We purchased 3-fluorophenylethylammonium bromide (m-FPEABr), phenylethylammonium bromide (PEABr), and poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] (PTAA) (average MW = 6000–15,000) from Xi’an Polymer Light Technology Corp. (Xi’an, China). We purchased PbBr2 (99.999%), CsBr (99.999%), poly(9-vinylcarbazole) (PVK) (MW = 1,100,000), DMSO (anhydrous, ≥99.9%), ethanol (anhydrous) and chlorobenzene (anhydrous, ≥99.8%) from Sigma-Aldrich (St. Louis, MO, USA). Nickel acetate tetrahydrate (Ni(CH3COO)2·4H2O) (99.9%) was purchased from Shanghai Aladdin Biochemical Technology Co., Ltd. (Shanghai, China). ethanolamine (99%) was purchased from ACROS, (St. Louis, MO, USA), and 1,3,5-tris(2-N-phenylbenzimidazolyl)-benzene) (TPBI) (≥99%) and LiF (≥99%) were purchased from Jilin OLED Photoelectric Material Corporation (Changchun, China). The molecular structures of m-FPEABr and PEABr are shown in Figure 1 a. All chemicals were used as received.
Poly 9 vinylcarbazole
Manufactured by Merck Group
Sourced in Germany
Poly(9-vinylcarbazole) is a material used in various laboratory applications. It is a polymer consisting of repeated vinylcarbazole units. The core function of this product is to serve as a photoconductive material in applications that require light-sensitive properties.
Automatically generated - may contain errors
Lab products found in correlation
Chlorobenzene, by Merck Group (7 mentions)
Dimethyl sulfoxide (dmso), by Merck Group (6 mentions)
Lithium fluoride, by Merck Group (3 mentions)
Toluene, by Merck Group (3 mentions)
Methanol, by Merck Group (3 mentions)
Ethanol, by Merck Group (3 mentions)
Poly bis 4 phenyl 2 4 6 trimethylphenyl amine ptaa, by Xi'an Yuri Solar Co. (3 mentions)
Pbbr2, by Merck Group (2 mentions)
Thiophenol, by Merck Group (2 mentions)
Polystyrene sulfonate, by Merck Group (2 mentions)
Cadmium nitrate tetrahydrate, by Merck Group (2 mentions)
Cesium bromide, by Merck Group (2 mentions)
Ethyl acetate, by Merck Group (2 mentions)
Ethanolamine, by Thermo Fisher Scientific (2 mentions)
Cyclohexanone, by Merck Group (1 mentions)
N butanol, by Merck Group (1 mentions)
1 4 dioxane, by Merck Group (1 mentions)
Acetonitrile, by Merck Group (1 mentions)
Phosphomolybdic acid, by Merck Group (1 mentions)
Anhydrous dimethyl sulfoxide, by Merck Group (1 mentions)
10 protocols using poly 9 vinylcarbazole
1
Synthesis and Characterization of Perovskite Materials
2
Synthesis of Luminescent Quantum Dots
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Chlorobenzene (CB, anhydrous, 99.8%), cyclohexanone (ACS reagent, ≥99.0%), 1,4-dioxane (anhydrous, 99.8%), dimethyl sulfoxide (DMSO, ≥99.9%), acetonitrile (anhydrous, 99.8%), n-butanol (anhydrous, 99.8%), phosphomolybdic acid (PMA), and poly(9-vinylcarbazole) (PVK) were purchased from Sigma Aldrich. Furthermore, N4,N4′-di(Naphthalen-1-yl)-N4,N4′-bis(4-vinylphenyl)biphenyl-4,4′-diamine (VNPB) was purchased from OSM. In addition, we prepared QD solutions (CdSe/CdS/CdZnS) according to a previous report [34 (link)].
