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75 protocols using nickel nitrate hexahydrate

1

Lignin-Grafted Polyethylene Composite

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LG was extracted from a black liquor collected from an alkali pulping mill in Hunan Province, China according to an acid precipitate method which has been exhaustively described in our previous study.22 (link) Commercially available PE powder with average Mw of ∼4000 and Mn of ∼1700 GPC was provided by Sigma-Aldrich Corporation (St. Louis, MO, USA). Chemicals including nickel nitrate hexahydrate (Ni), cobaltous nitrate hexahydrate (Co), iron nitrate nonahydrate (Fe), manganese nitrate tetrahydrate (Mn) and copper nitrate trihydrate in analytical reagent grade were obtained from Sigma-Aldrich Corporation (St. Louis, MO, USA).
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2

Synthesis of Ni/C and Ru/C Catalysts

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Nickel on carbon (Ni/C) catalysts were synthesized following our previously published wet impregnation procedure46 (link). Briefly, to prepare 10 g of 15 wt% catalyst, 7.432 g nickel nitrate hexahydrate (Sigma-Aldrich) was dissolved in 10.2 mL deionized water and added to 8.5 g Darco carbon (Sigma-Aldrich, 100 mesh). After equilibrating at ambient conditions for 16 h and drying for 24 h at 120 °C, the catalyst was thermally reduced in a tube furnace by heating to 450 °C over 1 h and then holding for 2 h at 450 °C under flowing nitrogen (100 mL min−1). The catalyst was used in batch reactions without further treatment. For flow reactions, the catalyst required pelletizing to ensure a good flow profile and prevent large pressure drops. Since carbon does not pelletize easily, the 15 wt% Ni/C was mixed 50/50 w/w with SiO2 (Sigma-Aldrich, 12 nm) by agitating with a stir bar for 24 h. The resulting physical mixture was pelletized using 6 tons of pressure and sieved to 100–200 mesh.
Ruthenium on carbon (Ru/C) was purchased from Sigma-Aldrich (5 wt% loading) and used as-received.
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3

Synthesis of Metal Oxide Nanoparticles

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All the reagents, nickel nitrate hexahydrate (Ni(NO3)2·6H2O), aluminum nitrate nonahydrate (Al(NO3)3·9H2O), cerium nitrate hexahydrate (Ce(NO3)3·6H2O), gold(III) chloride trihydrate (HAuCl4·3H2O), sodium carbonate anhydrous (Na2CO3) and sodium hydroxide (NaOH) were of “pro analyze” purity grade, provided by Sigma-Aldrich (Steinheim, Germany), and were used for the synthesis as received. All the solutions were prepared with fresh distilled water.
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4

Synthesis and Characterization of Transition Metal-Doped Carbon Nanofibers

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All solvents and reagents throughout the current study were commercially pure products and used as received without any further purification. Manganese acetate, Mn (CH3COO)2, nickel nitrate hexahydrate, Ni (NO3)2·6H2O, and ammonium dibasic phosphate, (NH4)2HPO4, were purchased from Sigma Aldrich-United Kingdom. Deionized water was used to prepare all the solutions and rinse the electrodes during the experiment. The carbon nanofibers (CNFs), OD: 200–600 nm was ordered from the US Research Nanomaterials, Inc., Houston, USA. CNFs material was manufactured by CVD technique and has high purity >95 wt%. It possesses a tap density of 0.043 g cm−3 and a high electrical conductivity of 100 S cm−1. Also, potassium hydroxide, urea, Nafion, and formaldehyde 37–38% w/w STB MT, Nafion (5% water) were obtained from Pan Rec Applichem.
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5

Synthesis of Perovskite Catalysts

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Strontium nitrate (99 %, Acros Organics), titanium‐(IV) isopropoxide (97 %, Alfa Aesar), lanthanum(III) nitrate hexahydrate (99.9 %, Alfa Aesar), nickel nitrate hexahydrate (97 %, Sigma‐Aldrich) and anhydrous citric acid (99.6 %, Acros Organics), and glycerol (99 %, Alfa Aesar) were used as received without further purification. The commercial 1 % Ni/Al2O3 was purchased by Riogen Inc., NJ, USA.
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6

