commercially and were used as received. Tetrachloroauric acid (trihydrate,
HAuCl4·3H2O, >99.9%), silver nitrate
(AgNO3, 99.9999%), sodium citrate dihydrate, HOC(COONa)(CH2COONa)2·2H2O (>99.9%), sodium
borohydride
(powder, NaBH4, 98%), and rhodamine 6G (R6G, 99%) were
purchased from Merck. Nitrogen gas (purity 99.999%) was purchased
from Air Products (Poland). Sodium hydroxide (NaOH) was purchased
from Avantor Performance Materials (Poland). Hydrogen peroxide (H2O2, 30%) and ammonia solution (NH4OH,
25%) were purchased from Chempur (Poland). Potassium bromide (KBr,
spectroscopic grade) was purchased from Pike Technologies. All solutions
were prepared using distilled water (Milli-Q, 18.2 MΩ•cm).
Solutions for nanoparticle synthesis were deoxygenated by bubbling
with nitrogen gas.