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8 protocols using multiwall carbon nanotubes

1

Synthesis of Magnetic Nanocomposites

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Nickel nitrate hexahydrate (Ni(NO3)2·6H2O), iron nitrate nonahydrate (Fe(NO3)3·9H2O), Multiwall—Carbon Nanotubes (MWCNT), Nitrofurantoin (NFT), ethylene glycol (HOCH2CH2OH), disodium hydrogen phosphate (Na2HPO4), monosodium dihydrogen phosphate (NaH2PO4), ethanol, acetone are purchased from Sigma-Aldrich of analytical grade with a purity of ~ 99% and used as received. Different pH values for phosphate buffer solution were prepared by NaH2PO4·H2O and Na2HPO4·2H2O by dissolving in double-distilled water (ddH2O).
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2

Selective Ion-Sensing Electrochemical Sensor

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Selectophore grade sodium ionophore X, bis(2-ethylehexyl) sebacate (DOS), sodium tetrakis[3,5-bis(trifluoromethyl)phenyl] borate (Na-TFPB), high-molecular-weight polyvinyl chloride (PVC), tetrahydrofuran, valinomycin (potassium ionophore), sodium tetraphenylborate (NaTPB), cyclohexanone, polyvinyl butyral resin BUTVAR B-98 (PVB), sodium chloride (NaCl), 3,4-ethylenedioxythiophene (EDOT), poly(sodium 4-styrenesulfonate) (NaPSS), glucose oxidase (from Aspergillus niger), chitosan, single-walled carbon nanotubes, iron (III) chloride, potassium ferricyanide (III), multiwall carbon nanotubes and block polymer PEO-PPO-PEO (F127) were obtained from Sigma Aldrich. L-lactate oxidase (>80 activity units per milligram) was procured from Toyobo Corp. and PBS (pH 7.2) was obtained from Life Technologies. Moisture-resistant 100-μm-thick PET was purchased from McMaster-Carr.
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3

Myricetin and Carbon Nanotubes Spectroelectrochemical Analysis

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Myricetin was purchased from Sigma-Aldrich Co. and used as received. Stock solution of Myricetin (1.0×10−3 mol L−1) was prepared in ethanol as solvent and diluted with 0.1 M phosphate medium (pH 3.5) before use. Multi-wall carbon nanotubes (diameter: 10–20 nm, length: 1–2 µm, purity >95%) were obtained from Sigma-Aldrich Co. Gold nanoparticles with average diameters of ∼13 and ∼40 nm were prepared by the reduction of HAuCl4.3H2O (Merck) with sodium citrate. Other chemicals were analytical grade and used without further purification in double-distilled water.
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4

Synthesis of Functional Polymer Materials

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NiCl2, CuCl2, NaBH4, aminoborane aryl azides, acetonitrile (ACN), lithium perchlorate (LiClO4), 3,4-ethylene dioxythiophene (EDOT), multiwall carbon nanotubes, NN –Dimethylformamide (DMF), sulfuric acid, hydrochloric acid, and nitric acid were purchased from Sigma-Aldrich. Tetrahydrofuran (THF; 99.5%), HClO4 (60%), 2-propanol, and Methanol (≥ 99.5%) were obtained from Merck. All test materials and other components were cleaned with distilled water. The pure water used was supplied by the Millipore water distillation system.
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5

Synthesis of CNT@TiO2 Nanocomposites

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To prepare CNT and TiO2 nanocomposites (CNT@TiO2), multiwall carbon nanotubes purchased from Sigma Aldrich were immersed in a solution of nitric acid and sulfuric acid at room temperature for 12 hours. TiO2 was synthesized on the acid-treated CNTs using a solution-based layer-by-layer coating method presented in Fig. S1. 2 mL of titanium tetra isopropoxide (TTIP) were dissolved in 40 mL of isopropyl alcohol (IPA). Then, 40 mg of the acid-treated CNTs were added to the solution and sonicated for 30 min. The prepared mixture was kept at 80 °C for 2 hours for the adsorption of TTIP on the acid-treated CNTs and filtered. The collected powder was washed with ethanol. Then, DI water was dropped onto the powder for hydrolysis of TTIP adsorbed on CNT. The products were collected and dried in a convection oven at 60 °C for 3 hours. The adsorption and hydrolysis processes were alternately repeated 2, 4, 6 and 8 times to obtain corresponding number of TiO2 layers on CNT. Then, the products were heated at 350 °C in air for 2 hours for calcination.
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6

Functionalized Carbon Nanotubes for Mercury Remediation

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Multi-wall carbon nanotubes with specifications of D×L 6-9 nm × 5 µm ˃95% (carbon), TBAB, Gly, sulfuric acid (95%-97%), nitric acid (65%), potassium permanganate, sodium hydroxide pellets, and hydrochloric acid (36.5-38%) were all supplied by SIGMA-ALDRICH.
A 1,000 mg/L mercury standard solution was supplied by MERCK.
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7

Fabrication of Polymer-Nanotube Composites

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Polyvinylpyrrolidone (PVP; Mw 1,300,000, MW 30,000), Polyacrylic acid (PAA, Mw 450,000,), Multi Wall Carbon Nanotubes (MWCNT), S(-)-limonene (S-lim, 96%), α-Pinene (α-Pin, 98%), Linalool (Lin, 97%), Toluene (Tol, anhydrous, 99.8%), Hyaluronic Acid Sodium Salt from Streptococcus equi (HyA, Mw 750,000-1,000,000), Absolute Ethanol (EtOH, 99.8%), and N-N-Dimethylformamide (DMF, 99.8%) were reagent grade purchased by Merck KGaA (Darmstadt, Germany) and used without further purification.
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8

Synthesis of Vanadium-Doped Zinc Oxide Nanocomposites

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Zinc nitrate (Zn (NO3)2.4H2O, 99%), Vanadium pentoxide (V2O5), and Multiwall carbon nanotubes (MWCNT, >98%) were purchased from Merck Company. Hydrogen peroxide (H2O2), sodium hydroxide (NaOH Pellets), and ethanol were supplied by Loba Chemie. All of the chemicals were used as received without further purifications.
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