Synthesis and Characterization of Metal-Dye Complexes

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The chemicals in this study
were used as received and without any further purification. Aluminum
nitrate nonahydrate Al(NO3)3·9H2O was provided by BDH. Nickel nitrate hexahydrate Ni(NO3)2·6H2O and ethanol absolute were purchased
from Sigma-Aldrich. Propylene oxide (noted PO; CH3CHCH2O), orange II (noted OII, C16H11N2NaO4S), methyl orange (noted MO, C14H14N3NaO3S), Congo Red (noted CR,
C32H22N6Na2O6S2), methylene blue (noted MB, C16H18ClN3xH2O), rhodamine
B (noted rhB, C28H31ClN2O3), and rhodamine 6G (noted rh6G, C28H31N2O3Cl) were provided by Acros. Acetone was purchased
from Scharlau Chemie S.A. Double distilled water was obtained from
our laboratory.
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7

Synthesis of Nanocomposite Materials

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Nickel nitrate hexahydrate (Ni(NO3)2•6H2O, >99.999%), cobalt nitrate hexahydrate (Co(NO3)2•6H2O, >99.999%), aluminium nitrate nonahydrate (Al(NO3)3•9H2O, >99.997%), dimethyl sulfoxide anhydrous (C2H6OS, >99.9%), ethanol (C2H5OH, 99.9%), acetone (C3H6O, 99.5%), carbon black (>99.95%), ethylene glycol anhydrous (C2H6O2, >99.8%), polyvinylidene fluoride (PVDF), and urea (CH4N2O, >90%) were purchased from Sigma-Aldrich and used as received. Deionised water was used in the experiment and for the washing of the samples. Finally, HERMLE Z 36 HK centrifuge was used for washing purposes.
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8

Synthesis and Characterization of Metal-Based Nanomaterials

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The metal precursors such as nickel nitrate hexahydrate [Ni(NO3)2.6H2O; (99.99%)], sodium molybdate dihydrate [Na2MoO4.2H2O; (99.5%)], sodium hydroxide [NaOH; (97%)], and Urea [CO(NH2)2; (99.5%)] were purchased from sigma Aldrich. All the chemicals were of analytical grade and used without further purification. Deionized water was used as a solvent throughout the synthesis of the material. Acridine orange (AO), 2,2-diphenyl-1-picryl-hydrazyl-hydrate (DPPH), Hydrogen peroxide (H2O2), 2',7'-dichlorodihydrofluorescein diacetate (H2DCFDA), 2,3,5-triphenyl tetrazolium chloride (TTC), Propidium Iodide (PI), 4',6-diamidino-2-phenylindole (DAPI), potassium persulfate, trichloroacetic acid and other reagents and chemicals were purchased from HiMedia Laboratories Pvt. Ltd., (Mumbai, India). The pathogenic bacterial strains of Bacillus subtilis, Staphylococcus aureus, Pseudomonas aeruginosa and Escherichia coli were obtained from the Microbial Type Culture Collection (MTCC), Chandigarh, India.
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9

Graphene Foam Synthesis via APCVD

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Nickel nitrate hexahydrate (Ni(NO3)2·H2O), sodium nitrate (NaNO3), ammonium phosphate (N2H9PO4) and urea (CH4N2O) were purchased from Sigma Aldrich and used as received without further modification. Graphene foam used in this work was prepared by means of an atmospheric pressure chemical vapor deposition (APCVD) technique as reported in our previous work.30 (link)
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10

Synthesis of Magnetic Nanocomposites

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Nickel nitrate hexahydrate (Ni(NO3)2·6H2O), iron nitrate nonahydrate (Fe(NO3)3·9H2O), Multiwall—Carbon Nanotubes (MWCNT), Nitrofurantoin (NFT), ethylene glycol (HOCH2CH2OH), disodium hydrogen phosphate (Na2HPO4), monosodium dihydrogen phosphate (NaH2PO4), ethanol, acetone are purchased from Sigma-Aldrich of analytical grade with a purity of ~ 99% and used as received. Different pH values for phosphate buffer solution were prepared by NaH2PO4·H2O and Na2HPO4·2H2O by dissolving in double-distilled water (ddH2O).
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