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4 protocols using antimony trichloride

1

Synthesis of Tin(II) Halides and Antimony Trichloride

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Tin(ii) bromide, tin(ii) iodide, antimony trichloride, N,N′-dimethylethylenediamine (99%), 1-butyl-1-methylpyrrolidinium chloride, γ-butyrolactone (GBL, ≥99%), hydrobromic acid (48 wt% in H2O) and hydriodic acid (55%) were purchased from Sigma-Aldrich. Dichloromethane (DCM, 99.9%), dimethylformamide (DMF, 99.8%), toluene (anhydrous, 99.8%) and ethyl ether (stabilized with ∼1 ppm BHT) were purchased from VWR. Acetone (HPLC grade) was purchased from EMD Millipore. All reagents and solvents were used without further purification unless otherwise stated.
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2

Synthesis of Colloidal Nanostructures

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Bismuth trichloride (98%, Sigma-Aldrich), antimony trichloride (99%, Sigma-Aldrich), carbon disulphide (99.9%, Sigma-Aldrich), piperidine (99.5% Sigma-Aldrich), oleylamine (98% Sigma-Aldrich), 1-dodecanethiol (98% Sigma-Aldrich), ethanol (99.8% Sigma-Aldrich), chloroform (99.8% Sigma-Aldrich), chloroform-d (99.8% Sigma-Aldrich), and sodium hydroxide (97% Fisher Scientific) were used as supplied without further purification.
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3

Fabrication of FTO-based Optoelectronic Devices

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The following materials
were used: FTO substrate (7 Ω sq–1), titanium(IV)
tetraisopropoxide (TTIP)—99 wt % (Acros Organics), acetylacetone—99
wt % (Acros Organics), ethanol—96.6 vol % (Estonian Spirit),
methanol—99.9 vol % (Sigma-Aldrich), antimony trichloride—99.99
wt % (Sigma-Aldrich), thiourea—99 wt % (Sigma-Aldrich), chlorobenzene—99.5
vol % (Sigma-Aldrich), poly(3-hexyl-thiophene-2,5-diyl) (P3HT)—100
kDa, >90% regioregular (Sigma-Aldrich), and materials related to
HTM
synthesis as mentioned in the S1. The materials
were used as received.
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4

Synthesis of Lipid-Polymer Nanoparticles

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1,2-distearoyl-sn-glycero-3-phosphoethanolamineN-[amino(polyethylene glycol)2000] (DSPE-PEG) were purchased from Avanti Polar Lipids (USA). Dodecylthiol (DDT, 99.9%), Oleylamine (OLA, 70%), Oleic acid (OA, 90%), Technical grade octadecene (ODE, 90%), tert-Butylamine borane (99%), and antimony trichloride (SbCl3, 99.999%) were purchased from Sigma Aldrich. Toluene and absolute ethanol were purchased from Beijing Chemical Reagent Ltd., China. Unless otherwise mentioned, all chemicals were used as received without further purification.
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