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Terephthaloyl chloride

Manufactured by Thermo Fisher Scientific

Terephthaloyl chloride is a chemical compound commonly used as a precursor in the production of various polymers and industrial materials. It is a crystalline solid with a characteristic pungent odor. Terephthaloyl chloride is primarily employed as a building block in the synthesis of polyesters, polyamides, and other specialty chemicals.

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2 protocols using terephthaloyl chloride

1

Electrochemical Sensor Fabrication Protocol

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4-Nitrobenzaldehyde (99%), tin(ii) chloride dihydride (SnCl2·2H2O, 98+%) were purchased from Acros Organics, terephthaloyl chloride (99%) and Nafion solution (5% w/w in H2O and 1-propanol) were obtained in Alfa Aesar, pyrrole (98%), pyridine (99%), sulfuric acid (H2SO4), potassium hydroxide (KOH) and 1.0 M PBS buffer (pH = 7) were purchased from Fisher Scientific and used without further purification. All the glassware and cells were decontaminated by soaking in aqua regia solution (conc. HCl/conc. nitric acid = 3 : 1). The glass apparatus was washed with deionized water and oven dried. Carbon paper substrate was purchased from Fuel Cell Store (AvCarb P75T −40 × 40 cm), which is carbon particle-filled, polyacrylonitrile (PAN) based carbon fiber paper with hydrophobic Teflon wet-proof (13% wt treatment) coating nominal thickness of 0.255 mm (@ 1 psi/0.7 N cm−2).
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2

Synthesis and Characterization of REE Complexes

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Chemical and materials. Tetraethoxysilane (TEOS, 98%), (3-aminopropyl)triethoxysilane (APTS, 98%), and N,N-dioctylamine (97%) were purchased from Sigma-Aldrich. Phthaloyl chloride (94%), isophthaloyl dichloride (98%), and terephthaloyl chloride (99%) were purchased from Alfa Aesar and were used without further purification. Analytical-reagent grade hydrochloric acid (37%), nitric acid (65%), and sodium hydroxide were purchased from Merck and were used without further purification. Toluene (Sigma-Aldrich) and triethylamine (Sigma-Aldrich, 99%) were dried and distilled using Na/benzophenone, and stored on molecular sieves under nitrogen. Solutions of REEs (Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) and additional ions (Al and Fe) were prepared from the reference standard solutions (Plasma, Cal, SCP Science) using nanopure water.
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