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8 protocols using cadmium oxide

1

Synthesis of Colloidal Nanocrystals

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Cadmium oxide (CdO, 99.99%), copper(I) chloride
(CuCl, 99.999%), trioctylphosphine oxide (TOPO, 99%), trioctylphosphine
(TOP, 97%), and selenium powder (Se, 99.99%) were purchased from Strem
Chemicals. Cadmium chloride (CdCl2, 99.99%), iodine (I2, 99.99%), iron(III) chloride (FeCl3, 98%), oleylamine
(70%), tetrakis(acetonitrile)copper(I) hexafluorophosphate, and sulfur
powder (S, 99.9%) were purchased from Sigma-Aldrich. Copper(II) chloride
(CuCl2, 99%) was purchased from Alfa Aesar. Octadecylphosphonic
acid (ODPA) and hexylphosphonic acid (HPA) were purchased from Polycarbon
Industries. Cerium(IV) ammonium nitrate (>98.5%), nitric acid (HNO3, 67−69%), anhydrous toluene and methanol were purchased
from Carlo Erba reagents.
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2

Synthesis of Semiconductor Nanocrystals

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Cadmium oxide (CdO, 99.5%), trioctylphosphine
oxide (99%), trioctylphosphine (TOP, 97%), selenium powder (Se, 99.99%),
and lead(II) acetate trihydrate (Pb(CH3CO2)2·3H2O, 99.999%) were purchased from Strem
Chemicals. Octadecylphosphonic acid (99%) was purchased from Polycarbon
Industries. Copper(II) acetylacetonate (Cu(acac)2, 97%),
hexadecylamine (98%), tetrakis(acetonitrile)copper(I) hexafluorophosphate
(99.99%), octadecene (technical grade, 90%), 1-dodecanethiol (≥98%),
oleylamine (70%), tetrachloroethylene (≥99%), anhydrous chloroform,
methanol, toluene, and tetrahydrofuran were purchased from Sigma-Aldrich.
All chemicals were used without any further purification.
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3

Synthesis of Colloidal Nanocrystals

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Selenium powder (Se, 99.99%), trioctylphosphine oxide (TOPO, 99%), tetradecylphosphonic acid (TDPA), 1- thioglycolic acid (TGA), tetramethylammonium hydroxide (TMAH), tetrabutylammonium hexafluorophosphate (NBu4PF6, 98%), and Pt foil (0.125–0.135 mm thickness, 99.9%) were purchased from Sigma-Aldrich; cadmium oxide (CdO, 99.99%) and trioctylphosphine (TOP>85%) were purchased from Strem chemicals; lead nitrate (Pb(NO3)2, 99.3%) was purchased from Fisher; all chemicals were of analytical grade and used without further purification.
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4

Synthesis of CdS Quantum Dots

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Trioctylphosphine oxide (TOPO, 90%), tetranitromethane (TNM), thioglycolic acid (98%), and 11-mercaptoundecanoic acid (MUA, 95%) were purchased from Aldrich. Cadmium oxide (99.999%), sulfur (99.999 %) and titanium (IV) oxide nanopowder were purchased from Strem Chemicals. 1-tetradecylphosphonic acid (TDPA, 98%) was purchased from Alfa-Aesar, and tetramethylammonium hydroxide pentahydrate (TMAH, 97%), methylene blue (MB) and methyl orange (MO) were purchased from ACROS. Oleylamine (>40%) was purchased from TCI America. Toluene, methanol, butanol and ethyl acetate were purchased from Mallinckrodt. TOPO was distilled before use; all the other chemicals were used as received.
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5

Synthesis of Colloidal Nanoparticles

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Oleylamine (OLAM, 70%), oleic acid (OLAC,
90%), 1-octadecene (ODE, 90%), toluene (>99%), ethanol (99.8%),
and
acetone (99.5%) were all purchased from Sigma-Aldrich and used as
received. Copper chloride (CuCl, 99.999%), bismuth chloride (BiCl3, >98%), cadmium oxide (CdO, 99.99%), selenium (Se 99.99%),
trioctylphosphine oxide (TOPO, 99%), and trioctylphosphine (TOP, 97%)
were purchased from Strem Chemicals.
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6

Colloidal Semiconductor Nanocrystal Synthesis

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Cadmium
nitrate tetrahydrate (99.997%), sodium myristate (99%), cadmium(II)
acetate (Cd(OAc)2; 99.995%), cadmium acetate dihydrate
(Cd(OAc)2·2H2O), octadecene (ODE; 90%),
oleic acid (90%), trioctylphosphine (TOP; 90%), propionic acid (99.5%)
methanol (99.9%), and hexane (95%) were purchased from Sigma-Aldrich.
Cadmium oxide (99.999%) sulfur (S; 99.9%), selenium powder (Se; 99.99%),
and tellurium (Te; 99.99%) were purchased from Strem Chemicals.
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7

Synthesis of Colloidal Nanocrystals

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Octadecene (ODE, Alpha Aesar, 90%), cadmium acetate dihydrate (Cd(OAc)2.2H2O,Sigma-Aldrich, 98%), cadmium oxide (CdO, Strem Chemicals, 99.99%), myristic acid (Aldrich, >99%), oleic acid (OA, Alpha Aesar 90%), trioctylphosphine (TOP, Alpha Aesar, 90%), selenium (Strem Chemicals 99.99%), sulfur (Sigma-Aldrich), tellurium (Alpha Aesar, 18 + 60 mesh, 99.999%), hexane (VWR Chemicals), ethanol absolute (VWR Chemicals), methanol (VWR Chemicals)
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8

Synthesis of Colloidal Quantum Dots

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trioctylphosphine oxide (TOPO, 99%), trioctylphosphine (TOP, 97%), cadmium oxide (CdO, 99.999%), sulfur powder (99%), and selenium powder (99.99%) were purchased from Strem Chemicals. cadmium oxide (CdO, 99.5%) was purchased from Sigma-Aldrich. Octadecylphosphonic acid (ODPA, 99%) and hexylphosphonic acid (HPA, 99%) were purchased from Polycarbon Industries.
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