2,2’-Azino-bis (3-ethylbenzothiazoline-6-sulfonic acid) (ABTS), veratryl alcohol, catechol, veratryl alcohol, methyl red, nicotinamide adenine dinucleotide (NADH) and dichlorophenol indophenols (DCIP) were procured from HiMedia Laboratories Pvt. Ltd. (Mumbai, India). Chloranil, dimethylformamide (DMF), aniline-2-sulfonic acid and all other chemicals were obtained from Sigma-Aldrich (St. Louis, MO, USA). All the chemicals used in this study were of high purity (>98%). Trypan Blue (CAS No. 72-57-1; CI No. 23850; CI Name = Direct Blue 14; Molecular Formula = C34H24N6O14S4Na4; Molecular Weight = 960.81 g∙mol−1; λmax 660 nm); λmax 660 nm), a water-soluble azo dye was procured from Sigma-Aldrich and used as received. Its chemical structure is shown in Figure 1 . Unless otherwise stated, the working concentration of dye Trypan Blue was 50 mg∙L−l.
Chloranil
Manufactured by Merck Group
Sourced in United States
Chloranil is a chemical compound primarily used as a reagent in analytical and organic chemistry laboratories. It serves as an oxidizing agent and can be utilized in various chemical reactions and analyses. The core function of Chloranil is to facilitate specific chemical transformations and to aid in the identification and characterization of organic compounds.
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Lab products found in correlation
Gallic acid, by Merck Group (5 mentions)
Folin ciocalteu reagent, by Merck Group (4 mentions)
Ascorbic acid, by Merck Group (3 mentions)
Veratryl alcohol, by HiMedia (2 mentions)
Methyl red, by HiMedia (2 mentions)
2 2 azino bis, by HiMedia (2 mentions)
2 6 dichloroindophenol sodium salt hydrate, by Merck Group (2 mentions)
Catechin hydrate, by Merck Group (2 mentions)
Vanillin, by Merck Group (2 mentions)
Acetic acid, by Sangon (2 mentions)
Catechol, by HiMedia (1 mentions)
Azo dye, by Merck Group (1 mentions)
Trypan blue, by Merck Group (1 mentions)
Nicotinamide adenine dinucleotide nadh, by HiMedia (1 mentions)
Nicotinamide adenine dinucleotide, by HiMedia (1 mentions)
Dimethylformamide, by Merck Group (1 mentions)
Dichloromethane, by Thermo Fisher Scientific (1 mentions)
Benzidine, by Merck Group (1 mentions)
Triflic acid, by Merck Group (1 mentions)
Acetone, by Thermo Fisher Scientific (1 mentions)
11 protocols using chloranil
1
Enzymatic Decolorization of Trypan Blue
2
Decolorization of Textile Azo Dyes
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The textile azo dyes viz. C.I. Reactive black 5 (RB 5), C.I. Reactive orange 16 (RO 16), C.I. Disperse red 78 (DR 78) and C.I. Direct red 81 (DR 81) were kindly provided by Mahesh Textile Processors, Ichalkaranji, India. The structural information of dyes is shown in Table 1(Tab. 1) . Veratryl alcohol, 2,2’-Azino-bis (3-ethylbenzothiazoline-6-sulfonic acid) (ABTS), methyl red, nicotinamide adenine dinucleotide (NADH), dichlorophenol indophenols (DCIP) and dehydrated microbiological medium nutrient broth (NB) were obtained from HiMedia Laboratories Pvt. Ltd., Mumbai, India. Chloranil, Dimethylformamide and Aniline-2-sulfonic were purchased from Sigma-Aldrich (St. Louis, MO, USA).
