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2 protocols using ethyl alcohol

1

Synthesis of Rare-Earth Doped Nanocrystals

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Materials Y2O3 (99.99%), Yb2O3 (99.99%), Er2O3 (99.99%), Tm2O3 (99.99%), Ho2O3 (99.99%), Y2O3 (99.99%), GdCl3·6H2O (99.99%), NH4F (98%), NaF (98%), and CF3COONa (97%) were purchased from Aladdin (Shanghai, China). Oleic acid (OA, 90%), 1-octadecene (ODE, 90%), and sodium oleate (Na-OA, >97%) were purchased from Sigma-Aldrich (Darmstadt, Germany). Other chemical reagents, such as NaOH (90%), ethyl alcohol (99.7%), methanol (99.5%), and n-hexane (97%), were obtained from Shanghai Lingfeng Chemical Reagent Co., Ltd. All chemicals were used as received without further purification.
Rare earth chloride (LnCl3) stock solutions of 1 M (Ln = Y, Yb) and 0.1 M (Ln = Er, Tm, and Ho) were prepared by dissolving the corresponding metal oxides in hydrochloric acid at elevated temperature. The final solutions were adjusted to pH ~6.
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2

Synthesis of UV-Curable Epoxy Resins

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SWO (46–50% linoleic
acid, 30–35% oleic acid, and 15–20% palmitic acid; iodine
value: 104–116.8 gI2/100 g) was purchased from Jiangxi
Fenglin Investment and Development Co., Ltd., China. Sodium hydroxide
(98.0%), ethyl alcohol (99.0%), and formic acid (88.0%) (all stabilized)
were purchased from Shanghai Lingfeng Chemical Reagent Co., Ltd.,
China. Hydrochloric acid (37%), ethyl acetate (99.5%), P-toluene sulfonic acid (98.5%), and H2O2 (30%)
(all stabilized) were provided by Nanjing Chemical Reagent Co., Ltd.,
China. Maleic anhydride (99.5%), triphenyl phosphate (98.0%), 2,2-dimethoxy-2-phenylacetophenone
(DMPA, 98%), and hydroquinone (99.0%) (all stabilized) were offered
by Sinopharm Chemical Reagent Co., Ltd., China. E51 epoxy resin and
tris (dimethylaminomethyl)phenol (DMP-30) were purchased from Wuxi
resins Co., Ltd., China. Glycidyl methacrylate (GMA, stabilized, 97%)
was produced by Aladdin Industrial Corporation (Shanghai). All these
chemicals were used as received.
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