group (1 mentions)
Micrococcus lysodeikticus, by Merck Group (1 mentions)
N isopropylacrylamide, by Fujifilm (1 mentions)
Insulin from bovine pancreas, by Merck Group (1 mentions)
M lysodeikticus, by Merck Group (1 mentions)
Nipam, by Fujifilm (1 mentions)
Agno3, by Fujifilm (1 mentions)
Methyl methacrylate, by Fujifilm (1 mentions)
Acrylonitrile, by Tokyo Chemical Industry (1 mentions)
N n dimethylformamide (dmf), by Fujifilm (1 mentions)
7 protocols using azobisisobutyronitrile
1
Monomer Synthesis and Polymerization for Biomaterial Development
2
Synthesis and Characterization of Sulfobetaine-Based Polymers
Check if the same lab product or an alternative is used in the 5 most similar protocols
+ Expand
Sulfobetaine (SPB) monomer was donated by Osaka Organic Chemical (Osaka, Japan) and used without further purification. 2-(Dodecylthiocarbonothioylthio)-2-methylpropionic acid, Thioflavin T (ThT), Micrococcus lysodeikticus, and lysozyme from chicken egg white were purchased from Sigma-Aldrich. Azobisisobutyronitrile (AIBN) was purchased from Wako Pure Chemical Industries (Osaka, Japan) and was recrystallized from methanol before use. Ethylene glycol dimethacrylate, BuMA and 4,4′-azobis-(4-cyanovaleric acid) (V-501, initiator) were purchased from TCI (Tokyo, Japan). Prior to its use, the inhibitor from BuMA was removed by passing through an inhibitor removal prepacked column (Sigma-Aldrich).
3
Synthesis and Evaluation of Epoxy Resin Composition
Check if the same lab product or an alternative is used in the 5 most similar protocols
+ Expand
Example 3
Main raw materials used in the synthesis test of Test Example 3 are as follows.
[Main Raw Materials]1,3-Diallyl-2-imidazolidinone (synthesized in accordance with the method described in WO2002/036662. See chemical formula (4-1))
1,3-Diallyl-2-benzimidazolone (synthesized in accordance with the method described in J. Am. Chem. Soc., vol. 80, pp. 1657-1662 (1958). See chemical formula (5-1))
Thioacetic acid (manufactured by Tokyo Chemical Industry Co., Ltd., see chemical formula (13))
Azobisisobutyronitrile (manufactured by Wako Pure Chemical Industries Ltd.)
An epoxy resin composition was prepared by mixing 128.1 parts by weight of the thiol compound synthesized in Example 3-1 as a curing agent, 10.4 parts by weight of dimethylbenzylamine as a curing accelerator and 174.0 parts by weight of jER152 as an epoxy compound. The amount of the curing accelerator used was adjusted such that gelation time (80° C.) of the epoxy resin composition is 2 minutes±20 seconds.
The epoxy resin composition was subjected to evaluation tests (measurement of storage modulus of cured product, and measurement of adhesive strength thereof when used as adhesive). Test results obtained are shown in Table 3.
4
Synthesis of Copolymeric Hydrogels
Check if the same lab product or an alternative is used in the 5 most similar protocols
+ Expand
N,N-Dimethylacrylamide (DMAAm), Styrene (St), and methyl methacrylate (MMA) was purchased from Wako Pure Chemical Industries and used after distillation. N-isopropylacrylamide and azobis(isobutyronitrile) was purchased from Wako Pure Chemical Industries and used after recrystallization. Ammonium persulfate (APS), N,N′-methylenebis(acrylamide) (MBAAm), N,N,N’,N’-tetramethylethlenediamine (TEMED) were purchased from Wako Pure Chemical Industries (Osaka, Japan) and used as purchased without further purification.
5
Sulfobetaine Monomer Synthesis and Characterization
Check if the same lab product or an alternative is used in the 5 most similar protocols
+ Expand
Osaka Organic Chemical
(Osaka, Japan) donated sulfobetaine monomer that was used without
further purification. Insulin from bovine pancreas, lysozyme from
chicken egg white, M. lysodeikticus, and 2-(dodecylthiocarbonothioylthio)-2-methylpropionic acid (R1)
were obtained from Sigma-Aldrich (Japan). Azobisisobutyronitrile (AIBN)
was obtained from Wako Pure Chemical Industries (Osaka, Japan). 3-((((1-Carboxyethyl)thio)carbonothioyl)thio)propanoic
acid (R2) was purchased from Boron Molecular (North Carolina).
