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34 protocols using toluene

1

Multifunctional Polymer Conjugate Synthesis

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Methoxy poly(ethylene glycol) (mPEG45, 98%) and n-hexylamine (99%) was purchased from Sigma-Aldrich (St. Louis, MO, USA). L-Valine (L-Val, 98%) is from GL Biochemicals Co., Ltd. (Shanghai, P. R. China). Mtx (99%) and alendronate (97%) was purchased from Sigma-Aldrich (St. Louis, MO, USA). Triphosgene (98%) was purchased from Shanghai Duodian Chemical Co., Ltd. (Shanghai, P. R. China). p-toluenesulfonyl chloride (99%) was purchased from Sinopharm Chemical Reagent Co., Ltd (Shanghai, P. R. China). n-Hexane (99%), toluene (99%), ethyl acetate (99.8%), N,N-dimethylformamide (DMF, 99.5%), and diethyl ether (98%) were purchased at Beijing Chemical Plant (Beijing, P. R. China). Among them, n-hexylamine and DMF were purified by a solvent treatment system.
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Synthesis of Pt-Cu Nanoparticle Catalyst

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Chloroplatinic acid hexahydrate (H2PtCl6·6H2O, ACS reagent, ≥37.5% Pt basis), copper(II) acetylacetonate (Cu(acac)2, 97%), and oleylamine (70%, technical grade) from Sigma-Aldrich, element sulfur (S, ≥99.5%), aqueous HClO4 solution (70%, ACS reagent), and Nafion 117 solution (5% in a mixture of lower aliphatic alcohols and water) from Aladdin Reagents, methanol (99%) and toluene (99.5%) from Beijing Chemical Works, and Vulcan XC-72 carbon powders (XC-72C, BET surface area = 250 m2 g−1 and average particle size = 40~50 nm) from Cabot Corporation, were used as received. All glassware and Teflon-coated magnetic stir bars were cleaned with aqua regia, followed by copious washing with de-ionized water before drying in an oven.
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Synthesis of Platinum Nanoparticles

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α-SiC powders with average particle size of ca. 167.3 μm from Zhengzhou Xingshi Abrasive Co. Ltd., China, α-Al2O3 with average particle size of ca. 6.8 μm from Zhengzhou Yufa Abrasive Group Co. Ltd., China, kaolin and methyl cellulose from Sigma-Aldrich, Hydrogen hexachloroplatinate(IV) hydrate (H2PtCl6·6H2O, 37.5% Pt basis), sodium borohydride (NaBH4, 98%), tri-sodium citrate dihydrate (C6H5Na3O7·2H2O, ≥99%), dodecylamine (DDA, 98%), ethanol (99.5%), 2-propanol (97%), polyvinyl alcohol (98%) and toluene (99.5%) from Beijing Chemical Works, were used as received. Glassware and magnetic stirring bars are cleaned with aqua regia, followed by copious rinsing with de-ionized water before drying in an oven.
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4

Synthesis of Colloidal Lead Halide Perovskite Nanocrystals

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CH3COOCs (CsAc, 99.9%), Oleic acid (OA, 90%), Oleylamine (OLA, 70%), octadecene (ODE, 90%), ethyl acetate (99.9%), triphenylphosphine (TPP, ≥95%) and 2-(Diphenylphosphino)-biphenyl (DPB, 98%) were purchased from Aladdin, and lead iodide (PbI2, 99.999%) were obtained from Sigma-Aldrich. Toluene (99.5%) was purchased from Beijing Chemical Factory. All chemicals were used directly without further purification.
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5

Chromatographic Purification and Characterization

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Chromatographic purifications were performed by column chromatography using 0.06–0.20 mm silica gel. NMR spectra were measured with a JEOL JNM-ECA 300/600 instrument (JEOL Ltd, Tokyo, Japan). A Bruker Esquire-LC spectrometer (Bruker, Fallanden, Switzerland) was employed to measure electrospray ionization mass spectrometry (ESI-MS). TEM was performed using a Tecnai Spiri 120 KV instrument (FEI, Hillsboro, OR, USA). Rheological properties were measured by a Physica MCR301 rotary rheometer (Anton Paar, Germany) at room temperature.
Triethylamine (Et3N), benzoyl chloride, toluene, chlorobenzene, o-dichlorobenzene, bromobenzeneand, DMF were purchased from Beijing Chemical Plant (analytical purity). All solid samples requiring drying were vacuum-dried for 5–10 h before use.
p-phenylenediamine, 1-ethyl-3-(dimethylaminopropyl) carbonyl diimide hydrochloride (EDCI), trifluoroacetic acid (TFA) and isophthaloyl dichloride were purchased from J&K Scientific Co., Ltd. (Beijing, China).
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6