3
Fabrication of Perovskite Solar Cells
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Indium tin oxide (ITO) coated glass substrates
and borosilicate substrates were purchased from KINTEC. Anhydrous N,N-dimethylformamide (DMF, 99% purity),
anhydrous dimethyl sulfoxide (DMSO, 99.9% purity), lead bromide (PbBr2, trace metals basis), poly(9-vinylcarbazole) (PVK, Mn 25000–50000), lithium fluoride (LiF,
≥ 99.99% trace metals basis), and chlorobenzene (CB, > 99.8%
purity) were purchased from Sigma-Aldrich. Methylamine hydrobromide
(MABr, > 98% purity) was purchased from TCI. T1100 sol–gel
was purchased from SCIL Nanoimprint Solution. 2,2′,2″-(1,3,5-Benzinetriyl)-tris(1-phenyl-1-H-benzimidazole) (TPBi, > 99.5% purity) was purchased
from
Ossila. Aluminum pellets (Al, 99.99% purity) were purchased from Kurt
Lesker.
and borosilicate substrates were purchased from KINTEC. Anhydrous N,N-dimethylformamide (DMF, 99% purity),
anhydrous dimethyl sulfoxide (DMSO, 99.9% purity), lead bromide (PbBr2, trace metals basis), poly(9-vinylcarbazole) (PVK, Mn 25000–50000), lithium fluoride (LiF,
≥ 99.99% trace metals basis), and chlorobenzene (CB, > 99.8%
purity) were purchased from Sigma-Aldrich. Methylamine hydrobromide
(MABr, > 98% purity) was purchased from TCI. T1100 sol–gel
was purchased from SCIL Nanoimprint Solution. 2,2′,2″-(1,3,5-Benzinetriyl)-tris(1-phenyl-1-H-benzimidazole) (TPBi, > 99.5% purity) was purchased
from
Ossila. Aluminum pellets (Al, 99.99% purity) were purchased from Kurt
Lesker.
4
Fabrication of Organic Optoelectronic Devices
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Cadmium nitrate-tetrahydrate (Cd(NO3)2·4H2O, 99.99%), thiophenol (99%), sulphur powder (99.98%), poly(9-vinylcarbazole) (PVK, 98%), poly(3,4-ethylenedi-oxythiophene):poly(styrene sulfonate) (PEDOT:PSS, 1.3% water solution), toluene, methanol and dimethyl sulfoxide (DMSO) were purchased from Sigma-Aldrich (Darmstadt, Germany) and used without further purification. Reduced graphene oxide (rGO) was obtained from Graphenano “nanotechnologies” (Yecla, Spain) and used without further purification.
5
Fabrication of Perovskite Solar Cells
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Lead(II) bromide (PbBr2), cesium bromide (CsBr), cesium iodide (CsI), isopropyl ammonium bromide (iPABr), 2‐phenylethylammonium bromide (PEABr), 2‐phenylethylammonium iodide (PEAI), dimethyl sulfoxide (DMSO), toluene, chloroform, chlorobenzene, poly(9‐vinylcarbazole) (PVK), Nafion perfluorinated resin solution (PFI), and lithium fluoride (LiF) were purchased from Sigma‐Aldrich. n‐propylammonium bromide (nPABr) and benzylammonium bromide (BABr) were purchased from GreatCell Solar. PEDOT:PSS Al4083 was purchased from Heraeus. 2,2′′,2′′‐(1,3,5‐benzenetriyl)tris(1‐phenyl‐1H‐benzimidazole) (TPBi) was purchased from Tokyo Chemical Industry. Al was purchased from Itasco. All commercially available chemicals were used as received without further purification.
6
Synthesis of Perovskite Optoelectronic Materials
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Lead bromide (PbBr2, >99.9%) and 2,8‐Bis(diphenyl‐phosphoryl)‐dibenzo[b,d]furan (PPF, ≥96%) were purchased from Tokyo Chemical Industry Co., Ltd. Cesium bromide (CsBr, >99.9%), phenethylammonium bromide (PEABr, ≥98%), 2,8‐Bis(diphenyl‐phosphoryl)‐dibenzo[b,d]thiophene (PPT, >96.5%), Poly[N,N″‐bis(4‐butylphenyl)‐N,N″‐bis(phenyl)‐benzidine] (Poly‐TPD), Poly(9‐vinylcarbazole) (PVK), lithium fluoride (LiF, >99.99%), and solvents including chlorobenzene (CB, 99.8%) and dimethyl sulfoxide (DMSO, ≥99.9%) were purchased from Sigma‐Aldrich and used without further purification. 2,2′,2″‐(1,3,5‐Benzinetriyl)‐tris(1‐phenyl‐1‐Hbenzimidazole) (TPBi) was purchased from Ultra Fine Chemical Technology Corp. 1,4,7,10,13,16‐Hexaoxacyclooctadecane (18‐crown‐6, 99%) was purchased from Alfa Aesar.
