Tetrakis acetonitrile copper 1 hexafluorophosphate

Manufactured by Merck Group

Sourced in Belgium

Tetrakis(acetonitrile)copper(I) hexafluorophosphate is a coordination complex used as a precursor in organic synthesis and inorganic chemistry. It contains a central copper(I) ion coordinated to four acetonitrile ligands and a hexafluorophosphate counterion.

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Lab products found in correlation

Oleylamine, by Merck Group (4 mentions) Trioctylphosphine oxide, by Strem Chemicals (2 mentions) Selenium powder, by Strem Chemicals (2 mentions) Sulfur powder, by Merck Group (2 mentions) Cadmium oxide, by Strem Chemicals (2 mentions) Trioctylphosphine, by Strem Chemicals (2 mentions) Octadecene, by Merck Group (2 mentions) 1 dodecanethiol, by Merck Group (2 mentions) Methanol, by Merck Group (2 mentions) 1 octanethiol, by Merck Group (2 mentions) Cadmium chloride, by Merck Group (1 mentions) Copper 1 chloride, by Strem Chemicals (1 mentions) Copper 2 chloride, by Thermo Fisher Scientific (1 mentions) Iodine, by Merck Group (1 mentions) Iron 3 chloride, by Merck Group (1 mentions) Nitric acid, by Carlo Erba (1 mentions) Hexadecylamine, by Merck Group (1 mentions) Anhydrous chloroform, by Merck Group (1 mentions) Tetrachloroethylene, by Merck Group (1 mentions) Copper 2 acetylacetonate, by Merck Group (1 mentions)

Close spelling variants of this product

Acetonitrile (5292 citations) ) copper(I) hexafluorophosphate (2 citations)

9 protocols using tetrakis acetonitrile copper 1 hexafluorophosphate

Synthesis of Colloidal Nanocrystals

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Cadmium oxide (CdO, 99.99%), copper(I) chloride
(CuCl, 99.999%), trioctylphosphine oxide (TOPO, 99%), trioctylphosphine
(TOP, 97%), and selenium powder (Se, 99.99%) were purchased from Strem
Chemicals. Cadmium chloride (CdCl₂, 99.99%), iodine (I₂, 99.99%), iron(III) chloride (FeCl₃, 98%), oleylamine
(70%), tetrakis(acetonitrile)copper(I) hexafluorophosphate, and sulfur
powder (S, 99.9%) were purchased from Sigma-Aldrich. Copper(II) chloride
(CuCl₂, 99%) was purchased from Alfa Aesar. Octadecylphosphonic
acid (ODPA) and hexylphosphonic acid (HPA) were purchased from Polycarbon
Industries. Cerium(IV) ammonium nitrate (>98.5%), nitric acid (HNO₃, 67−69%), anhydrous toluene and methanol were purchased
from Carlo Erba reagents.

Miszta K., Brescia R., Prato M., Bertoni G., Marras S., Xie Y., Ghosh S., Kim M.R, & Manna L. (2014). Hollow and Concave Nanoparticles via Preferential Oxidation of the Core in Colloidal Core/Shell Nanocrystals. Journal of the American Chemical Society, 136(25), 9061-9069.

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Synthesis of Semiconductor Nanocrystals

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Cadmium oxide (CdO, 99.5%), trioctylphosphine
oxide (99%), trioctylphosphine (TOP, 97%), selenium powder (Se, 99.99%),
and lead(II) acetate trihydrate (Pb(CH₃CO₂)₂·3H₂O, 99.999%) were purchased from Strem
Chemicals. Octadecylphosphonic acid (99%) was purchased from Polycarbon
Industries. Copper(II) acetylacetonate (Cu(acac)₂, 97%),
hexadecylamine (98%), tetrakis(acetonitrile)copper(I) hexafluorophosphate
(99.99%), octadecene (technical grade, 90%), 1-dodecanethiol (≥98%),
oleylamine (70%), tetrachloroethylene (≥99%), anhydrous chloroform,
methanol, toluene, and tetrahydrofuran were purchased from Sigma-Aldrich.
All chemicals were used without any further purification.

Gariano G., Lesnyak V., Brescia R., Bertoni G., Dang Z., Gaspari R., De Trizio L, & Manna L. (2017). Role of the Crystal Structure in Cation Exchange Reactions Involving Colloidal Cu2Se Nanocrystals. Journal of the American Chemical Society, 139(28), 9583-9590.

