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2 protocols using titanium 4 tetrachloride

1

Synthesis of Silica Nanoparticles via Sol-Gel

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Titanium (IV) tetrachloride (99.9% trace metals basis), benzyl alcohol (puriss., 99–100.5% (GC)), 2‐amino‐2‐(hydroxymethyl)‐1,3‐propanediol (Trizma base, puriss., ≥99.7%), chloroform (≥99.8%), diethyl ether (for HPLC, ≥99.9%, inhibitor‐free), ethanol (absolute), tetraethylorthosilicate (TEOS, 98%), methyl orange (MO), and acetaminophen (paracetamol, ≥99%) were purchased from Sigma‐Aldrich. Hydrochloric acid 37% was obtained from Carlo Erba. Decahydronaphthalene (decalin, a mixture of cis and trans isomers, 98%) and sorbitan monooleate surfactant (Span 80, HLB: 4.3) were obtained from Merck. 3‐Glycidyloxypropyl)trimethoxysilane (GPTMS, Xiameter OFS‐6040, >98.5%) was supplied by Dow. All chemicals were used without further purification.
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2

Synthesis of Titanium Oxide Nanoparticles

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Titanium(IV) tetrachloride
(99.9% trace metal basis), benzyl alcohol (puriss., 99–100.5%
(GC)), tris(hydroxymethyl)-aminomethane (Trizma base, puriss., ≥99.7%),
ethanol (absolute ≥99.8% for analysis), diethyl ether (puriss.,
≥99.8%), n-hexane (≥97.0% for HPLC),
acetone (≥99.8% for HPLC), and Drierite (without indicator,
4 mesh) were purchased from Sigma-Aldrich/Merck. RTV Silicon Elastosil
E43 was purchased from Wacker Chemie AG. Nitrogen 4.5, helium 4.6,
oxygen 5.0, and carbon dioxide 3.0 were purchased from PanGas AG Switzerland,
and sulfur hexafluoride 3.0 was purchased from Linde Gas. All chemicals
were used as received without further purification.
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