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10 protocols using toluene

1

Surface Modification of Polyester Fabrics

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Polyester fabrics (100% PET; 86 g/cm2) were purchased from the Aotai Textile Sales Company, China. DPOP and VTES were obtained from Shanghai Aladdin Biochemical Technology Co. Ltd., China. MTES and OTMS were supplied by Shanghai Aladdin Biochemical Technology Co. Ltd., China. Sodium hydroxide (NaOH) was obtained from Tianjin Beichenfangzheng Chemical Co. Ltd., China. Ethanol (AR), butanol, hexanol, acetone, THF, DMSO, TCM, toluene, n-hexane, and PE were supplied by Chengdu Kelong Chemical Co. Ltd., China. All materials were used without further treatment.
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2

Synthesis of Phenolphthalin from Phenolphthalein

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2,6-difluorobenzonitrile (DFBN, AR) and potassium hydroquinonesulfonate (SHQ, AR) were supplied by Sigma Aldrich (Shanghai, China). Phenolphthalein (PP, AR), anhydrous potassium carbonate (K2CO3, AR), N-methyl pyrrolidone (NMP, AR), toluene (AR), ethanol (AR), hydrochloric acid (AR), and N,N-Dimethylacetamide (DMAc, AR) were supplied by Chengdu Kelong Chemical Co. (Chengdu, China). All the materials above were used as received without further purification. The synthesis of phenolphthalin (PPL) from PP was implemented according to the literature [26 (link)].
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3

Epoxy Resin Synthesis with Flame Retardants

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Diglycidyl ether of bisphenol A (DGEBA, E-51: epoxide value 0.51 mol/100 g) was acquired from Nantong Xingchen Synthetic Material Co., Ltd. (Nantong, China). Anhydrous ethanol and toluene were obtained from Chengdu Kelong Chemical Co., Ltd. (Chengdu, China). Vanillin (VN) was purchased from Shanghai Yuan Ye Biotechnology Co., Ltd. (Shanghai, China). 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) and 4,4-diaminodiphenylmethane (DDM) were purchased from Shanghai Macklin Biochemical Co., Ltd. (Shanghai, China). 2,4-Diamino-6-phenyl-1,3,5-triazine (DPT) was purchased from Wuhan Lanbai Pharmaceutical Chemical Co., Ltd. (Wuhan, China).
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4

Immobilized TiO2 Nanoparticles for Enzymatic Detection

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Commercial 3-aminopropyltriethoxysilane (APTES)-modified TiO2 NPs (TiO2 content ≥ 95%) were purchased from Huizhe Fine Chemistry Co., Ltd. (Suzhou, China). Hexamethylene tetramine (HMTA, purity ≥ 99.5%) and hydrogen peroxide (purity 30%) were obtained from Aladdin Biochemical Technology Co., Ltd. (Shanghai, China). DA (purity ≥ 98%), NAD+ (purity ≥ 98%), NADH (purity ≥ 98%), Fluorescein isothiocyanate (FITC) and ADH were purchased from Hefei Bomei Biological Technology Co., Ltd. (Hefei, China). Ethanol, toluene, tetraethoxysilane (TEOS) and Tris-HCl were purchased from Chengdu Kelong Chemical Reagent Factory (Chengdu, China). All other chemicals were of analytical grade and used without further purification. All water used in experiments was obtained from Millipore water purification system Milli-Q Integral 5 (Paris, France) (resistance ≥ 18.25 MΩ·cm−1).
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5

Bisphenol-AF Synthesis Protocol

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Bisphenol-AF(BPAF) was obtained from Aladdin Chemicals (Shanghai, China). 2,6-Dichlorobenzonitrile (DCBN), K2CO3, N-methyl-2-pyrrolidone (NMP), and toluene were all purchased from Chengdu Kelong Chemical Co., Ltd. (Chengdu, China). All the chemical reagents were used without further purification.
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6

Synthesis and Characterization of PASS Polymers

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PASS with an inherent viscosity of 0.42 dL g−1 were synthesized in our laboratory.29 (link) GNPs (purity > 99%) were supplied by The Sixth Element Co., Ltd (Changzhou, China). N-Methyl pyrrolidone (NMP, AR grade), hydrochloric acid, sodium hydroxide, toluene, tetrahydrofuran (THF) and acetone were provided by the Chengdu Kelong Chemical Reagent Factory (China). High-temperature resistant silver paste was purchased from the Jiangsu Shenggelu New Materials Company (China).
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7

