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2 protocols using ch3oh

1

Synthesis of Inorganic Compounds and Dye

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CsCl (99.0%), NaCl (99.5%), Bi2O3 (99.99%), BiOCl (99.5%), Nb2O5 (99.9%), H2PtCl6 (99.9%), CH3OH (99.8%), Pb(NO3)2 (99.9%), and MnSO4·5H2O (99.9%) were purchased from FUJIFILM Wako Pure Chemical Corporation. Rh(NO3)3 and Na3RhCl6 were purchased from Kanto Chemical Corporation. Sodium 2-sulfonate-1,3,5,7-tetramethyl-8-(3,4-dinitrophenyl)-4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (MS-DN-BODIPY) was synthesized according to the literature. Water was purified using a Milli-Q purification system (Direct-Q UV S.).
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2

Synthesis of Platinum and Palladium Catalysts

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Palladium acetylacetonate (Pd(acac)2, 99%), platinum acetylacetonate (Pt(acac)2, 97%), triphenylphosphine (TPP, 99%), borane tert-butylamine complex (BTB, 97%), trioctylphosphine oxide (TOPO, technical grade, 90%), oleylamine (OAm, technical grade, 70%), tetrabutylammonium bromide (TBAB, 99%) and Nafion perfluorinated ion-exchange resin (5 wt% solution in a lower aliphatic alcohol/H2O mixture that contains 15–20% water) were all purchased from Sigma-Aldrich. Acetic acid (CH3COOH, 99.7%) and methanol (CH3OH, 99%) were purchased from Wako Pure Chemical Industries Ltd. Commercial Pt/C (50% platinum on Vulcan XC-72) was purchased from Fuel Cell Store. Carbon black (Vulcan XC-72) was purchased from Moubic Inc. Polishing alumina (0.05 μm) was purchased from BAS Inc. All the chemicals were used as received without further purification.
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