Synthesis and Cytotoxicity Evaluation of Imidazole Derivatives

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All reagents and starting materials were obtained commercially and were used as received without any further purification. Zn(NO3)2·6H2O was purchased from Sinopharm Chemical Reagent Co. Ltd. Imidazole-2-carbaldehyde and malonitrile were purchased from J&K Chemical Co. Toluene and N,N-dimethylformamide were purchased from Beijing Chemical Works. Dulbecco's Modified Eagle Medium (DMEM), Fetal bovine serum (FBS) were purchased from Biodee Co., 3-(4,5-dimethylthiazol-2-yl)-5-(3-carboxymethoxyphenyl)-2-(4-sulfophenyl)-2H-tetrazolium (MTS) were purchased from Promega Co.
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7

Magnetic Nanoparticle-Based Phenylarsonic Acid Analysis

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Five phenylarsonic acids (98%) were obtained from the Chinese Academy of Agricultural Sciences. The standard stock solutions were prepared by dissolving each arsenic species in pure water at an arsenic concentration equivalent to that of 1 mg/mL phenylarsonic acids and stored at 4°C in the dark.
Reagents for preparing magnetic nanoparticles: FeCl2⋅4H2O and FeCl3⋅6H2O (analytical reagent grade) were purchased from Tianjin Guangfu Fine Chemical Research Institute. Sodium chloroacetate (98%) was bought from Alfa Aesar. α-cyclodextrin (98%) was purchased from Beijing Dilang Biochemical Technology Co., Ltd., China. Other reagents including methanol, ethanol, acetone, toluene, formic acid and sodium hydroxide were of analytical reagent grade and all bought from Beijing Chemical Plant. The water used throughout the experiment was purified using a Milli-Q water purification system (Millipore, Germany).
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8

Synthesis of Platinum Nanoparticle Catalysts

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Potassium tetrachloroplatinate(II) (K2PtCl4, 98%), silver nitrate (AgNO3, 99%), aqueous HClO4 solution (70%, ACS reagent), and Nafion 117 solution (5% in a mixture of lower aliphatic alcohols and water) from Aladdin Reagents, bis(p-sulfonatophenyl)phenylphosphane dihydrate dipotassium salt (BSPP, 97%) from Strem Chemicals, oleylamine (70%, technical grade) from Sigma-Aldrich, methanol (99%), ethanol (99.5%), and toluene (99.5%) from Beijing Chemical Works, and Vulcan XC-72 carbon powders (XC-72C, BET surface area = 250 m2 g−1 and average particle size = 40 ~ 50 nm) from Cabot Corporation, were used as received. All glassware and Teflon-coated magnetic stir bars were cleaned with aqua regia, followed by copious washing with de-ionized water before drying in an oven.
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9

Synthesis of Cr(III)-based Metal-Organic Framework

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Chromium (III) nitrate [Cr (NO3)3·9H2O], 1,4-benzene dicarboxylic acid (H2BDC), and hydrofluoric acid (HF) were purchased from Aladdin Industrial Co. Ltd (Shanghai, China), and sodium citrate was obtained from Alfa Aesar. Toluene, chloroform, and formaldehyde were bought from Beijing Chemical Works.
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Synthesis of Platinum, Gold, and Palladium Nanoparticle Catalysts

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The following materials were used as received: potassium tetrachloroplatinate(II) (K2PtCl4; 98%), silver nitrate (AgNO3; 99%), gold(III) chloride trihydrate [HAuCl4·3H2O; ACS reagent; 49.0% Au basis), palladium(II) acetylacetonate [Pd(acac)2; 99%], acetic acid (CH3COOH; 98%), sulfur powder (S; chemical grade), and oleylamine (primary amine; 95.4%) from J&K Scientific; aqueous HClO4 solution (ACS reagent; 70%) and Nafion 117 solution (5% in a mixture of lower aliphatic alcohols and water) from Aladdin Reagents; ethanol (99%), methanol (99%), and toluene (99.5%) from Beijing Chemical Works; and Vulcan XC 72 carbon powders (XC 72C) with a BET (Brunauer–Emmett–Teller) surface area of ca. 250 m2 g−1 and average particle sizes of ca. 40 to 50 nm from Cabot Corporation. Commercial Pd/C and Pt/C catalysts were purchased from Johnson Matthey. All glassware and Teflon-coated magnetic stir bars were cleaned with aqua regia, followed by copious washing with deionized water before drying in an oven.
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