All the chemicals and solvents were obtained commercially and used without further purification. Pd(ii ) acetylacetonate and borane–triethylamine complex were purchased from Sigma-Aldrich. n-Octadecane and TOPO were purchased from Aldrich. 1-Dodecanol was purchased from Nakarai Tesque, Inc. Potassium hydroxide (KOH), potassium carbonate (K2CO3), CTAC, oleylamine, iodobenzene and palladium-activated carbon (Pd 5 wt%, Pd/C) were purchased from Wako Pure Chemical Industries, Ltd. Hydrogen chloride methanol solution (6.6 w/w%), 4-iodophenol, phenylboronic acid and 4-methylphenylboronic acid were purchased from Tokyo Chemical Industries Co., Ltd.
1 dodecanol
Manufactured by Nacalai Tesque
1-Dodecanol is a long-chain primary alcohol with the chemical formula CH3(CH2)10CH2OH. It is a colorless, waxy solid at room temperature. 1-Dodecanol is commonly used as a reagent in organic synthesis and as an intermediate in the production of other chemical compounds.
Automatically generated - may contain errors
Lab products found in correlation
2 protocols using 1 dodecanol
1
Hydrothermal Synthesis of Metal Nanoparticles
2
Synthesis of Diazoacetates and Reagents
Check if the same lab product or an alternative is used in the 5 most similar protocols
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Tetrahydrofuran
(THF) and toluene were dried
over a Na/K alloy and Na, respectively, and distilled before use.
CH2Cl2 was dried over CaH2 and used
without further purification. Cu(acac)2 (TCI; >97%),
Rh2(OAc)4 (AZmax; 99%), RuCl(cod)Cp* (Sigma-Aldrich),
Grubbs first catalyst (Sigma-Aldrich; 97%), 1-hexanol (TCI; >98.0%),
diisopropyl azodicarboxylate (Wako; >90%), triphenylphosphine (Nacalai;
>98.0%), MgCl2 (Nacalai; >97.0%), 1,8-diazabicyclo[5,4,0]-7-undecene
(DBU) (Nacalai; >97.0%), and 1-dodecanol (TCI; >99.0%) were
used as
received without further purification. Tosyl azide,27 4,4′-biphenylenediacetic acid,28 (link) 1,4-phenylenediacetic acid,28 (link),29 (link) and 2,2′-(9,9-dioctyl-9H-fluorene-2,7-diyl)diacetonitrile30 (link) were prepared following the procedures reported in the literatures.
Methyl 2-diazo-2-phenylacetate17 (link) was prepared
using tosyl azide as a diazo transfer agent following a reported general
procedure for this type of diazoketones. Caution! Extra care must
be taken for the preparation and handling of the diazoacetates because
of their potential explosiveness.
(THF) and toluene were dried
over a Na/K alloy and Na, respectively, and distilled before use.
CH2Cl2 was dried over CaH2 and used
without further purification. Cu(acac)2 (TCI; >97%),
Rh2(OAc)4 (AZmax; 99%), RuCl(cod)Cp* (Sigma-Aldrich),
Grubbs first catalyst (Sigma-Aldrich; 97%), 1-hexanol (TCI; >98.0%),
diisopropyl azodicarboxylate (Wako; >90%), triphenylphosphine (Nacalai;
>98.0%), MgCl2 (Nacalai; >97.0%), 1,8-diazabicyclo[5,4,0]-7-undecene
(DBU) (Nacalai; >97.0%), and 1-dodecanol (TCI; >99.0%) were
used as
received without further purification. Tosyl azide,27 4,4′-biphenylenediacetic acid,28 (link) 1,4-phenylenediacetic acid,28 (link),29 (link) and 2,2′-(9,9-dioctyl-9H-fluorene-2,7-diyl)diacetonitrile30 (link) were prepared following the procedures reported in the literatures.
Methyl 2-diazo-2-phenylacetate17 (link) was prepared
using tosyl azide as a diazo transfer agent following a reported general
procedure for this type of diazoketones. Caution! Extra care must
be taken for the preparation and handling of the diazoacetates because
of their potential explosiveness.
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