The largest database of trusted experimental protocols

8 protocols using 2 phenylpyridine

1

Synthesis and Characterization of Organometallic Complexes

Check if the same lab product or an alternative is used in the 5 most similar protocols
All chemical compounds: vanadyl acetylacetonate, 2-phenylpyridine, 4,4′-dimethoxy-2,2′-bipyridine, toluene, dimethylsulfoxide, dipicolinic acid, modified methylaluminoxane (7% aluminum in toluene), 2-propen-1-ol, 2-chloro-2-propen-1-ol, and norbornene were purchased from Merck, Darmstad, Germany. The purity of reagents was in the range 97–100%.
+ Open protocol
+ Expand
2

Synthesis and Characterization of Vanadium Complexes

Check if the same lab product or an alternative is used in the 5 most similar protocols
All chemical compounds: vanadyl acetylacetonate, vanadyl sulfate pentahydrate, 1,10-phenanthroline, thiodiacetate, oxydiacetic acid, 2-phenylpyridine, dipicolinic acid, 4,4′-dimethoxy-2,2′-bipyridine, 2,2′-bipyridine, n-hexane, ethylaluminium dichloride, dimethyl sulfoxide, 3-buten-2-ol, allyl alcohol, 2-chloro-2-propen-1-ol and 2,3-dibromo-2-propen-1-ol were purchased from Merck, Darmstad, Germany. The purity of the reagents was in the range of 97–100%.
+ Open protocol
+ Expand
3

Synthesis of Pt(II) Complexes with Bidentate Ligands

Check if the same lab product or an alternative is used in the 5 most similar protocols
Reagents were used as received unless otherwise specified. All solvents used were of analytical grade or higher and purchased from Labserv (Mandaluyong, Philippines), Chem-Supply (Gillman, SA, USA), or Merck Chemicals (Darmstadt, Germany). Potassium tetrachloroplatinate (K2PtCl4) was purchased from Precious Metals Online. 2-phenylpyridine, benzo(h)quinoline, dibenzo(f,h)quinoline, (1S,2S)-(+)-1,2-diaminocyclohexane, and (1R,2R)-(+)-1,2-diaminocyclohexane were purchased from Sigma-Aldrich. Methanol, ethanol, diethyl ether, and methoxy-ethanol were obtained from Honeywell. Deuterated solvents d6-dimethylsulphoxide (DMSO-d6, 99.9%) and deuterium oxide (D2O, 99.9%) were purchased from Cambridge Isotope Laboratories (Tewksbury, MA, USA).
+ Open protocol
+ Expand
4

Synthesis and Biological Evaluation of Pyridine Derivatives

Check if the same lab product or an alternative is used in the 5 most similar protocols
2-Phenylpyridine, 4-pyridinemethanol, 4-dimethylaminopyridine,
methylnicotinate, N,N-diethylnicotinamide, 3-picoline,
4-picoline, 3-acetylpyridine, 9-ethylguanine, and 9-methyladenine
were purchased from Sigma-Aldrich. For the biological experiments,
RPMI-1640 medium, fetal bovine serum, l-glutamine, penicillin/streptomycin
mixture, trypsin/EDTA, and phosphate-buffered saline (PBS) were purchased
from PAA Laboratories GmbH. Cisplatin CDDP (≥99.9%), trichloroacetic
acid (≥99%), sulforhodamine B (75%), sodium phosphate monobasic
monohydrate (≥99%), sodium phosphate dibasic heptahydrate (≥99%),
acetic acid (≥99%), staurosporine, propidium iodide (>94%),
and RNase A were obtained from Sigma-Aldrich. Complex [(η5-Cpxph)Ir(phpy)Cl] was prepared according to reported
methods.6d
+ Open protocol
+ Expand
5