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Synthesis of Colloidal Nanocrystals

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Diethylzinc solution (1.0 M in hexane), zinc acetate (anhydrous, 99.99%), zinc oxide (ZnO, 99.0%), 1-octadecene (ODE, 90%), oleic acid (OA, 90%), selenium (99.99%), 1-octanethiol (≥98.5%), oleylamine (OLA, 70%), cadmium oxide (CdO, ≥99.99%), trioctylphosphine oxide (TOPO, 99%), diphenylphosphine (DPP, 98%), tetrakis(acetonitrile)copper(I) hexafluorophosphate (97%) and zinc chloride (dry, ≥98.5%) were purchased from Sigma. Trioctylphosphine (TOP, 97%) was purchased from Strem. Octadecylphosphonic acid (ODPA, >99%), tetradecylphosphonic acid (TDPA, >99%) and hexylphosphonic acid (HPA, >99%) were purchased from PCI synthesis. All chemicals were used as received without any further purification.

Ji B., Panfil Y.E., Waiskopf N., Remennik S., Popov I, & Banin U. (2019). Strain-controlled shell morphology on quantum rods. Nature Communications, 10, 2.

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Comparative Analysis of Wild-Type and CTR1-Deficient Mouse Fibroblasts

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The wild type mouse embryo fibroblast cell line (CTR^+/+) and a line established from mice in which both alleles of CTR1 were knocked out (CTR1^−/−) were gifts from Dr. Dennis Thiele (Duke University). These cells were grown in DMEM Hi-glucose media with 20% FBS. (Invitrogen, Carlsbad, CA). The human epithelial tumor cell line 2008 was grown in RPMI-1640 media supplemented with 10% FBS. All cells were grown at 37°C and 5% CO₂. The 2008-based CTR2 knock down, mCherry, and mCherry-hCTR2 cell lines were grown continuously in 10 μg/mL puromycin supplemented media. cDDP was purchased from Teva Parenteral Medicines, Inc. (Irvine, CA). Mouse monoclonal antibody to hCTR2 was obtained from the National Cancer Institute. Tetrathiomolybdate and Tetrakis(acetonitrile)copper(I)hexafluorophosphate was purchased from Sigma-Aldrich, St. Louis, MO.

Huang C.P., Fofana M., Chan J., Chang C.J, & Howell S.B. (2014). Copper Transporter 2 Regulates Intracellular Copper and Sensitivity to Cisplatin. Metallomics : integrated biometal science, 6(3), 654-661.

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Synthesis of Colloidal Nanocrystals

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Molybdenum hexacarbonyl, sulfur powder, tetrakis(acetonitrile)copper(i) hexafluorophosphate (97%), and 1-octadecene (ODE, technical grade 90%) were all purchased from Sigma-Aldrich. Oleylamine (OLA, >50%) was purchased from TCI. The solvents such as hexanes (certified ACS grade) were acquired from Fisher Scientific. Ethanol (200 proof) was brought from Decon Laboratories, Inc. All chemicals were used as received without further purification.

Wang Z., Kannan H., Su T., Swaminathan J., Shirodkar S.N., Robles Hernandez F.C., Benavides H.C., Vajtai R., Yakobson B.I., Meiyazhagan A, & Ajayan P.M. (2021). Substitution of copper atoms into defect-rich molybdenum sulfides and their electrocatalytic activity. Nanoscale Advances, 3(6), 1747-1757.

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Copper-Catalyzed Click Chemistry for Oligonucleotides

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4-ethynylaniline (HC ---CC 6 H 4 NH 2 ), 4-azidoaniline hydrochloride (N 3 C 6 H 4 NH 2 • HCl), sodium nitrite (NaNO 2 ), tris[(1-benzyl-1H-1,2,3-triazol-4-yl)methyl]amine (TBTA), tetrakis(acetonitrile)copper(I) hexafluorophosphate (TCH), (+)-sodium L-ascorbate (SA), dimethyl sulfoxide (DMSO), acetonitrile (ACN), iron(III) chloride hexahydrate (FeCl 3 • 6 H 2 O), potassium chloride (KCl), hydrochloric acid (HCl, 37 %), isopropyl alcohol (IPA) and acetone were purchased from Sigma Aldrich (Belgium). All reagents were used without further purification. Alkyne-and azide-modified oligonucleotides (25mer) were purchased from IDT (Belgium) (sequences in Supporting Information).

