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5 protocols using ch4n2o

1

Indigo Carmine Colorimetric Analysis

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All chemicals were used of analytical grade and without further purification. Indigo Carmine (IC, 99%) also called indigotine or acid blue 74 (Scheme 1), was purchased from Sigma-Aldrich. Test solutions were made by diluting the stock solution in distilled water. NaOH (0.10 mol/L) and HCl (0.10 mol/L) were used to adjust the pH value of the IC solution. CH4N2O, (NH4)2S2O8, HNO3, sodium thiosulfate Na2S2O3, and iodine solution were purchased from Sigma-Aldrich (Schnelldorf, Germany).
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2

Synthesis of High-Surface-Area SnO2 Catalyst

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High‐surface‐area tin(IV) oxide [Brunauer‐Emmett‐Teller (BET) surface area of ≈230 m2 g−1, cassiterite crystal structure], synthesized by urea (CH4N2O, Sigma‐Aldrich) precipitation methodology, was used as a support to enhance the metal dispersion over SnO2.[51] SnO2 was chosen as the support for its semiconductor properties, as well as its durability under harsh operating conditions (e. g., pH and electric current).[52] An aqueous solution of 0.1 m SnCl4 and 10‐fold excess of urea was refluxed at 90 °C for 15 h in a round‐bottom flask. The precipitate was isolated and washed by centrifugation, dried at 120 °C for 16 h, and calcined at 200 °C for 4 h in air.
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3

Cobalt-Phosphate Complex Synthesis

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Cobalt chloride hexahydrate (CoCl2.6H2O), cobalt acetate tetrahydrate [Co(CH3COO)2.4H2O)] and di-sodium hydrogen phosphate (Na2HPO4) anhydrous were purchased from Sigma-Aldrich (San Francisco, USA). Ammonia water (NH4OH 28%) and CH4N2O were purchased from Merck (Darmstadt, Germany). In-house prepared deionized (DI) water was used throughout the experiment.
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4

Synthesis of g-C3N4/Ag-TiO2 Nanocomposites

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In this study, Ag-doped TiO2 nanoparticles were prepared using several reagents, including titanium tetra isopropoxide (C12H28O4Ti, 97%, Sigma-Aldrich, St. Louis, MO, USA), silver nitrate (AgNO3, 99%, Merck, Boston, MA, USA), glacial acetic acid (CH3COOH, 99%, Merck), nitric acid (HNO3, 69%, Merck), and absolute ethanol (C2H5OH, Sigma-Aldrich). Moreover, analytical-grade urea (CH4N2O, 99.5%, Merck) and thiourea (CH4N2S, 99%, Merck) were used to synthesize g-C3N4 nanosheets. Fabricated Ag–TiO2 nanoparticles and g-C3N4 nanosheets were used to synthesize heterostructured g-C3N4/Ag–TiO2 nanocomposites. All the chemicals and reagents were used as received without further purification. Distilled water was used in all experiments.
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5

Synthesis of Metal-Organic Complexes

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The chemicals used include Zn(NO3)2.6H2O, Fe(NO3)3.9H2O, KCl, CH4N2O (urea), NH2CH2COOH (glycine), and C10H16N2O8 (EDTA), and were purchased from Merck Company. Also, distilled water was used for the experiment.
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