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6 protocols using trifluoroacetic anhydride

1

Propionic Anhydride Treatment of Cypress Wood

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Pieces of Japanese cypress (Chamaecyparis obtuse) (Yamani, Co., Ltd., Nagano, Japan) with dimensions of 5.0 mm (longitudinal direction, L) × 20 mm (radial direction, R) × 20 mm (tangential direction, T) were used as wood specimens. The specimens were cut from a larger piece with a transverse section of 20 mm (R) × 20 mm (T). The initial mass of these specimens was ~0.7 g. Methanol, propionic anhydride (PA), trifluoroacetic anhydride (TFAA), propionic acid, 4-dimethylaminopyridine (DMAP), N-methyl pyroridone, sodium hydrogen sulfate, and sulfuric acid (SA) were purchased from FUJIFILM Wako Pure Chemical Corp. (Osaka, Japan) and utilized as obtained.
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2

Synthesis of Substituted Phenylacetones

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4-Chlorophenylacetone, methylamine hydrochloride, and sodium cyanoborohydride were purchased from Tokyo Chemical Industry (Tokyo, Japan). Ortho- and m-chlorophenylacetone and trifluoroacetic anhydride (TFAA) were purchased from Wako Pure Chemical Industries (Osaka, Japan). N,O-Bis(trimethylsilyl)trifluoroacetamide (BSTFA) with 1 % trimethylchlorosilane (TMCS) was obtained from Supelco (St Louis, MO, USA). All other chemicals were of analytical grade.
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3

Pullulan-Cellulose Composite Synthesis

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Powdered pullulan (PL) was purchased from Tokyo Chemical Industry Co., Ltd, Japan. Cotton lint cellulose was purchased from Walmart Stores, Inc. Trifluoroacetic anhydride (TFAA), acetic acid, propionic acid, and all other reagents were purchased from Wako Pure Chemical Industries, Ltd, Japan, and were used without further purification.
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4

Synthesis of Aromatic Diamines for Polymeric Materials

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4-Aminocinnamic acid, pentafluoropropionic anhydride, triphenyl phosphite, 4,4′-diaminodiphenyl ether, 4,4′-diaminodiphenylmethane, 2,2-bis(4-aminophenyl)hexafluoropropane, 4,4′-diaminobenzophenone, and 4,4′-diaminodiphenyl sulfone were purchased from Tokyo Chemical Industry Co., LTD, Tokyo, Japan. Trifluoroacetic anhydride, triethylamine, and N,N-dimethylacetamide were purchased from FUJIFILM Wako Pure Chemical Corporation. Dichloromethane, methanol, ethanol, pyridine, N,N-dimethylformamide (DMF), and N-methyl-2-pyrrolidone (NMP) were purchased from Kanto Chemical Co., Inc, Tokyo, Japan. All chemicals were directly used as purchased. 4,4′-Diamino-α-truxillic acid and 4,4′-diamino-α-truxillic acid dimethyl ester were synthesized based on previous research [4 (link),5 (link),10 (link)].
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5

Synthesis of Substituted Phenylacetones

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2-Bromophenylacetone, 3-bromophenylacetone, and N,O-bis(trimethylsilyl)trifluoroacetamide (BSTFA) containing 1 % trimethylchlorosilane (TMCS) were purchased from Sigma–Aldrich (St. Louis, MO, USA), and 4-bromophenylacetone was obtained from Alfa Aesar (Heysham, UK). Methylamine hydrochloride and sodium cyanoborohydride were purchased from Tokyo Chemical Industry (Tokyo, Japan), and trifluoroacetic anhydride (TFAA) was purchased from Wako Pure Chemical Industries (Osaka, Japan). All other chemicals were of analytical grade.
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6

Synthesis and Characterization of PVA Films

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(weight-average molecular weights (M w ) = 150,000), trifluoroacetic anhydride (TFAA), acetic acid, propionic acid, butyric acid, valeric acid, hexanoic acid, octanoic acid, decanoic acid, lauric acid, ethanol, and chloroform were purchased from Wako Pure Chemicals (Tokyo, Japan). PVA films were provided by Kuraray. All reagents are used without further purification.
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