Platinum atr single reflection

All manipulations were performed under aerobic conditions, using materials (reagent grade) and solvents as received unless otherwise noted. The Schiff base ligand sacbH₂ was prepared, purified, and characterized as described elsewhere [20 (link),21 (link)]. Infrared spectra were recorded in the solid state on a Bruker’s FT-IR spectrometer (ALPHA’s Platinum ATR single reflection) in the 4000–400 cm⁻¹ range. Elemental analyses (C, H, and N) were performed on a Perkin-Elmer 2400 Series II Analyzer. Variable-temperature magnetic susceptibility studies were performed, using an MPMS5 Quantum Design magnetometer operating at 0.03 T in the 300–2.0 K range. Diamagnetic corrections were applied to the observed paramagnetic susceptibility, using Pascal’s constants [22 (link)].

All manipulations were performed under aerobic conditions using materials (reagent grade) and solvents as received unless otherwise noted. The Schiff base ligand nacbH₂ was prepared, purified and characterized as described elsewhere [21 (link),22 (link)]. Infrared spectra were recorded in the solid state on a Bruker’s FT-IR spectrometer (ALPHA’s Platinum ATR single reflection, in the 4000–400 cm⁻¹ range. Elemental analyses (C, H and N) were performed on a Perkin-Elmer 2400 Series II Analyzer. Magnetic susceptibility studies were performed at the temperature range 1.9-300 K using a Quantum Design MPMS XL-7 SQUID magnetometer equipped with a 7 T magnet. Pascal’s constants were used to estimate the diamagnetic correction, which was subtracted from the experimental susceptibility to give the molar paramagnetic susceptibility (χ_M) [43 (link)].