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2 protocols using copper 1 chloride

1

Synthesis of Colloidal Nanocrystals

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Cadmium oxide (CdO, 99.99%), copper(I) chloride
(CuCl, 99.999%), trioctylphosphine oxide (TOPO, 99%), trioctylphosphine
(TOP, 97%), and selenium powder (Se, 99.99%) were purchased from Strem
Chemicals. Cadmium chloride (CdCl2, 99.99%), iodine (I2, 99.99%), iron(III) chloride (FeCl3, 98%), oleylamine
(70%), tetrakis(acetonitrile)copper(I) hexafluorophosphate, and sulfur
powder (S, 99.9%) were purchased from Sigma-Aldrich. Copper(II) chloride
(CuCl2, 99%) was purchased from Alfa Aesar. Octadecylphosphonic
acid (ODPA) and hexylphosphonic acid (HPA) were purchased from Polycarbon
Industries. Cerium(IV) ammonium nitrate (>98.5%), nitric acid (HNO3, 67−69%), anhydrous toluene and methanol were purchased
from Carlo Erba reagents.
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2

Synthesis of Copper-Platinum-Selenium Nanostructures

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Copper(I) chloride (CuCl, 99.999%-Cu), platinum(II) acetyl-acetonate (Pt(acac) 2 , 98%) and selenium powder (Se, 99.99%) were obtained from Strem Chemicals. Oleylamine (OLAm, 70%), 1-octadecene (ODE, 90%), oleic acid (OLAc, ≥99%), 2-propanol (≥99.9%), toluene (99.9%) and ethanol (HPLC, 99.999%) were purchased from Sigma-Aldrich. Melamine (99%) was purchased from Alfa Aesar. All the reagents and solvents were used without further purification, except for the ODE and OLAm which had been previously degassed under vacuum for 3 h at 120 °C.
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