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Nickel 2 acetylacetonate

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Nickel (II) acetylacetonate is a chemical compound with the formula Ni(acac)2. It is a green crystalline solid that is commonly used as a precursor in the synthesis of various nickel-containing materials.

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Lab products found in correlation

Benzyl ether, by Merck Group (2 mentions) D glucose, by Merck Group (1 mentions) Nafion, by Merck Group (1 mentions) Calcium chloride dihydrate, by Thermo Fisher Scientific (1 mentions) Adenosine, by Merck Group (1 mentions) Guanosine, by Merck Group (1 mentions) Cytosine, by Merck Group (1 mentions) Cytidine, by Merck Group (1 mentions) Guanine, by Merck Group (1 mentions) Iron 3 acetylacetonate, by Thermo Fisher Scientific (1 mentions) Potassium phosphate, by Merck Group (1 mentions) Ethanol, by Merck Group (1 mentions) N n dimethylformamide (dmf), by Thermo Fisher Scientific (1 mentions) Acetone, by Merck Group (1 mentions) Phenylboronic acid, by Merck Group (1 mentions) 4 bromobenzaldehyde, by Merck Group (1 mentions) Diethanolamine, by Merck Group (1 mentions) Sodium hydroxide (naoh), by Beijing Chemical Works (1 mentions) Nafion solution, by Thermo Fisher Scientific (1 mentions) Toluene, by Beijing Chemical Works (1 mentions)

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Nickel acetylacetonate (2 citations)

5 protocols using nickel 2 acetylacetonate

1

Synthesis of Adenosine Derivatives

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Adenine (> 99%) and D‐(−)‐ribose (analytical grade) were purchased from TCI EUROPE N.V., and Serva, respectively. Adenosine, D‐(+)‐glucose, cytosine, cytidine, guanine, and guanosine were purchased from Aldrich. Calcium chloride‐dihydrate (≥ 99%) was purchased from Fisher Chemicals. Iron (III)‐acetylacetonate (99+%) and nickel (II)‐acetylacetonate (96%) were from Acros, respectively. Nafion (5 wt. % in a mixture of lower aliphatic alcohols and water, containing 45% water) was from Aldrich. The chemicals were all used as received. The RuO2 and IrO2 were purchased from Aldrich, 99.9%
Li C., Lepre E., Bi M., Antonietti M., Zhu J., Fu Y, & López‐Salas N. (2023). Oxygen‐Rich Carbon Nitrides from an Eutectic Template Strategy Stabilize Ni, Fe Nanosites for Electrocatalytic Oxygen Evolution. Advanced Science, 10(22), 2300526.
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2

Synthesis of Pyridylphenylene Polymer

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Nickel (II) acetylacetonate (Acros Organics, 97%), benzyl ether (Sigma-Aldrich, 98%), potassium phosphate (Merck, 99%), phenylboronic acid (Merck, 95%), and 4-bromobenzaldehyde (Merck, 99%) were used as received. N,N-dimethylformamide (Acros Organics, 99.8%, extra dry) was used without further purification. Acetone (99.5%) and ethanol (99.8%) were purchased from Sigma-Aldrich and used without purification. Hyperbranched pyridylphenylene polymer (PPP) was synthesized as described in [39 (link)]. According to size-exclusion chromatography (SEC), the average molecular weight of the polymer was 23,403 g/mol.
Sorokina S.A., Kuchkina N.V., Ezernitskaya M.G., Bykov A.V., Vasiliev A.L., Efimov N.N, & Shifrina Z.B. (2022). Ni Nanoparticles Stabilized by Hyperbranched Polymer: Does the Architecture of the Polymer Affect the Nanoparticle Characteristics and Their Performance in Catalysis?. International Journal of Molecular Sciences, 23(22), 13874.
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3

Perovskite Solar Cell Fabrication

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Fluorine-doped tin oxide (FTO, 1.5 cm × 1.5 cm) was purchased from OPV TECH LTD. Methylammonium iodide (MAI) was purchased from Dyesol Ltd. Lead iodide (PbI2, extra dry, 99.999%) and nickel(ii) acetylacetonate (95%) were purchased from Alfa Aesar Ltd. N,N-Dimethylformamide (DMF, anhydrous, 99.8%), dimethyl sulfoxide (DMSO, anhydrous, 99.8%) and chlorobenzene (CB, extra dry, 99.5%) were purchased from Acros Ltd. 2,2,2-Trifluoroethanol (TFE, 99.5%) was purchased from Energy chemical Ltd. [6,6]-Phenyl-C61-butyric acid methyl ester (PC61BM) was purchased from NANO-C Tech Ltd. Anisole (anhydrous, 99.7%) was purchased from Aladdin Ltd. Diethanol amine (DEA, 99%) was purchased from Sigma-Aldrich Ltd.
Zhao R., Zhang K., Zhu J., Xiao S., Xiong W., Wang J., Liu T., Xing G., Wang K., Yang S, & Wang X. (2021). Surface passivation of organometal halide perovskites by atomic layer deposition: an investigation of the mechanism of efficient inverted planar solar cells. Nanoscale Advances, 3(8), 2305-2315.
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4

Synthesis of Pd/C and Ni Catalysts

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Palladium (II) acetylacetonate (Pd(acac)2, 99%), nickel (II) acetylacetonate (Ni(acac)2, 95%), trioctylphosphine (TOP) (90%), Nafion solution (5 wt%), Palladium on activated carbon (Pd/C, 10 wt%) were purchased from Alfa Aesar. Oleylamine (OAm) (>70%) was purchased from Sigma Aldrich. NaOH, ethanol, cyclohexane, toluene, n-hexane and isopropanol were obtained from Beijing Chemical Reagent Company. Ketjen Black was obtained from Shanghai HESEN Electric Company. Milli-Q ultrapure water was utilized through all the experiments.
Chen L., Lu L., Zhu H., Chen Y., Huang Y., Li Y, & Wang L. (2017). Improved ethanol electrooxidation performance by shortening Pd–Ni active site distance in Pd–Ni–P nanocatalysts. Nature Communications, 8, 14136.
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5

Synthesis and Characterization of Pt/Al2O3 Catalysts

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Platinum (II) acetylacetonate (Pt(acac)2, 97%) and nickel (II) acetylacetonate (Ni(acac)2, anhydrous, >95%) were purchased from Alfa Aesar. Cobalt (III) acetylacetonate (Co(acac)3, 99.95%) was purchased from Strem Chemicals, and 1,2-hexadecanediol (90%), benzyl ether (99%), oleylamine (70%), and oleic acid (99+%) were purchased from Sigma Aldrich. γ-phase aluminum oxide pellet (43832) was purchased from Alfa Aesar and kept under ball milling conditions for 48 h before further use. Vulcan carbon XC-72 was obtained from Cabot. Overall, 5.0 wt% or 1.0 wt% Pt/Al2O3 catalysts used in this work were also purchased from Alfa Aesar as the control catalysts. Gases of propane (1 vol% balanced by Argon), O2 (20 vol% balanced by N2), and H2 (99.99%) gases were purchased from Airgas. All chemicals were used as received.
Shan S., Li J., Maswadeh Y., O’Brien C., Kareem H., Tran D.T., Lee I.C., Wu Z.P., Wang S., Yan S., Cronk H., Mott D., Yang L., Luo J., Petkov V, & Zhong C.J. (2020). Surface oxygenation of multicomponent nanoparticles toward active and stable oxidation catalysts. Nature Communications, 11, 4201.
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