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6 protocols using methyltrichlorosilane

1

Superhydrophobic Coatings via Silane Chemistry

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Methyltrichlorosilane (TCMS, 99%), TiO2 nanoparticles (P25, mixture of anatase and rutile), and hexadecane
(reagentPlus, 99%) were purchased from Aldrich. 1H,1H,2H,2H-Perfluorodecyltrichlorosilane
(PFDTS, 96%) was purchased from Alfa Aesar; n-hexane
(95%) from Fisher Chemical. Toluene, acetone, and ethanol absolute
were provided by VWR Chemicals. Ultrapure water with a resistivity
of 18.2 MΩ·cm was produced using a Sartorius Arium 611
VF water purification system. Glass slides of 26 × 76 mm2 in size were provided by Menzel-Gläser, Germany. Polystyrene
particles (negative charged, with a −COOH group on the surface)
with diameters of 270 nm, 572 nm, and 1.25 μm were prepared
using surfactant-free emulsion polymerization50 (link) and purified by several cycles of centrifugation and redispersion
in ultrapure water.
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2

Synthesis of Nanofilaments by CVD

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Surface was prepared as described in the literature34 (link). Silicon (100) wafer was cleaned by ultrasonication in alkaline solvent (Deconex 11 Universal, VWR), rinsed thoroughly by Milli-Q water, and dried under nitrogen flow. Synthesis of the nanofilaments was done by chemical vapour deposition in an in-house built gas-phase reactor operating at atmospheric pressure. The reactor was purged with dry argon followed by pre-humidified argon until the relative humidity reached ca. 30% followed by sealing the reactor and injecting methyltrichlorosilane (99%, Aldrich) through a silicone septum. methyltrichlorosilane evaporated and nanofilaments were grown onto the surface.
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3

Fabricating Hydrophobic Microfluidic Devices

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Silicone oil (Silicone Oil AP 1,000, viscosity μ=1,000 mPa s, density ρ=1.09 g cm−3; Silicone Oil AP 100, μ=100 mPa s, ρ=1.06 g cm−3; Silicone Oil AR 20, μ=20 mPa s, ρ=1.01 g cm−3), methyltrichlorosilane, fluosilicic acid, glycol, glycerine and the surfactant Tween 60 were obtained from Sigma-Aldrich Co. and used as received. methyltrichlorosilane and fluosilicic acid were used to form a hydrophobic layer on the glass capillaries. The interfacial tension between water and silicone oil was adjusted by Tween 60; the viscosity of the dispensed liquids was varied by addition of glycerine.
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4

Poplar-Derived PC Fiber Characterization

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The PC fibers (hereafter referred to as PC fibers) were collected from poplar trees at Qingdao University, Shandong. Chitosan (CS) (95% degree of deacetylation, 100–200 mPa·s) was purchased from Aladdin, Industrial Co., Ltd., Shanghai, China. Hexane, absolute alcohol, acetic acid, dichloromethane, chloroform, and ethyl acetate were purchased commercially without further purification. Methyltrichlorosilane (MTCS, 98%) was obtained from Sigma, America. Methylene blue and oil red O were both from Hefei Sifu Biotechnology Co., Ltd., Hefei, China. Several oils were purchased commercially (see Table S1).
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5

Synthesis of Antimicrobial Cotton Fabric

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Methyltrichlorosilane (MTS, ≥99%) and octadecyltrichlorosilane (OTS, >90%) were purchased from Sigma-Aldrich (St. Louis, MO). Toluene is of ACS reagent grade and ordered from Fisher Chemical (Fair Lawn, NJ). AgNO3 (99%) was purchased from Anachemia (Montreal, QC). NaBH4 (12% w/w, in 14 M NaOH) was obtained from Aldrich as well. Bleached woven cotton fabric (16.5 mg/cm2) was purchased locally. All aqueous solutions were prepared with deionized water (>18.2 MΩ • cm), produced with a Barnstead EASYpure UV/UF compact water system (Dubuque, IA).
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6

Deacetylated Cellulose Acetate Electrospun Membranes

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Cellulose acetate (Mn = 30 000
Da, 39.8 wt % acetyl content) was electrospun
into fibrous membranes from 2:1 w/w acetone/DMAc at 15 wt % and then
deacetylated in 0.05 M aqueous NaOH at ambient temperature for 24
h.44 (link) Methyltrichlorosilane (99%, Sigma-Aldrich),
methylene blue (Certified biological stain, Fisher Scientific), hexane
(Certified ACS, Fisher Scientific), decane (Certified, Fisher Scientific),
cyclohexane (HPLC grade, EM Science), acetone (Histological grade,
Fisher Scientific), xylene (GR ACS, EM Science), toluene (Certified
ACS, Fisher Scientific), pump oil (Maxima C Plus, Fisher Scientific),
DMSO (GR, EMD), and chloroform (Certified ACS, Fisher Scientific)
were used as received without further purification. All water used
was purified using a Milli-Q plus water purification system (Millipore
Corporate, Billerica, MA).
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