3
Synthesis of Aromatic Compounds using Diverse Reagents
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Acetone, acetonitrile, chloroform, dichloromethane, methanol, tetrahydrofuran (THF), toluene, and 1,4-dioxane were purchased from Fisher chemicals. 1-ethynyl-4-fluorobenzene and 1,3,5-tri-(4-aminophenyl)benzene were purchased from TCI. 1-ethynyl-4-(trifluoromethyl)benzene as purchased from 1Click Chemistry Stock Products. Methyl 4-ethynyl benzoate was purchased from AK scientific. 2,5-Dimethoxyterephthalaldehyde were purchased from Carbosynth chemicals. 2,4-diphenyl-quinoline were purchased from EnamineStore. Phenylacetylene, 4-ethynyl benzonitrile, boron trifluoride diethyl etherate, triethylamine were purchased from Alfa Aesar chemicals. Chloranil, triflic acid, 1,3,5-triformylbenzene, benzidine, mesitylene, o-dichlorobenzene, n-butanol were purchased from Sigma Aldrich chemicals.
4
Antioxidant Capacity Evaluation Protocol
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Ascorbic acid (ASA), 2,6-dichloroindophenol sodium salt hydrate, chloranil, catechin hydrate, vanillin, Folin-Ciocalteu reagent, hydrocortisone, penicillin, streptomycin, gentamicin, Gallic acid, 2,2′-Azobis-amidinopropane (ABAP) and dichlorofluorescin diacetate (DCFH-DA) were purchased from Sigma Chemical Co. (St. Louis, MO, USA). NaOH, KH2PO4, KOH, AlCl3, acetic acid, NaHCO3, and K2HPO4 were bought from Sangon (Shanghai, China). Chlorogenic acid, Caffeic acid, 4-Coumaric acid, Ferulic acid and benzoic aicd, NaBH4 were bought from Aladdin Co. (Shanghai, China). WME medium, Hank's balanced salt solution (HBSS), epidermal growth factor, heparin, insulin, and other cell culture reagents were purchased from Gibco Biotechnology Co. All reagents used were of analytical grade.
5
Antioxidant Assays of Natural Compounds
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Ascorbic acid (ASA), catechin, chloranil, 2,6-dichloroindophenol sodium salt hydrate (DIP), 2,2′-azobis-amidinopropane (ABAP), Trolox, Folin-Ciocalteu reagent, and gallic acid (GA) were purchased from Sigma (St. Louis, MO, USA). Metaphosphoric acid, acetone, alcohol, hydrochloric acid (HCl), ethyl acetate, sodium carbonate (Na2CO3), tetrahydrofuran (THF), vanillin, sodium borohydride (NaBH4), methanol, and fluorescein disodium salt were purchased from Aladdin (Shanghai, China). Acetic acid, sodium hydroxide (NaOH), potassium hydroxide, potassium phosphate dibasic, potassium phosphate monobasic, aluminum chloride, and sodium bicarbonate (NaHCO3) were acquired from Sangon Company (Shanghai, China).
6
Phytochemical Analysis and Antioxidant Assays
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Gallic acid, chlorogenic acid, vanillic acid, p-coumaric acid, ferulic acid, 2,2-diphenyl-1-picrylhydrazyl (DPPH) free radical, sodium borohydride, chloranil, tetrahydrofuran (THF), vanillin, 2,4,6-Tris (2-pyridyl)-s-triazine (TPTZ), and FeSO4 were purchased from Sigma Aldrich Co. (St. Louis, MO, USA). Rutin, resveratrol, quercetin, kaempferol, baicalein, and wogonin were purchased from Beijing Century Aoke Biological Technology Co. (Beijing, China). Folin Ciocalteu’s reagent was purchased from Beijing Soledad Bao Technology Co. (Beijing, China). All the other chemicals were of analytical grade or HPLC grade.
