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3 protocols using tantalum 5 chloride

1

Synthesis of Perovskite Oxide Nanoparticles

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Ruthenium(III)
acetylacetonate, Ru(acac)3, sodium acetate CH3COONa, CH3COOH,
Ti(OC(CH3)3)4 (TBOT), lanthanum nitrate,
La(NO3)3·xH2O, tantalum(V) chloride, TaCl5, HCl, CH3OH,
F-127 pluronic (EO106-PO70EO106,
MW 12 600 g mol–1), and C2H5OH were procured from Sigma-Aldrich.
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2

Synthesis and Characterization of Nanoparticles

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Gadolinium(III) acetate hydrate (99.9% trace metals basis), ytterbium(III) chloride hexahydrate (99.9%), tantalum(V) chloride (99.8%), tungsten(VI) chloride (99.9%), gold(III) chloride trihydrate (99.9%), bismuth(III) nitrate pentahydrate (98.0%), tantalum(V) ethoxide (99.98%), cyclohexane (99%), IGEPAL CO-520, ammonium hydroxide solution (28.0–30.0% NH3 basis) and calcium phosphate (96.0%) were purchased from Sigma-Aldrich (St. Louis, MO). 2-(carbomethoxy)ethyltrimethoxysilane and 3-(trimethoxysilyl)propyl-N,N,N-trimethylammonium chloride were obtained from Gelest, Inc (Morrisville, PA). Iomeron 400 mg/ml was purchased from Bracco (Milan, Italy). The cell lines used for in vitro experiments, HepG2, Renca, SVEC4-10EHR1, were provided by ATCC (Manassas, VA). LIVE/DEAD assay kits were purchased from Life Technologies Invitrogen (Grand Island, NY).
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3

Synthesis of Copper-Chitosan Composite

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Copper chloride (CuCl2·2H2O, 97%), chitosan ((C6H11NO4)n, 75–85%), sodium hydroxide (NaOH, 98%) and tantalum(v) chloride (TaCl5, 99.8%) were acquired from Sigma-Aldrich (Germany).
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