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6 protocols using dibutyltin dilaurate

1

Polymer-Derived Ceramic Synthesis

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Hydroxyl terminated polymethyldiphenylsiloxane was purchased from the Shanghai Resin company (Shanghai, China); tetraethoxysilane (TEOS), tetrapropoxysilane (TPOS), and dibutyl tin dilaurate (DBTDL) were purchased from Sinopharm (Shanghai, China); polysilazane was purchased from the Institute of Chemistry, Chinese Academy of Sciences (Beijing, China). The molecular weight of the polysilazane was about 1000 Da, and the kinematic viscosity was about 2000–3000 mpa s.
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2

Synthesis of Functionalized Polyesters

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PLLA (Mw = 2.0 × 105 g mol−1) was purchased from Nature Works Company. d-Lactide (optical purity > 99%) was obtained from Jinan Daigang Biomaterial Co., Ltd (Shandong, China). δ-Valerolactone (VL, 98%), ε-caprolactone (CL, 99%), diethylene glycol (DEG, >98%), 2-amino-4-hydroxyl-6-methylpyrimidine and 1,6-hexyldiisocyanate (HDI) were purchased from J&K Chemical (Beijing, China). Dibutyltin dilaurate and stannous octoate (Sn(Oct)2) were acquired from Sinopharm Group Chemical Reagent (China). 2(6-Isocyanatohexylaminocarbonyl-amino)-6-methyl-4[1H]pyrimidinone (UPy-NCO) was synthesized according to a previously reported method35 (link) using 2-amino-4-hydroxyl-6-methylpyrimidine and 1,6-hexyldiisocyanate as raw materials. Toluene was further dried by distillation from sodium prior to use. Other reagents were of analytical grade and used without further purification.
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3

Synthesis of Polyurethane Elastomers

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Isophorone diisocyanate (IPDI, 99%) was bought from Aladdin (Shanghai) Co., Ltd. N, N-bis (2-hydroxyethyl) methylamine (MDEA, 99%), 1,3-propanesultone (PST, 98%) and anhydrous tetrahydrofuran (THF, 99.5%) were all available from Energy Chemical. Polycarbonate diol (PCDL, Mn = 1000 g/mol) was purchased from Shandong Baiyi Chemical Co., Ltd. (Qingdao, China). Dibutyltin dilaurate (DBTDL) and glacial acetic acid (HAc) were supplied from Sinopharm Chemical Reagent Co., Ltd. (Shanghai, China). Additionally, PCDL were vacuum-dried at 100 °C for about 12 h prior to use. All other reagents were used without further purification.
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4

Synthesis of Boron-Based Compounds

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Elemental boron powder (99 wt%) was purchased from Baoding Pengda Chemical Industry Co., Ltd. (Baoding, China). Nitric acid (65–68 wt%), dibutyltin dilaurate (DBTL), 2,4-toluene diisocyanate, 3-amino-1,2,4-triazole and potassium nitrate were of analytical purity and obtained from Sinopharm Chemical Reagent Co., Ltd. Acetone containing water at 0.3 wt% and other reagents used in the presented study were commercially purchased.
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5

Hydrogel-based Heavy Metal Removal

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All reagents used in the experiment were of analytical reagent grade. Poly(ethylene oxide) diglycidyl ether (PEO-DE, Sigma Aldrich, USA) and N-ethylethylene diamine (EED, Alfa Aesar, London) were used as received. 3-Isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate (IPDI), dibutyltin dilaurate (DBTDL), 1-ethyl-3-(3-dimethylaminopropyl) carbodiimide hydrochloride (EDC), N-hydroxyl succinimide (NHS) and other chemicals were obtained from Sinopharm Chemical Reagent Beijing Co., Ltd, China. In addition, methylene blue (MB) and methylene violet (MV), which were employed as the dye source, and lead nitrate, which was employed as the heavy metal source, were dissolved in ultrapure water prior to use. 0.1 mol L−1 HCl and 0.1 mol L−1 NaOH were used for pH adjustment.
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6

Synthesis and Characterization of PEG Polymers

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PEG with Mn of 6 K and of 10 K g/mol was obtained from Sigma-Aldrich (USA), and vacuum dried at 60 °C overnight to remove residual water before use. Stannous octoate, trimethylamine (TEA), DOX, acryloyl chloride, dichloromethane, dimethyl phenylphosphonite, 2,4,6-trimethylbenzoly chloride, lithium bromide, and 2-butanone were purchased from Aladdin (China), and used as received. Diethyl carbonate, 1,3-propanediol, dimethylbenzene, dibutyltin dilaurate, zinc powder and sodium metal were supplied by Sinopharm Chemical Reagent Co., Ltd (Shanghai, China). SK-BR-3 and L929 cells were purchased from ATCC (USA). Fetal bovine serum (FBS), pH 7.4 phosphate-buffered saline (PBS), MoCoy 5A and DMEM with penicillin and streptomycin were obtained from Gibco (USA). Transwell with PC membrane was purchased from Corning (USA).
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