Synthesis of Cadmium Sulfide Nanoparticles

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All chemicals are commercially available and used as received without purification (except stated otherwise). Cadmium oxide (CdO, 99.99%), oleic acid (OA, 90%), ODE (90%), and bis(trimethylsilyl)sulfide ((TMS)2S) were purchased from Sigma-Aldrich. Cadmium acetate dihydride (Cd(OAc)2·2H2O, 99.999%) and the bulk cadmium sulfide (CdS, 98%) were from Alfa Aesar. Powder sulfur (S, 99.5%) and isopropanol (i-PrOH, 99.7%) were received from Chengdu Ke Long Chemical. Phenylacetic acid (PhCH2COOH, 98%) was from Sinopharm Chemical Reagent. DCTB (98.0%) and CHCA were obtained from Tokyo Chemical Industry. Toluene (99.5%) and cyclohexane (CH, 99.5%) were from Chengdu Ke Long Chemical; dried solvents were used for the kinetic study (with ~20 g of Na2SO4 for 1000 mL of solvents).
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8

Synthesis and Characterization of Octa-Epoxy POSS

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Epoxy resin (E-51) was supplied by SINOPEC Baling Petrochemical Co., Ltd (China). Methylhexahydrophthalic anhydride (MHHPA) was purchased from Adamas-beta Chemical Reagent Co., Ltd (China). N,N′-Dimethylbenzylamine (DMBA) and tetramethylammonium hydroxide pentahydrate (TMAH·5H2O) were analytical grade reagents purchased from Shanghai Macklin Biochemical Technology Co., Ltd (China). KH-560 was purchased from Dinghai Plastic Chemical Co., Ltd (China). Isopropanol (IPA) and toluene were chemical grade reagents purchased from Chengdu Kelong Chemical Co., Ltd (China). Sodium chloride and anhydrous magnesium sulfate were analytical grade chemicals purchased from Sinopharm Chemical Reagent Co., Ltd (China). All chemicals were used directly without further purification or treatment.
The octa-epoxy terminated polyhedral oligomeric silsesquioxane (OG-POSS) was synthesized in the laboratory, with an epoxy value of 0.56 mol (100 g)−1. The synthesis route of OG-POSS is shown in Fig. 1, and the details, synthesis and characterization, are described in the ESI S1.
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9

Graphene-Reinforced Polymer Microspheres

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Styrene (St) and Span 80 were obtained from Innochem Technology Co., Ltd., Beijing, China. Divinylbenzene (DVB), sodium persulfate (Na2S2O8) and sodium dodecyl sulfonate (SDS) were obtained from Aldrich, Shanghai, China. Graphene (GN, lamellae size 5–15 µm) was supplied by Deyang Carbonene Technology Co., Ltd., and the lamellae were composed of five to six layers of graphene. Absolute ethanol, petroleum ether, chloroform, toluene and acetone were all purchased from Chengdu Kelong Chemical Reagent Factory. Ultrapure deionized water from an ultrapure water machine was used to prepare all solutions.
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10

Synthesis of Colloidal Nanocrystals

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Cadmium
oxide (CdO, 99.5%),
oleic acid (HOA, 90.0%), hexanoic acid (C6 acid, 99.5%), myristic
acid (MA, 99.0%), zinc acetate (Zn(OAc)2, 99.99%), manganese
acetate tetrahydrate (Mn(OAc)2·4H2O, 99.0%,),
and 1-octadecene (ODE, C18H36, 90.0%) were purchased
from Sigma-Aldrich. Sulfur powder (S, 99.5%), acetic acid (HOAc, CH3COOH, 99.5%), stearic acid stearic acid (SA, 99.0%), ethanol
(EtOH, 95%), and toluene (Tol, 99.5%) were purchased from Chengdu
Kelong Chemical. Butyric acid (C4 acid, 99.0%) was purchased from
Alfa Aesar, and cyclohexane (CH, 99.5%) was purchased from Tianjin
Zhiyuan Chemical. All the chemicals were used as received without
further purifications.
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