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2 protocols using iodobenzene

1

Hydrothermal Synthesis of Metal Nanoparticles

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All the chemicals and solvents were obtained commercially and used without further purification. Pd(ii) acetylacetonate and borane–triethylamine complex were purchased from Sigma-Aldrich. n-Octadecane and TOPO were purchased from Aldrich. 1-Dodecanol was purchased from Nakarai Tesque, Inc. Potassium hydroxide (KOH), potassium carbonate (K2CO3), CTAC, oleylamine, iodobenzene and palladium-activated carbon (Pd 5 wt%, Pd/C) were purchased from Wako Pure Chemical Industries, Ltd. Hydrogen chloride methanol solution (6.6 w/w%), 4-iodophenol, phenylboronic acid and 4-methylphenylboronic acid were purchased from Tokyo Chemical Industries Co., Ltd.
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2

Synthesis of Imidazolium Bromide MS Precursor

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Imidazolium bromide as a MS precursor was synthesized according to the literature method 24) . Pd (OAc) 2 (> 97.0%) , NaBr (99.9%) , dimethyl sulfoxide (99.0%) , trimethylamine (99.0%) , dichloromethane (99.0%) , methanol (99.5%) , chloroform (99.0%) , iodobenzene (97.0%) , chlorobenzene (99.0%) , and 4-iodoacetophenone (90.0%) were purchased from Wako pure Chemical Industries, Ltd., Japan. Bromobenzene (99.0%) , p-iodoanisole (96.0%) , 4-iodobenzoic acid (>98.0%) , and methyl acrylate (> 99.0%) were procured from Tokyo Chemical Industry Co., Ltd., Japan. All chemicals were used as received.
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