(Osaka, Japan) donated sulfobetaine monomer that was used without
further purification. Insulin from bovine pancreas, lysozyme from
chicken egg white, M. lysodeikticus, and 2-(dodecylthiocarbonothioylthio)-2-methylpropionic acid (R1)
were obtained from Sigma-Aldrich (Japan). Azobisisobutyronitrile (AIBN)
was obtained from Wako Pure Chemical Industries (Osaka, Japan). 3-((((1-Carboxyethyl)thio)carbonothioyl)thio)propanoic
acid (R2) was purchased from Boron Molecular (North Carolina).
6
Stimuli-Responsive Polymer Hydrogel Synthesis
Check if the same lab product or an alternative is used in the 5 most similar protocols
+ Expand
The silica gel [spherical (particles of size 63–210 μm), neutral] (Kanto, Tokyo, Japan), silylation reagents [(3-isocyanatopropyl)trimethoxysilane (purity, >97%; IPTMS) and PhTMS (>98%)], polyethers [PEG with molecular weight (Mw) = 2000 and PTMO with Mw = 2000], and the catalyst [dibutyltin dilaurate (DBTD), extra pure grade (TCI, Tokyo, Japan)] were used as received. The vinyl monomer NIPAM and cross-linker BIS (Wako, Osaka, Japan) were purified by recrystallization before use. The IPN gel was synthesized in THF solvent with a radical initiator, azobisisobutyronitrile (>98%, AIBN) (Wako) and was chemically stimulated by various metal salts [purities >99%; (CH3CO2)K, >97%; CuCl2, >95% (practical grade)] and a 0.1 M aqueous solution of AgNO3 (f = 1.000, Wako).
7
Synthesis of Binder Polymer CP-3
Check if the same lab product or an alternative is used in the 5 most similar protocols
+ Expand
Example 3
5.80 g of N,N′-dimethylformamide (manufactured by Wako Pure Chemical Industries, Ltd.) was weighed in a three-neck flask provided with a condenser and a stirrer, and the solution was stirred at 65° C. for 30 minutes while flowing nitrogen. Next, 7.21 g of 4-methacrylamidebenzenesulfonamide (manufactured by FUJIFILM Finechemicals Co., Ltd.), 3.00 g of methyl methacrylate (manufactured by Wako Pure Chemical Industries, Ltd.), 2.12 g of acrylonitrile (manufactured by Tokyo Chemical Industry Co., Ltd.), 23.0 g of N,N′-dimethylformamide (manufactured by Wako Pure Chemical Industries, Ltd.), and 0.324 g of azobisisobutyronitrile (manufactured by Wako Pure Chemical Industries, Ltd.) were weighed using a dropping funnel, dissolved, and added dropwise to the flask for 2 hours. Further, the resulting solution was stirred at 65° C. for 3 hours. The reaction solution was added dropwise to a mixed solution of 0.5 L of pure water and 0.5 L of methanol to precipitate the polymer. The polymer was filtered, washed, and dried, thereby obtaining 11.2 g of a binder polymer (CP-3) having a weight-average molecular weight of 53000. It was confirmed whether the polymer was a target object using an NMR spectrum, an IR spectrum, and GPC (polystyrene conversion).
Further, the numerical values at the lower right of parentheses in CP-1 to CP-3 are molar ratios.
About PubCompare
Our mission is to provide scientists with the largest repository of trustworthy protocols and intelligent analytical tools, thereby offering them extensive information to design robust protocols aimed at minimizing the risk of failures.
We believe that the most crucial aspect is to grant scientists access to a wide range of reliable sources and new useful tools that surpass human capabilities.
However, we trust in allowing scientists to determine how to construct their own protocols based on this information, as they are the experts in their field.
Ready to get started?
Sign up for free.
Registration takes 20 seconds.
Available from any computer
No download required
Revolutionizing how scientists
search and build protocols!