Synthesis of Cyclometalated Iridium and Rhodium Complexes

Check if the same lab product or an alternative is used in the 5 most similar protocols
The starting materials RhCl3·3H2O, IrCl3·3H2O, 2-phenylpyridine, 8-aminoquinoline, 1-napthylamine and 1-methyl-2-imidazolecarboxaldehyde were purchased from Sigma–Aldrich and used without further purification. All the solvents were dried by usual methods prior to use. The cyclometalated iridium(III) and rhodium(III) chloro bridged dimer [Ir(ppy)2Cl]2 and [Rh(ppy)2Cl]2 was prepared according to the literature methods [74 –75 ].
+ Open protocol
+ Expand
6

Iridium-Based Organometallic Complexes

Check if the same lab product or an alternative is used in the 5 most similar protocols
All solvents were of analytical grade. All buffer components were of biological grade and used as received. Iridium chloride hydrate, p-tolualdehyde and 2-acetylpyridine, 2-phenyl-pyridine (ppy), cisplatin, rapamycin, carbonyl cyanide-4-(trifluoromethoxy)-phenylhydra-zone (FCCP) and carbonyl cyanide m-chlorophenyl-hydrazone (CCCP) were bought from Sigma Aldrich (USA). MitoTracker Red FM (MTR) was purchased from Life Technologies (USA). Microanalysis (C, H, and N) was performed using a Vario EL elemental analyzer. 1H NMR spectra were recorded on a Bruker ADVANCE AV 400 NMR spectrometer using (CD3)2SO as a solvent at room temperature and TMS as the internal standard. Electrospray mass spectra (ES-MS) were recorded on a LCQ system (Finnigan MAT, USA). The spray voltage, tube lens offset, capillary voltage and capillary temperature were set at 4.50  kV, 30.00 V, 23.00 V and 200 °C, respectively, and the quoted m/z values refer to the major peaks in the isotope distribution. UV–Vis spectra were recorded on a Perkin-Elmer Lambda 850 spectrophotometer. Emission spectra were recorded on a Perkin-Elmer LS 55 spectrofluorophotometer at room temperature.
+ Open protocol
+ Expand
7

Synthesis of Cyclometalated Iridium(III) Complexes

Check if the same lab product or an alternative is used in the 5 most similar protocols
The starting materials IrCl3·3H2O, 2-phenylpyridine, 1,10-phenanthroline, aldehydes, and n-octanol were purchased from Sigma-Aldrich and used without further purification. All the solvents were dried by usual methods prior to use. The cyclometalated iridium(iii) chloro bridged dimer [Ir(ppy)2Cl]2 was prepared according to the methods described in the literature.46
+ Open protocol
+ Expand
8

Synthesis and Characterization of Iridium(III) Complexes

Check if the same lab product or an alternative is used in the 5 most similar protocols
Iridium (III) chloride hydrate, 2-phenyl pyridine and 2-ethoxyethanol (Sigma-Aldrich), 1phenyl-3-methyl-2-pyrazoline-5-one (Merck) were used as received. The organic solvents and other reagents were used after purification using the standard protocols. 43, 44 All the reactions were carried out in nitrogen atmosphere with the Schlenk line. The nuclear magnetic resonance (NMR) spectra were collected using a Bruker 400 MHz Spectrometer (Fig. S7-S9). Deuterated dimethyl sulfoxide (DMSO-d 6 ) was used as solvent for the measurement and calibration for the residual peak of the deuterated solvent (δ 2.52 for 1 H NMR). The high resolution mass spectra (HR-MS) of the complexes were taken with the Shimadzu LCMS-2010 Spectrometer (Fig. S10).
The FT-IR Spectra were taken with the Infrared Spectrophotometer MB-3000 (Fig. S11).
+ Open protocol
+ Expand

About PubCompare

Our mission is to provide scientists with the largest repository of trustworthy protocols and intelligent analytical tools, thereby offering them extensive information to design robust protocols aimed at minimizing the risk of failures.

We believe that the most crucial aspect is to grant scientists access to a wide range of reliable sources and new useful tools that surpass human capabilities.

However, we trust in allowing scientists to determine how to construct their own protocols based on this information, as they are the experts in their field.

Ready to get started?

Sign up for free.
Registration takes 20 seconds.
Available from any computer
No download required

Sign up now

Revolutionizing how scientists
search and build protocols!