7
Perovskite Solar Cell Fabrication
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Nickel(II) acetate tetrahydrate [Ni(CH3COO)2·4H2O, 99.995%], ethanolamine (NH2CH2CH2OH, 99.5%), ethanol (99.8%), poly(9-vinylcarbazole) (PVK, average Mn ranging from 25,000 to 50,000 g mol−1), CsBr (99.999%), PbBr2 (99.999%), chlorobenzene (anhydrous, 99.8%), and ethyl acetate (anhydrous, 99.8%) were purchased from Sigma-Aldrich. 2PACz (>98.0%) was purchased from Tokyo Chemical Industry Co., Ltd. Phenylethylammonium bromide (PEABr, 99.5%), iso-propylammonium bromide (IPABr, 99.5%) and formamidinium bromide (FABr) were purchased from Xi’an Polymer Light Technology Corp. DMSO (>99.0%) was purchased from Acros. LiF was purchased from Alfa Aesar. 1,3,5-Tris(1-phenyl-1H-benzimidazol-2-yl)benzene (TPBi) was purchased from Lumtec. All chemicals were used as received.
8
Synthesis of Organic Semiconductors
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Cadmium nitrate-tetrahydrate (Cd(NO3)2·4H2O, 99.99%), thiophenol (99%), sulfur powder (99.98%), poly(9-vinylcarbazole) (PVK, 98%), poly(3,4-ethylenedi-oxythiophene):poly(styrene sulfonate) (PEDOT:PSS, 1.3% water solution), toluene, methanol and dimethyl sulfoxide (DMSO) were purchased from Sigma-Aldrich (Darmstadt, Germany) and used without further purification.
9
Synthesis and Characterization of Perovskite Materials
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Dimethyl sulfoxide (DMSO; 99.9%), 18-Crown-6 (18Cr6), hydrobromic acid (HBr), Poly (9-vinylcarbazole) (PVK), lithium fluoride (LiF), cesium bromide (CsBr), chlorobenzene, and xylene were purchased from Sigma-Aldrich. PbBr2 and sodium trifluoroacetate (STFA) was purchased from TCI. Ethanolamine and Nickel (II) acetate tetrahydrate was purchased from Alfa Aesar. Phenethylamine (PEA) was purchased from Adamas. Poly[N,N’-bis (4-butylphenyl)-N,N’-bisphenylbenzidine] (poly-TPD) from Xi'an p-OLED company. Formamidinium bromide (FABr; ≥99.99%) from Greatcell Solar Materials. 1,3,5-Tris (1-phenyl-1H-benzimidazol-2-yl) benzene (TPBi) from Jilin OLED material tech.
10
Fabrication and Characterization of Fluorescent Silica Nanoparticles
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Click to copy section linkSection link copied! Materials TEOS (tetraethyl orthosilicate, 99%), APTMS ((3aminopropyl)trimethoxysilane, 97%), FITC (fluorescein isothiocyanate isomer I, 98%), RITC (Rhodamine B isothiocyanate, mixed isomers), ThT (thioflavin T), KOH (potassium hydroxide), methanol (99.9%), ammonium hydroxide (26%), PLGA (poly(lactic-co-glycolic acid, lactide:glycolide (65:35), 40 000â€"75 000 Da), ethyl acetate (≥99.5%), chitosan (from shrimp shells, ≥75%, deacetylated), poly(9-vinylcarbazole) (PVK, ∼1 100 000 Da), and tetrahydrofuran (THF) were purchased from Sigma-Aldrich, Ireland; ethanol (99.9%) from Merck, Germany; MEM (Minimum Essential Media) and FBS (fetal bovine serum) were purchased from Gibco, Life
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