Levrie K., Jans K., Vos R., Ardakanian N., Verellen N., Van Hoof C., Lagae L, & Stakenborg T. (2016). Multiplexed site-specific electrode functionalization for multitarget biosensors. Bioelectrochemistry (Amsterdam, Netherlands), 112.

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Biofunctionalized Silane Coatings Synthesis

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Methyltrimethoxysilane (98% purity, MTMS), (3-mercaptopropyl)trimethoxysilane (95% purity, MPTMS), hexadecyltrimethylammonium bromide (98% purity, CTAB), methanol (99.8%, MeOH) and tetrakis(acetonitrile)copper(I) hexafluorophosphate were acquired from Sigma Aldrich. Oxalic acid, vinyltrimethoxysilane (97% purity, VTMS), Ellman's reagent (5,5′-dithiobis-(2-nitrobenzoic acid) or DTNB) and sodium azide (NaN 3 ) were from Merck. (3-Chloropropyl)-trimethoxysilane (97% purity; CPTMS) and (3-methacryloxypropyl)trimethoxysilane (98% purity, MAPTMS) were purchased from ABCR. Propiolic acid (98%) was obtained from Acros Organics. Ammonium hydroxide (28% in H 2 O), sodium carbonate (Na 2 CO 3 ), potassium permanganate (KMnO 4 ), N,N-dimethylformamide (DMF), acetonitrile (ACN) and sodium azide were procured from VWR.

Ehgartner C.R., Grandl S., Feinle A, & Hüsing N. (2017). Flexible organofunctional aerogels. Dalton transactions (Cambridge, England : 2003), 46(27).

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Synthesis of Colloidal Nanocrystals

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Copper(I) chloride (CuCl, 99.99% extra pure), ethanol (EtOH, 99.5%, extra dry) and silver nitrate (99.85%) were purchased from Acros Organics. Selenium (Se, 99.999%, 200 mesh), methanol (MeOH, 99.9%, anhydrous), toluene (99.8%, anhydrous packed under argon) and n-butanol (99.9% packed under argon) were purchased from Alfa Aesar. Sulfur (S, 99.98%), tetrakis (acetonitrile)copper(I) hexafluorophosphate ([Cu(CH 3 CN) 4 ]PF 6 , 97%), dodecylamine (DDA, 98%), didodecyl-dimethylammonium bromide (DDAB, 98%), octadecene (ODE, 90%) and oleylamine (OLA, >70%) were purchased from Sigma Aldrich. Gold(III) chloride (99%) was purchased from ABCR. Hydrochloric acid (>37%, for trace analysis) and nitric acid (>69%, for trace analysis) were purchased from Fluka.
Pre-degassed OLA and ODE were prepared by placing each solvent in a separate flask and heating them under reflux (≤1 × 10 -3 mbar, 115 °C) for 6 h, while purging them multiple times with argon. Afterwards they are transferred and stored inside the glove box under inert gas.
All other chemicals were used without further purification.
If not otherwise mentioned all experiments have been done under argon using standard Schlenk line techniques or were done inside a nitrogen filled glove box.

Wolf A., Kodanek T, & Dorfs D. (2015). Tuning the LSPR in copper chalcogenide nanoparticles by cation intercalation, cation exchange and metal growth. Nanoscale, 7(46).

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Synthesis of Colloidal Nanoparticles

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Chemicals 1-Octadecene (ODE, 90%), oleic acid (90%) and 1-octylamine (99%) were purchased from Alfa Aesar. 1-Octanethiol (OT, 98.5%), 1-octadecanethiol (ODT, 98%), 1-dodecanethiol (DDT, 98%), 1-hexadecanethiol (HDT, 95%), trioctylphosphine (TOP, 97%), tetrakis(acetonitrile)copper(I) hexafluorophosphate (97%), cadmium nitrate tetrahydrate (Cd(NO 3 )•4H 2 O, 99%) and cadmium acetate dihydrate (98%) were obtained from Sigma-Aldrich. Selenium powder (99.99%) was purchased from Strem. Na(myristate) (98%) was purchased from TCI.
All chemicals were used directly without purification.

Martinet Q ., Baronnier J ., Girard A ., Albaret T ., Saviot L ., Mermet A ., Abecassis B ., Margueritat J , & Mahler B . (2021). Ligand-dependent nano-mechanical properties of CdSe nanoplatelets: calibrating nanobalances for ligand affinity monitoring. Nanoscale, 13(18).

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