7
Synthesis of Chromium Corrole and Porphyrin Complexes
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Pyrrole, chloranil, Cr(CO)6, and
TBAP (tetrabutylammonium perchlorate) were purchased from Sigma-Aldrich
(USA). p-Cyanobenzaldehyde was purchased from Merck
(India). Hexane and dichloromethane were obtained via distillation from KOH and CaH2, respectively. The rest
of the starting chemicals were of reagent grade. Oxo-[5,10,15-tris(p-cyanophenyl)corrolato]chromium(V),1 , was
synthesized by following a literature-reported method.39 (link) (Saloph)MnV(N) was prepared by following
a literature-reported method.41 (link) 5,10,15-Tris(4-cyanophenyl)corrole
was prepared according to a literature-reported protocol.24 (link) The chloro(porphyrinato)chromium(III) complex,4 , was also prepared by following a literature-reported method.38f
TBAP (tetrabutylammonium perchlorate) were purchased from Sigma-Aldrich
(USA). p-Cyanobenzaldehyde was purchased from Merck
(India). Hexane and dichloromethane were obtained via distillation from KOH and CaH2, respectively. The rest
of the starting chemicals were of reagent grade. Oxo-[5,10,15-tris(p-cyanophenyl)corrolato]chromium(V),
synthesized by following a literature-reported method.39 (link) (Saloph)MnV(N) was prepared by following
a literature-reported method.41 (link) 5,10,15-Tris(4-cyanophenyl)corrole
was prepared according to a literature-reported protocol.24 (link) The chloro(porphyrinato)chromium(III) complex,
8
Antioxidant Compounds Extraction and Characterization
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Ascorbic acid, gallic acid, Folin–Ciocalteu reagent, sodium borohydride (NaBH4), aluminum chloride, chloranil, vanillin, and 2,7-dichlorodihydrofluorescein diacetate (DCFH-DA) were obtained from Sigma Chemical Co (St. Louis, MO, United States). Potassium hydroxide (KOH), 2,20-azobis-amidinopropane (ABAP), sodium hydroxide (NaOH), potassium dihydrogen phosphate (KH2PO4), potassium hydrogen phosphate (K2HPO4), and sodium bicarbonate (NaHCO3) were obtained from Aladdin Co., Ltd (Shanghai, China). All reagents used in this study were of analytical grade. Methanol and acetonitrile used for the HPLC analysis were purchased from Aladdin Co., Ltd (Shanghai, China).
9
Sildenafil Citrate Sensor Development
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Sildenafil citrate (SC, vit. V) was supplied as a gift from Pfizer, Cairo, Egypt (Pfizer Co., Cairo, Egypt, under the authority of Pfizer Inc., New York, NY, USA). Sodium tetraphenylborate (Na-TPB) and tetrahydrofuran (THF) were purchased from Fluka (Buchs, Switzerland). Phosphotungstic acid (PTA), dioctyl phthalate (DOP), O-nitrophenyl octyl ether (O-NPOE), high molecular mass PVC, and chloranil were obtained from (Sigma Aldrich, St. Louis, MO, USA). All other chemicals used were of analytical grade unless otherwise stated, and doubly-deionized water was used throughout.
10
Schizophyllum commune Bioactive Compounds
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Schizophyllum commune 5.43 was purchased from Guangdong Institute of Microbiology. RP was purchased from Good Wanjia Pharmacy Co. Ltd (Guangdong, China). Folin–Ciocalteu reagent, 2′,7′-dichlorodihydrofluorescein diacetate, gallic acid, chloranil, and catechin hydrate were purchased from Sigma Chemical Co. (St. Louis, MO, USA). All other chemicals and reagents were of analytical grade and purchased from local suppliers.
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Schizophyllum commune 5.43 was purchased from Guangdong Institute of Microbiology. RP was purchased from Good Wanjia Pharmacy Co. Ltd (Guangdong, China). Folin–Ciocalteu reagent, 2′,7′-dichlorodihydrofluorescein diacetate, gallic acid, chloranil, and catechin hydrate were purchased from Sigma Chemical Co. (St. Louis, MO, USA). All other chemicals and reagents were of analytical grade and purchased from local suppliers.
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